Literature DB >> 23478646

Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts.

Manuel Alcarazo1, Karin Radkowski, Gerlinde Mehler, Richard Goddard, Alois Fürstner.   

Abstract

Heterobimetallic complexes derived from carbodiphosphoranes or phosphinidene-carbene adducts are reported, in which the central atom accepts two lone-pairs from two different donor ligands and - at the same time - donates two lone-pairs to two different metal centers. Therefore these complexes are carbogenic yet captodative chiral entities.

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Year:  2013        PMID: 23478646     DOI: 10.1039/c3cc40382c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  6 in total

1.  Metalated Ylides: A New Class of Strong Donor Ligands with Unique Electronic Properties.

Authors:  Lennart T Scharf; Viktoria H Gessner
Journal:  Inorg Chem       Date:  2017-02-27       Impact factor: 5.165

2.  The Bonding Situation in Metalated Ylides.

Authors:  Lennart T Scharf; Diego M Andrada; Gernot Frenking; Viktoria H Gessner
Journal:  Chemistry       Date:  2017-03-07       Impact factor: 5.236

3.  Double dative bond between divalent carbon(0) and uranium.

Authors:  Wei Su; Sudip Pan; Xiong Sun; Shuao Wang; Lili Zhao; Gernot Frenking; Congqing Zhu
Journal:  Nat Commun       Date:  2018-11-27       Impact factor: 14.919

4.  Treatment of Silylene-Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon-Bonded Chalcogens.

Authors:  Soumen Sinhababu; Mujahuddin M Siddiqui; Samir Kumar Sarkar; Annika Münch; Regine Herbst-Irmer; Anjana George; Pattiyil Parameswaran; Dietmar Stalke; Herbert W Roesky
Journal:  Chemistry       Date:  2019-08-13       Impact factor: 5.236

5.  Complexes of Dichlorogermylene with Phosphine/Sulfoxide-Supported Carbone as Ligand.

Authors:  Ugo Authesserre; Sophie Hameury; Aymeric Dajnak; Nathalie Saffon-Merceron; Antoine Baceiredo; David Madec; Eddy Maerten
Journal:  Molecules       Date:  2021-04-01       Impact factor: 4.411

6.  Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.

Authors:  Kuntal Pal; Oliver B Hemming; Benjamin M Day; Thomas Pugh; David J Evans; Richard A Layfield
Journal:  Angew Chem Int Ed Engl       Date:  2015-12-08       Impact factor: 15.336

  6 in total

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