catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos-phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polymeric chains via W-S-Ag bridges having a [AgS(4)W] repeat unit; the W-Ag-W and Ag-W-Ag angles are 161.657 (17) and 153.978 (9)°, respectively. The title complex is isostructural with the Y, Yb, Eu, Nd, La and Dy isomorphs.

Related literature

For one-dimensional Mo(W)/S/Ag anionic polymers and their properties, see: Niu et al. (2004 ▶); Zhang, Song & Wang (2007 ▶). For the structure of isotypic Y, Yb, Eu, Nd, La and Dy complexes, see: Zhang, Cao et al. (2007 ▶); Zhang (2011 ▶); Cao et al. (2007 ▶); Zhang, Qian et al. (2007 ▶); Tang, Zhang & Zhang (2008 ▶); Tang, Zhang, Zhang & Lu (2008 ▶); Zhang (2010 ▶).

Experimental

Crystal data

[Sm(NO3)2(C6H18N3OP)4][AgS4W]

M = 1411.19

Monoclinic,

a = 15.817 (3) Å

b = 29.768 (6) Å

c = 11.372 (2) Å

β = 91.03 (3)°

V = 5353.5 (18) Å3

Z = 4

Mo Kα radiation

μ = 3.92 mm−1

T = 293 K

0.2 × 0.16 × 0.1 mm

Data collection

Rigaku Saturn724+ diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2007 ▶) T min = 0.476, T max = 0.676

24655 measured reflections

9738 independent reflections

9057 reflections with I > 2σ(I)

R int = 0.022

Standard reflections: 0

Refinement

R[F 2 > 2σ(F 2)] = 0.031

wR(F 2) = 0.078

S = 1.03

9738 reflections

532 parameters

H-atom parameters constrained

Δρmax = 1.16 e Å−3

Δρmin = −1.06 e Å−3

Data collection: CrystalClear (Rigaku, 2007 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536811035574/rz2631sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811035574/rz2631Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Sm(NO3)2(C6H18N3OP)4][AgS4W]	F(000) = 2804.0
Mr = 1411.19	Dx = 1.751 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 22427 reflections
a = 15.817 (3) Å	θ = 3.0–29.1°
b = 29.768 (6) Å	µ = 3.92 mm−1
c = 11.372 (2) Å	T = 293 K
β = 91.03 (3)°	Block, orange
V = 5353.5 (18) Å3	0.2 × 0.16 × 0.1 mm
Z = 4

Rigaku Saturn724+ diffractometer	9738 independent reflections
Radiation source: fine-focus sealed tube	9057 reflections with I > 2σ(I)
graphite	Rint = 0.022
dtprofit.ref scans	θmax = 25.4°, θmin = 3.0°
Absorption correction: multi-scan (CrystalClear; Rigaku, 2007)	h = −19→14
Tmin = 0.476, Tmax = 0.676	k = −35→35
24655 measured reflections	l = −13→12

