catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κ(2) O,O')erbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

In the title compound, {[Er(NO3)2(C6H18N3OP)4][AgWS4]} n , the polymeric anionic chain {[AgWS4](-)} n extends along [001]. The Er(III) atom in the cation is coordinated by eight O atoms from two bidentate nitrate anions and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having a [WS4Ag] repeat unit. The polymeric anionic chain has a distorted linear configuration, with W-Ag-W and Ag-W-Ag angles of 161.37 (2) and 153.548 (12)°, respectively. The title complex is isotypic with the Y, Yb, Eu, Nd, La, Dy, Sm, Lu and Tb analogues.

Related literature

For one-dimensional Mo(W)/S/Ag anionic polymers, see: Niu et al. (2004 ▶); Zhang et al. (2010 ▶). For their unique properties, see: Zhang, Song et al. (2007 ▶). For isotypic compounds, see: Zhang, Cao et al. (2007 ▶); Cao et al. (2007 ▶); Zhang, Qian et al. (2007 ▶); Tang, Zhang & Zhang (2008 ▶); Tang, Zhang, Zhang & Lu (2008 ▶); Zhang (2010 ▶); Zhang (2011a ▶,b ▶); Zhang (2012a ▶,b ▶).

Experimental

Crystal data

[Er(NO3)2(C6H18N3OP)4][AgWS4]

M = 1428.09

Monoclinic,

a = 15.763 (3) Å

b = 29.579 (6) Å

c = 11.368 (2) Å

β = 90.83 (3)°

V = 5299.8 (17) Å3

Z = 4

Mo Kα radiation

μ = 4.43 mm−1

T = 150 K

0.2 × 0.17 × 0.15 mm

Data collection

Rigaku Saturn724+ diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2008 ▶) T min = 0.428, T max = 0.514

26753 measured reflections

9597 independent reflections

8722 reflections with I > 2σ(I)

R int = 0.044

Standard reflections: 0

Refinement

R[F 2 > 2σ(F 2)] = 0.047

wR(F 2) = 0.092

S = 1.08

9597 reflections

532 parameters

H-atom parameters constrained

Δρmax = 0.91 e Å−3

Δρmin = −1.04 e Å−3

Data collection: CrystalClear (Rigaku, 2008 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812049987/rz5031sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812049987/rz5031Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Er(NO3)2(C6H18N3OP)4][AgWS4]	F(000) = 2828
Mr = 1428.09	Dx = 1.790 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 16527 reflections
a = 15.763 (3) Å	θ = 3.2–29.1°
b = 29.579 (6) Å	µ = 4.43 mm−1
c = 11.368 (2) Å	T = 150 K
β = 90.83 (3)°	Block, orange
V = 5299.8 (17) Å3	0.2 × 0.17 × 0.15 mm
Z = 4

Rigaku Saturn724+ diffractometer	9597 independent reflections
Radiation source: fine-focus sealed tube	8722 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.044
ω scans	θmax = 25.4°, θmin = 3.2°
Absorption correction: multi-scan (CrystalClear; Rigaku, 2008)	h = −15→18
Tmin = 0.428, Tmax = 0.514	k = −35→33
26753 measured reflections	l = −13→11