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.031	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.078	H-atom parameters constrained
S = 1.03	w = 1/[σ2(Fo2) + (0.0345P)2 + 16.4718P] where P = (Fo2 + 2Fc2)/3
9738 reflections	(Δ/σ)max = 0.001
532 parameters	Δρmax = 1.16 e Å−3
0 restraints	Δρmin = −1.06 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Sm1	0.737078 (14)	0.082698 (7)	0.82970 (2)	0.02352 (7)
P1	0.69501 (9)	−0.03068 (4)	0.69384 (12)	0.0347 (3)
P2	0.51916 (8)	0.13456 (4)	0.82656 (11)	0.0288 (3)
P3	0.79653 (11)	0.14726 (5)	1.10222 (14)	0.0467 (4)
P4	0.96063 (8)	0.09563 (4)	0.73301 (13)	0.0335 (3)
O1	0.7061 (2)	0.01700 (11)	0.7267 (3)	0.0348 (8)
O2	0.59965 (19)	0.10824 (11)	0.8257 (3)	0.0311 (8)
O3	0.7729 (2)	0.12756 (11)	0.9874 (3)	0.0366 (8)
O4	0.8783 (2)	0.08027 (11)	0.7821 (3)	0.0364 (8)
O5	0.7995 (2)	0.02572 (12)	0.9719 (3)	0.0395 (9)
O6	0.6671 (2)	0.04009 (12)	0.9942 (3)	0.0368 (8)
O7	0.7350 (3)	0.00096 (15)	1.1273 (4)	0.0596 (12)
O8	0.7511 (2)	0.15923 (11)	0.7355 (3)	0.0396 (9)
O9	0.7221 (2)	0.10477 (12)	0.6171 (3)	0.0396 (9)
O10	0.7223 (4)	0.17283 (16)	0.5515 (4)	0.0772 (16)
N1	0.7339 (3)	0.02158 (14)	1.0343 (4)	0.0376 (10)
N2	0.7320 (3)	0.14657 (15)	0.6320 (4)	0.0423 (11)
N3	0.7169 (3)	−0.03673 (15)	0.5547 (4)	0.0448 (12)
N4	0.7591 (4)	−0.06646 (16)	0.7605 (5)	0.0589 (15)
N5	0.6019 (4)	−0.0476 (2)	0.7318 (6)	0.0703 (18)
N6	0.4419 (2)	0.09986 (15)	0.8524 (4)	0.0338 (10)
N7	0.5222 (3)	0.17346 (16)	0.9285 (5)	0.0464 (12)
N8	0.5024 (3)	0.15940 (18)	0.7019 (4)	0.0485 (12)
N9	0.8986 (5)	0.1380 (2)	1.1266 (7)	0.090 (2)
N10	0.7788 (5)	0.19980 (17)	1.1016 (5)	0.0719 (19)
N11	0.7432 (6)	0.1236 (2)	1.2050 (5)	0.089 (2)
N12	1.0359 (3)	0.07061 (17)	0.8063 (5)	0.0503 (13)
N13	0.9587 (3)	0.0852 (2)	0.5901 (5)	0.0572 (14)
N14	0.9844 (3)	0.14859 (16)	0.7372 (5)	0.0534 (14)
C1	0.7225 (5)	−0.0823 (2)	0.5013 (6)	0.067 (2)
H1A	0.7358	−0.0796	0.4196	0.101*
H1B	0.6693	−0.0975	0.5087	0.101*
H1C	0.7659	−0.0993	0.5411	0.101*
C2	0.6989 (5)	−0.0014 (2)	0.4712 (6)	0.0655 (19)
H2A	0.7162	−0.0107	0.3944	0.098*
H2B	0.7293	0.0253	0.4939	0.098*
H2C	0.6393	0.0048	0.4697	0.098*
C3	0.7518 (7)	−0.0816 (3)	0.8757 (8)	0.101 (3)
H3A	0.7976	−0.1017	0.8942	0.152*
H3B	0.6990	−0.0971	0.8839	0.152*
H3C	0.7538	−0.0564	0.9284	0.152*
C4	0.8489 (6)	−0.0704 (3)	0.7282 (9)	0.107 (3)
H4A	0.8761	−0.0926	0.7770	0.161*
H4B	0.8765	−0.0419	0.7395	0.161*
H4C	0.8525	−0.0791	0.6472	0.161*
C5	0.5332 (4)	−0.0162 (3)	0.7495 (7)	0.070 (2)
H5A	0.4831	−0.0325	0.7701	0.105*
H5B	0.5227	0.0004	0.6784	0.105*
H5C	0.5482	0.0042	0.8118	0.105*
C6	0.5771 (6)	−0.0950 (3)	0.7156 (8)	0.107 (4)
H6A	0.5200	−0.0991	0.7408	0.160*
H6B	0.6142	−0.1139	0.7615	0.160*
H6C	0.5809	−0.1029	0.6341	0.160*
C7	0.3539 (3)	0.1094 (2)	0.8175 (5)	0.0477 (15)
H7A	0.3184	0.0849	0.8408	0.072*
H7B	0.3500	0.1131	0.7337	0.072*
H7C	0.3357	0.1365	0.8551	0.072*
C8	0.4516 (4)	0.0658 (2)	0.9449 (5)	0.0459 (14)
H8A	0.4009	0.0483	0.9490	0.069*
H8B	0.4620	0.0804	1.0191	0.069*
H8C	0.4984	0.0466	0.9273	0.069*