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.092	H-atom parameters constrained
S = 1.08	w = 1/[σ2(Fo2) + (0.024P)2 + 26.5377P] where P = (Fo2 + 2Fc2)/3
9597 reflections	(Δ/σ)max = 0.001
532 parameters	Δρmax = 0.91 e Å−3
0 restraints	Δρmin = −1.04 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Er1	0.261717 (18)	0.082599 (10)	0.17242 (3)	0.02182 (9)
P1	0.30083 (12)	−0.03020 (6)	0.29957 (18)	0.0304 (4)
P2	0.47743 (11)	0.13250 (6)	0.17898 (17)	0.0283 (4)
P3	0.20599 (14)	0.14671 (7)	−0.09571 (19)	0.0396 (5)
P4	0.04219 (11)	0.09630 (6)	0.26880 (18)	0.0301 (4)
O1	0.2929 (3)	0.01824 (14)	0.2704 (4)	0.0286 (11)
O2	0.3962 (3)	0.10679 (15)	0.1766 (4)	0.0270 (11)
O3	0.2272 (3)	0.12660 (16)	0.0203 (4)	0.0332 (12)
O4	0.1247 (3)	0.08070 (15)	0.2201 (5)	0.0314 (12)
O5	0.1983 (3)	0.02697 (16)	0.0365 (5)	0.0333 (12)
O6	0.3308 (3)	0.04094 (15)	0.0120 (4)	0.0309 (11)
O7	0.2627 (4)	0.00150 (19)	−0.1184 (5)	0.0517 (16)
O8	0.2475 (3)	0.15793 (16)	0.2617 (5)	0.0355 (12)
O9	0.2759 (3)	0.10278 (16)	0.3788 (4)	0.0326 (12)
O10	0.2730 (5)	0.1713 (2)	0.4458 (6)	0.0662 (19)
N1	0.2634 (4)	0.0222 (2)	−0.0254 (6)	0.0325 (14)
N2	0.2654 (4)	0.1450 (2)	0.3649 (6)	0.0387 (16)
N3	0.2788 (4)	−0.0367 (2)	0.4396 (5)	0.0369 (15)
N4	0.2357 (5)	−0.0654 (2)	0.2322 (6)	0.0455 (18)
N5	0.3945 (4)	−0.0479 (2)	0.2606 (6)	0.0471 (18)
N6	0.4773 (4)	0.1728 (2)	0.0807 (7)	0.0453 (18)
N7	0.5551 (3)	0.0976 (2)	0.1525 (5)	0.0321 (14)
N8	0.4928 (4)	0.1561 (3)	0.3049 (6)	0.0478 (18)
N9	0.1046 (5)	0.1388 (3)	−0.1233 (8)	0.072 (3)
N10	0.2258 (5)	0.2001 (2)	−0.0937 (6)	0.051 (2)
N11	0.2596 (6)	0.1239 (3)	−0.1975 (7)	0.063 (2)
N12	−0.0330 (4)	0.0706 (2)	0.1969 (6)	0.0448 (18)
N13	0.0175 (4)	0.1493 (2)	0.2613 (7)	0.0478 (18)
N14	0.0442 (4)	0.0864 (2)	0.4119 (6)	0.0444 (17)
C1	0.2737 (6)	−0.0824 (3)	0.4912 (8)	0.055 (2)
H1A	0.2610	−0.0801	0.5733	0.082*
H1B	0.3269	−0.0977	0.4821	0.082*
H1C	0.2297	−0.0993	0.4518	0.082*
C2	0.3022 (6)	−0.0022 (3)	0.5231 (8)	0.054 (2)
H2A	0.2852	−0.0113	0.6003	0.081*
H2B	0.2744	0.0256	0.5022	0.081*
H2C	0.3626	0.0021	0.5224	0.081*
C3	0.2467 (7)	−0.0811 (3)	0.1146 (10)	0.076 (3)
H3A	0.2009	−0.1011	0.0934	0.114*
H3B	0.2996	−0.0971	0.1096	0.114*
H3C	0.2471	−0.0558	0.0618	0.114*
C4	0.1460 (6)	−0.0679 (4)	0.2662 (11)	0.084 (4)
H4A	0.1171	−0.0898	0.2179	0.126*
H4B	0.1200	−0.0388	0.2554	0.126*
H4C	0.1426	−0.0766	0.3473	0.126*
C5	0.4648 (5)	−0.0170 (3)	0.2516 (9)	0.060 (3)
H5A	0.5145	−0.0333	0.2284	0.089*
H5B	0.4751	−0.0029	0.3265	0.089*
H5C	0.4516	0.0057	0.1939	0.089*
C6	0.4187 (7)	−0.0955 (3)	0.2793 (10)	0.077 (3)
H6A	0.4756	−0.1002	0.2528	0.115*
H6B	0.3805	−0.1148	0.2358	0.115*
H6C	0.4157	−0.1026	0.3615	0.115*
C7	0.5461 (6)	0.1830 (3)	0.0021 (9)	0.060 (3)
H7A	0.5306	0.2081	−0.0470	0.090*
H7B	0.5573	0.1571	−0.0462	0.090*
H7C	0.5960	0.1904	0.0474	0.090*
C8	0.4101 (6)	0.2069 (3)	0.0814 (10)	0.069 (3)
H8A	0.4190	0.2281	0.0189	0.103*
H8B	0.4111	0.2225	0.1555	0.103*
H8C	0.3561	0.1924	0.0703	0.103*
C9	0.6430 (5)	0.1065 (3)	0.1885 (8)	0.052 (2)
H9A	0.6784	0.0820	0.1639	0.078*
H9B	0.6464	0.1094	0.2726	0.078*
H9C	0.6619	0.1341	0.1528	0.078*
C10	0.5464 (5)	0.0644 (3)	0.0569 (7)	0.0403 (19)
H10A	0.5972	0.0466	0.0527	0.060*
H10B	0.5372	0.0799	−0.0164	0.060*
H10C	0.4989	0.0450	0.0719	0.060*
C11	0.5348 (6)	0.2001 (4)	0.3221 (10)	0.085 (4)
H11A	0.5376	0.2070	0.4045	0.127*
H11B	0.5031	0.2231	0.2814	0.127*
H11C	0.5912	0.1987	0.2915	0.127*
C12	0.4797 (6)	0.1309 (5)	0.4108 (9)	0.085 (4)
H12A	0.4919	0.1498	0.4777	0.127*
H12B	0.5167	0.1051	0.4123	0.127*
H12C	0.4218	0.1210	0.4133	0.127*
C13	0.0645 (7)	0.0960 (4)	−0.1105 (11)	0.082 (4)
H13A	0.0056	0.0985	−0.1321	0.124*
H13B	0.0695	0.0862	−0.0302	0.124*
H13C	0.0913	0.0743	−0.1606	0.124*
C14	0.0490 (8)	0.1713 (4)	−0.1835 (11)	0.099 (5)
H14A	−0.0070	0.1587	−0.1911	0.148*
H14B	0.0707	0.1777	−0.2601	0.148*
H14C	0.0467	0.1987	−0.1385	0.148*
C15	0.1981 (6)	0.2275 (3)	0.0056 (7)	0.049 (2)
H15A	0.2141	0.2584	−0.0068	0.073*
H15B	0.2244	0.2166	0.0768	0.073*
H15C	0.1375	0.2255	0.0120	0.073*
C16	0.2511 (9)	0.2258 (4)	−0.1981 (9)	0.092 (4)
H16A	0.2589	0.2570	−0.1773	0.137*
H16B	0.2077	0.2234	−0.2579	0.137*
H16C	0.3033	0.2138	−0.2275	0.137*
C17	0.3500 (7)	0.1209 (4)	−0.1868 (9)	0.078 (3)
H17A	0.3722	0.1064	−0.2554	0.116*
H17B	0.3648	0.1035	−0.1183	0.116*
H17C	0.3735	0.1507	−0.1796	0.116*
C18	0.2210 (11)	0.1070 (5)	−0.3088 (9)	0.127 (6)
H18A	0.2645	0.0948	−0.3577	0.190*
H18B	0.1932	0.1315	−0.3492	0.190*
H18C	0.1803	0.0839	−0.2916	0.190*
C19	−0.0203 (5)	0.0279 (3)	0.1385 (10)	0.067 (3)
H19A	−0.0725	0.0184	0.1013	0.100*
H19B	−0.0028	0.0056	0.1953	0.100*
H19C	0.0227	0.0311	0.0803	0.100*
C20	−0.1227 (5)	0.0803 (4)	0.2196 (11)	0.084 (4)
H20A	−0.1578	0.0618	0.1693	0.126*
H20B	−0.1341	0.1116	0.2040	0.126*
H20C	−0.1347	0.0737	0.3003	0.126*
C21	0.0485 (6)	0.1832 (3)	0.3428 (12)	0.085 (4)
H21A	0.0259	0.2122	0.3211	0.127*
H21B	0.1093	0.1842	0.3405	0.127*
H21C	0.0309	0.1757	0.4209	0.127*
C22	−0.0138 (8)	0.1691 (4)	0.1509 (10)	0.092 (4)
H22A	−0.0252	0.2007	0.1623	0.138*
H22B	−0.0651	0.1540	0.1266	0.138*
H22C	0.0282	0.1655	0.0913	0.138*
C23	0.0923 (5)	0.0480 (3)	0.4562 (8)	0.053 (2)
H23A	0.0877	0.0466	0.5403	0.079*
H23B	0.1509	0.0514	0.4358	0.079*
H23C	0.0703	0.0207	0.4220	0.079*
C24	−0.0291 (7)	0.0965 (4)	0.4838 (9)	0.085 (4)
H24A	−0.0169	0.0887	0.5642	0.127*
H24B	−0.0771	0.0794	0.4559	0.127*
H24C	−0.0418	0.1282	0.4787	0.127*
W1	0.783523 (17)	0.227488 (9)	0.52651 (2)	0.02184 (8)
Ag1	0.78222 (4)	0.26566 (2)	0.28700 (5)	0.03871 (16)
S1	0.78533 (12)	0.18464 (6)	0.36793 (16)	0.0312 (4)
S2	0.78321 (13)	0.30066 (6)	0.48679 (17)	0.0361 (5)
S3	0.66880 (12)	0.21148 (7)	0.62708 (17)	0.0353 (4)
S4	0.89701 (12)	0.21219 (7)	0.63272 (17)	0.0382 (5)

	U11	U22	U33	U12	U13	U23
Er1	0.01984 (16)	0.01636 (16)	0.02925 (18)	0.00031 (11)	0.00027 (13)	0.00062 (13)
P1	0.0344 (10)	0.0222 (10)	0.0347 (11)	0.0047 (8)	0.0069 (9)	0.0060 (8)
P2	0.0217 (9)	0.0340 (11)	0.0293 (10)	−0.0055 (8)	−0.0002 (8)	−0.0064 (8)
P3	0.0588 (14)	0.0271 (11)	0.0324 (11)	0.0096 (9)	−0.0183 (10)	−0.0012 (9)
P4	0.0204 (9)	0.0275 (10)	0.0425 (12)	0.0011 (7)	0.0024 (8)	−0.0075 (9)
O1	0.037 (3)	0.016 (2)	0.033 (3)	0.003 (2)	0.001 (2)	0.002 (2)
O2	0.023 (2)	0.025 (3)	0.033 (3)	0.0008 (19)	0.001 (2)	0.001 (2)
O3	0.033 (3)	0.030 (3)	0.036 (3)	0.000 (2)	−0.005 (2)	0.005 (2)
O4	0.023 (2)	0.026 (3)	0.045 (3)	0.003 (2)	0.004 (2)	−0.004 (2)
O5	0.026 (3)	0.026 (3)	0.048 (3)	0.002 (2)	−0.004 (2)	−0.007 (2)
O6	0.024 (3)	0.028 (3)	0.040 (3)	0.000 (2)	0.003 (2)	−0.002 (2)
O7	0.056 (4)	0.051 (4)	0.048 (4)	0.004 (3)	−0.005 (3)	−0.026 (3)
O8	0.038 (3)	0.025 (3)	0.043 (3)	0.004 (2)	−0.001 (3)	0.000 (2)
O9	0.044 (3)	0.023 (3)	0.032 (3)	0.001 (2)	0.005 (2)	0.001 (2)
O10	0.100 (5)	0.045 (4)	0.053 (4)	0.018 (4)	−0.009 (4)	−0.020 (3)
N1	0.027 (3)	0.031 (3)	0.039 (4)	0.003 (3)	−0.005 (3)	−0.007 (3)
N2	0.047 (4)	0.029 (4)	0.040 (4)	0.005 (3)	−0.001 (3)	−0.009 (3)
N3	0.052 (4)	0.029 (3)	0.030 (4)	0.005 (3)	0.006 (3)	0.005 (3)
N4	0.059 (5)	0.025 (3)	0.054 (5)	−0.009 (3)	0.024 (4)	−0.007 (3)
N5	0.043 (4)	0.043 (4)	0.056 (5)	0.019 (3)	0.015 (3)	0.021 (4)
N6	0.037 (4)	0.036 (4)	0.064 (5)	−0.004 (3)	0.014 (3)	0.013 (3)
N7	0.020 (3)	0.045 (4)	0.031 (3)	0.001 (3)	0.001 (3)	−0.003 (3)
N8	0.036 (4)	0.069 (5)	0.039 (4)	0.000 (3)	−0.003 (3)	−0.022 (4)
N9	0.072 (6)	0.043 (5)	0.101 (7)	0.019 (4)	−0.055 (5)	0.000 (5)
N10	0.092 (6)	0.030 (4)	0.033 (4)	0.012 (4)	0.002 (4)	0.011 (3)
N11	0.092 (6)	0.049 (5)	0.049 (5)	0.025 (4)	0.003 (5)	−0.009 (4)
N12	0.023 (3)	0.053 (4)	0.058 (5)	0.000 (3)	0.006 (3)	−0.032 (4)
N13	0.039 (4)	0.034 (4)	0.070 (5)	0.003 (3)	0.009 (4)	−0.010 (4)
N14	0.037 (4)	0.058 (5)	0.038 (4)	0.010 (3)	0.000 (3)	−0.004 (3)
C1	0.067 (6)	0.040 (5)	0.057 (6)	0.015 (4)	0.020 (5)	0.024 (4)
C2	0.067 (6)	0.053 (6)	0.042 (5)	0.009 (5)	−0.001 (5)	0.013 (5)
C3	0.097 (8)	0.055 (6)	0.077 (8)	−0.023 (6)	0.010 (7)	−0.030 (6)
C4	0.062 (7)	0.086 (8)	0.104 (10)	−0.018 (6)	0.003 (7)	−0.033 (7)
C5	0.034 (5)	0.059 (6)	0.086 (8)	0.003 (4)	−0.010 (5)	−0.008 (6)
C6	0.091 (8)	0.057 (6)	0.083 (8)	0.038 (6)	0.035 (6)	0.025 (6)
C7	0.060 (6)	0.049 (6)	0.072 (7)	−0.021 (5)	0.026 (5)	0.008 (5)
C8	0.069 (7)	0.035 (5)	0.103 (9)	−0.004 (5)	0.018 (6)	0.022 (5)
C9	0.034 (5)	0.072 (6)	0.050 (6)	0.005 (4)	−0.004 (4)	−0.011 (5)
C10	0.030 (4)	0.054 (5)	0.036 (5)	−0.002 (4)	0.010 (3)	−0.013 (4)
C11	0.061 (7)	0.091 (8)	0.102 (9)	−0.002 (6)	−0.024 (6)	−0.070 (8)
C12	0.052 (6)	0.160 (12)	0.043 (6)	0.016 (7)	−0.011 (5)	−0.003 (7)
C13	0.068 (7)	0.062 (7)	0.116 (10)	0.001 (6)	−0.045 (7)	−0.012 (7)
C14	0.111 (10)	0.074 (8)	0.108 (10)	0.036 (7)	−0.065 (8)	−0.002 (7)
C15	0.077 (6)	0.026 (4)	0.043 (5)	0.009 (4)	0.010 (5)	−0.001 (4)
C16	0.172 (13)	0.057 (7)	0.047 (7)	0.024 (7)	0.034 (7)	0.022 (5)
C17	0.100 (9)	0.075 (7)	0.059 (7)	0.034 (7)	0.035 (6)	0.008 (6)
C18	0.217 (17)	0.130 (12)	0.034 (6)	−0.022 (12)	0.002 (8)	−0.046 (7)
C19	0.035 (5)	0.064 (6)	0.101 (9)	−0.005 (4)	0.005 (5)	−0.042 (6)
C20	0.029 (5)	0.110 (9)	0.114 (10)	0.001 (5)	0.003 (5)	−0.076 (8)
C21	0.052 (6)	0.037 (5)	0.165 (13)	−0.011 (4)	0.029 (7)	−0.049 (7)
C22	0.103 (9)	0.083 (8)	0.091 (9)	0.058 (7)	0.031 (7)	0.037 (7)
C23	0.040 (5)	0.078 (7)	0.040 (5)	−0.002 (5)	0.002 (4)	0.005 (5)
C24	0.069 (7)	0.128 (10)	0.058 (7)	0.045 (7)	0.019 (6)	−0.012 (7)
W1	0.02715 (16)	0.02019 (15)	0.01811 (15)	0.00253 (11)	−0.00214 (11)	−0.00094 (11)
Ag1	0.0607 (4)	0.0356 (3)	0.0198 (3)	0.0003 (3)	−0.0010 (3)	0.0023 (2)
S1	0.0455 (11)	0.0234 (9)	0.0246 (9)	−0.0004 (8)	0.0008 (8)	−0.0048 (7)
S2	0.0564 (13)	0.0218 (9)	0.0301 (10)	0.0037 (8)	0.0015 (9)	−0.0032 (8)
S3	0.0301 (10)	0.0457 (12)	0.0301 (10)	−0.0059 (8)	0.0016 (8)	−0.0020 (9)
S4	0.0353 (11)	0.0491 (12)	0.0300 (10)	0.0155 (9)	−0.0064 (9)	−0.0044 (9)

Er1—O3	2.225 (5)	C6—H6A	0.9600
Er1—O4	2.235 (5)	C6—H6B	0.9600
Er1—O2	2.237 (4)	C6—H6C	0.9600
Er1—O1	2.256 (4)	C7—H7A	0.9600
Er1—O9	2.428 (5)	C7—H7B	0.9600
Er1—O5	2.460 (5)	C7—H7C	0.9600
Er1—O8	2.460 (5)	C8—H8A	0.9600
Er1—O6	2.468 (5)	C8—H8B	0.9600
Er1—N2	2.863 (6)	C8—H8C	0.9600
Er1—N1	2.872 (6)	C9—H9A	0.9600
P1—O1	1.476 (5)	C9—H9B	0.9600
P1—N5	1.634 (7)	C9—H9C	0.9600
P1—N4	1.644 (7)	C10—H10A	0.9600
P1—N3	1.646 (6)	C10—H10B	0.9600
P2—O2	1.489 (5)	C10—H10C	0.9600
P2—N8	1.609 (7)	C11—H11A	0.9600
P2—N7	1.634 (6)	C11—H11B	0.9600
P2—N6	1.633 (7)	C11—H11C	0.9600
P3—O3	1.481 (5)	C12—H12A	0.9600
P3—N11	1.593 (8)	C12—H12B	0.9600
P3—N10	1.610 (7)	C12—H12C	0.9600
P3—N9	1.640 (8)	C13—H13A	0.9600
P4—O4	1.494 (5)	C13—H13B	0.9600
P4—N13	1.619 (7)	C13—H13C	0.9600
P4—N12	1.620 (6)	C14—H14A	0.9600
P4—N14	1.653 (7)	C14—H14B	0.9600
O5—N1	1.260 (8)	C14—H14C	0.9600
O6—N1	1.266 (7)	C15—H15A	0.9600
O7—N1	1.223 (8)	C15—H15B	0.9600
O8—N2	1.262 (8)	C15—H15C	0.9600
O9—N2	1.269 (8)	C16—H16A	0.9600
O10—N2	1.208 (8)	C16—H16B	0.9600
N3—C2	1.438 (10)	C16—H16C	0.9600
N3—C1	1.476 (9)	C17—H17A	0.9600
N4—C3	1.429 (12)	C17—H17B	0.9600
N4—C4	1.472 (12)	C17—H17C	0.9600
N5—C5	1.442 (11)	C18—H18A	0.9600
N5—C6	1.473 (11)	C18—H18B	0.9600
N6—C7	1.446 (10)	C18—H18C	0.9600
N6—C8	1.462 (11)	C19—H19A	0.9600
N7—C9	1.463 (9)	C19—H19B	0.9600
N7—C10	1.470 (9)	C19—H19C	0.9600
N8—C12	1.433 (13)	C20—H20A	0.9600
N8—C11	1.470 (12)	C20—H20B	0.9600
N9—C13	1.425 (12)	C20—H20C	0.9600
N9—C14	1.464 (11)	C21—H21A	0.9600
N10—C15	1.461 (10)	C21—H21B	0.9600
N10—C16	1.471 (11)	C21—H21C	0.9600
N11—C17	1.430 (13)	C22—H22A	0.9600
N11—C18	1.482 (12)	C22—H22B	0.9600
N12—C19	1.444 (10)	C22—H22C	0.9600
N12—C20	1.468 (10)	C23—H23A	0.9600
N13—C21	1.445 (11)	C23—H23B	0.9600
N13—C22	1.463 (12)	C23—H23C	0.9600
N14—C23	1.450 (10)	C24—H24A	0.9600
N14—C24	1.457 (11)	C24—H24B	0.9600
C1—H1A	0.9600	C24—H24C	0.9600
C1—H1B	0.9600	W1—S4	2.1909 (19)
C1—H1C	0.9600	W1—S1	2.2043 (18)
C2—H2A	0.9600	W1—S3	2.205 (2)
C2—H2B	0.9600	W1—S2	2.2108 (19)
C2—H2C	0.9600	W1—Ag1	2.9474 (8)
C3—H3A	0.9600	W1—Ag1i	2.9685 (8)
C3—H3B	0.9600	Ag1—S2	2.496 (2)
C3—H3C	0.9600	Ag1—S1	2.5674 (19)
C4—H4A	0.9600	Ag1—S3ii	2.620 (2)
C4—H4B	0.9600	Ag1—S4ii	2.621 (2)
C4—H4C	0.9600	Ag1—W1ii	2.9685 (8)
C5—H5A	0.9600	S3—Ag1i	2.620 (2)
C5—H5B	0.9600	S4—Ag1i	2.621 (2)
C5—H5C	0.9600
O3—Er1—O4	88.67 (18)	N5—C5—H5C	109.5
O3—Er1—O2	92.88 (17)	H5A—C5—H5C	109.5
O4—Er1—O2	157.15 (17)	H5B—C5—H5C	109.5
O3—Er1—O1	157.85 (17)	N5—C6—H6A	109.5
O4—Er1—O1	93.63 (17)	N5—C6—H6B	109.5
O2—Er1—O1	93.44 (16)	H6A—C6—H6B	109.5
O3—Er1—O9	128.68 (17)	N5—C6—H6C	109.5
O4—Er1—O9	81.22 (17)	H6A—C6—H6C	109.5
O2—Er1—O9	80.05 (17)	H6B—C6—H6C	109.5
O1—Er1—O9	73.38 (16)	N6—C7—H7A	109.5
O3—Er1—O5	79.08 (17)	N6—C7—H7B	109.5
O4—Er1—O5	75.53 (17)	H7A—C7—H7B	109.5
O2—Er1—O5	127.14 (17)	N6—C7—H7C	109.5
O1—Er1—O5	80.18 (16)	H7A—C7—H7C	109.5
O9—Er1—O5	143.35 (17)	H7B—C7—H7C	109.5
O3—Er1—O8	76.60 (18)	N6—C8—H8A	109.5
O4—Er1—O8	80.12 (17)	N6—C8—H8B	109.5
O2—Er1—O8	78.09 (16)	H8A—C8—H8B	109.5
O1—Er1—O8	125.51 (17)	N6—C8—H8C	109.5
O9—Er1—O8	52.13 (16)	H8A—C8—H8C	109.5
O5—Er1—O8	145.74 (16)	H8B—C8—H8C	109.5
O3—Er1—O6	79.83 (17)	N7—C9—H9A	109.5
O4—Er1—O6	127.23 (16)	N7—C9—H9B	109.5
O2—Er1—O6	75.36 (16)	H9A—C9—H9B	109.5
O1—Er1—O6	81.28 (16)	N7—C9—H9C	109.5
O9—Er1—O6	143.29 (16)	H9A—C9—H9C	109.5
O5—Er1—O6	51.78 (16)	H9B—C9—H9C	109.5
O8—Er1—O6	143.25 (17)	N7—C10—H10A	109.5
O3—Er1—N2	102.64 (19)	N7—C10—H10B	109.5
O4—Er1—N2	80.79 (18)	H10A—C10—H10B	109.5
O2—Er1—N2	76.62 (18)	N7—C10—H10C	109.5
O1—Er1—N2	99.48 (18)	H10A—C10—H10C	109.5
O9—Er1—N2	26.14 (17)	H10B—C10—H10C	109.5
O5—Er1—N2	156.23 (18)	N8—C11—H11A	109.5
O8—Er1—N2	26.05 (17)	N8—C11—H11B	109.5
O6—Er1—N2	151.96 (17)	H11A—C11—H11B	109.5
O3—Er1—N1	76.12 (18)	N8—C11—H11C	109.5
O4—Er1—N1	101.18 (17)	H11A—C11—H11C	109.5
O2—Er1—N1	101.32 (17)	H11B—C11—H11C	109.5
O1—Er1—N1	81.82 (17)	N8—C12—H12A	109.5
O9—Er1—N1	155.20 (16)	N8—C12—H12B	109.5
O5—Er1—N1	25.89 (16)	H12A—C12—H12B	109.5
O8—Er1—N1	152.64 (18)	N8—C12—H12C	109.5
O6—Er1—N1	26.06 (15)	H12A—C12—H12C	109.5
N2—Er1—N1	177.59 (19)	H12B—C12—H12C	109.5
O1—P1—N5	109.0 (3)	N9—C13—H13A	109.5
O1—P1—N4	117.4 (3)	N9—C13—H13B	109.5
N5—P1—N4	103.4 (4)	H13A—C13—H13B	109.5
O1—P1—N3	108.2 (3)	N9—C13—H13C	109.5
N5—P1—N3	115.4 (3)	H13A—C13—H13C	109.5
N4—P1—N3	103.7 (3)	H13B—C13—H13C	109.5
O2—P2—N8	110.9 (3)	N9—C14—H14A	109.5
O2—P2—N7	108.7 (3)	N9—C14—H14B	109.5
N8—P2—N7	109.6 (3)	H14A—C14—H14B	109.5
O2—P2—N6	111.6 (3)	N9—C14—H14C	109.5
N8—P2—N6	106.9 (4)	H14A—C14—H14C	109.5
N7—P2—N6	109.2 (3)	H14B—C14—H14C	109.5
O3—P3—N11	111.2 (4)	N10—C15—H15A	109.5
O3—P3—N10	109.9 (3)	N10—C15—H15B	109.5
N11—P3—N10	108.8 (4)	H15A—C15—H15B	109.5
O3—P3—N9	108.7 (4)	N10—C15—H15C	109.5
N11—P3—N9	109.0 (5)	H15A—C15—H15C	109.5
N10—P3—N9	109.3 (4)	H15B—C15—H15C	109.5
O4—P4—N13	119.4 (3)	N10—C16—H16A	109.5
O4—P4—N12	107.6 (3)	N10—C16—H16B	109.5
N13—P4—N12	104.7 (4)	H16A—C16—H16B	109.5
O4—P4—N14	107.8 (3)	N10—C16—H16C	109.5
N13—P4—N14	103.0 (4)	H16A—C16—H16C	109.5
N12—P4—N14	114.7 (4)	H16B—C16—H16C	109.5
P1—O1—Er1	161.3 (3)	N11—C17—H17A	109.5
P2—O2—Er1	168.0 (3)	N11—C17—H17B	109.5
P3—O3—Er1	167.6 (3)	H17A—C17—H17B	109.5
P4—O4—Er1	158.7 (3)	N11—C17—H17C	109.5
N1—O5—Er1	95.6 (4)	H17A—C17—H17C	109.5
N1—O6—Er1	95.1 (4)	H17B—C17—H17C	109.5
N2—O8—Er1	95.1 (4)	N11—C18—H18A	109.5
N2—O9—Er1	96.4 (4)	N11—C18—H18B	109.5
O7—N1—O5	122.8 (6)	H18A—C18—H18B	109.5
O7—N1—O6	120.4 (6)	N11—C18—H18C	109.5
O5—N1—O6	116.8 (6)	H18A—C18—H18C	109.5
O7—N1—Er1	171.6 (5)	H18B—C18—H18C	109.5
O5—N1—Er1	58.5 (3)	N12—C19—H19A	109.5
O6—N1—Er1	58.9 (3)	N12—C19—H19B	109.5
O10—N2—O8	122.1 (7)	H19A—C19—H19B	109.5
O10—N2—O9	121.8 (7)	N12—C19—H19C	109.5
O8—N2—O9	116.1 (6)	H19A—C19—H19C	109.5
O10—N2—Er1	175.5 (6)	H19B—C19—H19C	109.5
O8—N2—Er1	58.9 (3)	N12—C20—H20A	109.5
O9—N2—Er1	57.4 (3)	N12—C20—H20B	109.5
C2—N3—C1	113.8 (7)	H20A—C20—H20B	109.5
C2—N3—P1	120.0 (5)	N12—C20—H20C	109.5
C1—N3—P1	120.3 (5)	H20A—C20—H20C	109.5
C3—N4—C4	111.1 (8)	H20B—C20—H20C	109.5
C3—N4—P1	123.9 (6)	N13—C21—H21A	109.5
C4—N4—P1	120.3 (6)	N13—C21—H21B	109.5
C5—N5—C6	114.7 (7)	H21A—C21—H21B	109.5
C5—N5—P1	120.9 (6)	N13—C21—H21C	109.5
C6—N5—P1	120.1 (6)	H21A—C21—H21C	109.5
C7—N6—C8	114.2 (7)	H21B—C21—H21C	109.5
C7—N6—P2	125.5 (6)	N13—C22—H22A	109.5
C8—N6—P2	119.5 (6)	N13—C22—H22B	109.5
C9—N7—C10	114.0 (6)	H22A—C22—H22B	109.5
C9—N7—P2	122.9 (5)	N13—C22—H22C	109.5
C10—N7—P2	119.7 (5)	H22A—C22—H22C	109.5
C12—N8—C11	114.8 (8)	H22B—C22—H22C	109.5
C12—N8—P2	120.0 (7)	N14—C23—H23A	109.5
C11—N8—P2	124.3 (7)	N14—C23—H23B	109.5
C13—N9—C14	111.5 (8)	H23A—C23—H23B	109.5
C13—N9—P3	122.7 (6)	N14—C23—H23C	109.5
C14—N9—P3	124.9 (8)	H23A—C23—H23C	109.5
C15—N10—C16	115.1 (7)	H23B—C23—H23C	109.5
C15—N10—P3	119.7 (6)	N14—C24—H24A	109.5
C16—N10—P3	123.4 (7)	N14—C24—H24B	109.5
C17—N11—C18	116.6 (9)	H24A—C24—H24B	109.5
C17—N11—P3	120.2 (7)	N14—C24—H24C	109.5
C18—N11—P3	123.2 (9)	H24A—C24—H24C	109.5
C19—N12—C20	113.0 (6)	H24B—C24—H24C	109.5
C19—N12—P4	122.5 (5)	S4—W1—S1	108.17 (7)
C20—N12—P4	121.3 (5)	S4—W1—S3	109.83 (8)
C21—N13—C22	112.4 (8)	S1—W1—S3	108.72 (7)
C21—N13—P4	124.0 (7)	S4—W1—S2	108.30 (8)
C22—N13—P4	120.7 (7)	S1—W1—S2	113.32 (7)
C23—N14—C24	112.4 (8)	S3—W1—S2	108.46 (8)
C23—N14—P4	118.9 (6)	S4—W1—Ag1	125.65 (6)
C24—N14—P4	120.7 (6)	S1—W1—Ag1	57.64 (5)
N3—C1—H1A	109.5	S3—W1—Ag1	124.50 (6)
N3—C1—H1B	109.5	S2—W1—Ag1	55.69 (5)
H1A—C1—H1B	109.5	S4—W1—Ag1i	58.79 (6)
N3—C1—H1C	109.5	S1—W1—Ag1i	148.81 (5)
H1A—C1—H1C	109.5	S3—W1—Ag1i	58.66 (5)
H1B—C1—H1C	109.5	S2—W1—Ag1i	97.87 (5)
N3—C2—H2A	109.5	Ag1—W1—Ag1i	153.548 (12)
N3—C2—H2B	109.5	S2—Ag1—S1	93.51 (6)
H2A—C2—H2B	109.5	S2—Ag1—S3ii	121.31 (7)
N3—C2—H2C	109.5	S1—Ag1—S3ii	119.92 (6)
H2A—C2—H2C	109.5	S2—Ag1—S4ii	120.66 (7)
H2B—C2—H2C	109.5	S1—Ag1—S4ii	117.59 (7)
N4—C3—H3A	109.5	S3ii—Ag1—S4ii	86.67 (6)
N4—C3—H3B	109.5	S2—Ag1—W1	47.03 (5)
H3A—C3—H3B	109.5	S1—Ag1—W1	46.49 (4)
N4—C3—H3C	109.5	S3ii—Ag1—W1	137.34 (5)
H3A—C3—H3C	109.5	S4ii—Ag1—W1	135.90 (5)
H3B—C3—H3C	109.5	S2—Ag1—W1ii	151.57 (5)
N4—C4—H4A	109.5	S1—Ag1—W1ii	114.89 (5)
N4—C4—H4B	109.5	S3ii—Ag1—W1ii	45.95 (5)
H4A—C4—H4B	109.5	S4ii—Ag1—W1ii	45.63 (4)
N4—C4—H4C	109.5	W1—Ag1—W1ii	161.37 (2)
H4A—C4—H4C	109.5	W1—S1—Ag1	75.87 (6)
H4B—C4—H4C	109.5	W1—S2—Ag1	77.28 (6)
N5—C5—H5A	109.5	W1—S3—Ag1i	75.39 (6)
N5—C5—H5B	109.5	W1—S4—Ag1i	75.59 (6)
H5A—C5—H5B	109.5