C9	0.4536 (4)	0.1839 (2)	1.0070 (6)	0.0572 (17)
H9A	0.4703	0.2080	1.0585	0.086*
H9B	0.4404	0.1578	1.0529	0.086*
H9C	0.4046	0.1927	0.9617	0.086*
C10	0.5905 (4)	0.2073 (2)	0.9267 (7)	0.0650 (19)
H10A	0.5838	0.2278	0.9910	0.098*
H10B	0.5876	0.2236	0.8538	0.098*
H10C	0.6443	0.1926	0.9341	0.098*
C11	0.5143 (5)	0.1364 (3)	0.5944 (6)	0.079 (2)
H11A	0.5015	0.1562	0.5299	0.118*
H11B	0.4774	0.1108	0.5906	0.118*
H11C	0.5719	0.1266	0.5899	0.118*
C12	0.4619 (5)	0.2038 (3)	0.6899 (8)	0.084 (3)
H12A	0.4582	0.2119	0.6082	0.125*
H12B	0.4949	0.2258	0.7319	0.125*
H12C	0.4061	0.2026	0.7217	0.125*
C13	0.9369 (5)	0.0953 (3)	1.1123 (9)	0.096 (3)
H13A	0.9958	0.0972	1.1340	0.144*
H13B	0.9314	0.0861	1.0316	0.144*
H13C	0.9096	0.0737	1.1616	0.144*
C14	0.9560 (7)	0.1710 (4)	1.1831 (10)	0.135 (5)
H14A	1.0115	0.1583	1.1913	0.202*
H14B	0.9352	0.1787	1.2594	0.202*
H14C	0.9584	0.1976	1.1355	0.202*
C15	0.8064 (5)	0.22735 (19)	1.0012 (6)	0.0614 (19)
H15A	0.7914	0.2582	1.0144	0.092*
H15B	0.7790	0.2169	0.9304	0.092*
H15C	0.8666	0.2249	0.9938	0.092*
C16	0.7532 (8)	0.2255 (3)	1.2080 (7)	0.122 (5)
H16A	0.7462	0.2566	1.1880	0.183*
H16B	0.7961	0.2226	1.2683	0.183*
H16C	0.7008	0.2138	1.2362	0.183*
C17	0.6521 (6)	0.1215 (3)	1.1937 (8)	0.099 (3)
H17A	0.6295	0.1070	1.2617	0.149*
H17B	0.6367	0.1047	1.1245	0.149*
H17C	0.6295	0.1513	1.1874	0.149*
C18	0.7897 (10)	0.1068 (4)	1.3136 (8)	0.168 (7)
H18A	0.7500	0.0942	1.3673	0.252*
H18B	0.8191	0.1313	1.3509	0.252*
H18C	0.8297	0.0841	1.2916	0.252*
C19	1.0227 (4)	0.0278 (2)	0.8622 (7)	0.072 (2)
H19A	1.0740	0.0184	0.9012	0.108*
H19B	1.0067	0.0059	0.8038	0.108*
H19C	0.9786	0.0305	0.9187	0.108*
C20	1.1249 (4)	0.0812 (3)	0.7889 (8)	0.092 (3)
H20A	1.1594	0.0631	0.8405	0.139*
H20B	1.1346	0.1124	0.8059	0.139*
H20C	1.1393	0.0752	0.7088	0.139*
C21	0.9098 (4)	0.0469 (3)	0.5462 (7)	0.072 (2)
H21A	0.9144	0.0451	0.4623	0.108*
H21B	0.8515	0.0507	0.5662	0.108*
H21C	0.9312	0.0198	0.5813	0.108*
C22	1.0333 (5)	0.0942 (4)	0.5197 (7)	0.093 (3)
H22A	1.0216	0.0862	0.4392	0.140*
H22B	1.0801	0.0767	0.5492	0.140*
H22C	1.0472	0.1255	0.5244	0.140*
C23	0.9529 (5)	0.1811 (3)	0.6518 (9)	0.094 (3)
H23A	0.9749	0.2103	0.6708	0.141*
H23B	0.8922	0.1818	0.6535	0.141*
H23C	0.9706	0.1726	0.5746	0.141*
C24	1.0127 (6)	0.1689 (3)	0.8474 (8)	0.099 (3)
H24A	1.0242	0.2002	0.8351	0.149*
H24B	1.0633	0.1541	0.8750	0.149*
H24C	0.9694	0.1657	0.9049	0.149*
W1	0.214355 (12)	0.272009 (6)	−0.022422 (15)	0.02289 (6)
Ag1	0.21554 (3)	0.234663 (14)	0.21751 (3)	0.04033 (11)
S1	0.21500 (10)	0.19943 (4)	0.01873 (11)	0.0386 (3)
S2	0.21225 (9)	0.31505 (4)	0.13519 (11)	0.0332 (3)
S3	0.10070 (9)	0.28668 (5)	−0.12896 (12)	0.0397 (3)
S4	0.32849 (8)	0.28805 (5)	−0.12238 (11)	0.0397 (3)

	U11	U22	U33	U12	U13	U23
Sm1	0.01783 (12)	0.01705 (12)	0.03568 (14)	0.00005 (9)	0.00088 (10)	0.00038 (10)
P1	0.0428 (8)	0.0251 (6)	0.0365 (7)	−0.0083 (6)	0.0102 (6)	−0.0077 (6)
P2	0.0202 (6)	0.0330 (7)	0.0333 (7)	0.0051 (5)	−0.0012 (5)	0.0043 (6)
P3	0.0650 (11)	0.0349 (8)	0.0395 (8)	−0.0128 (7)	−0.0210 (7)	0.0034 (7)
P4	0.0202 (6)	0.0308 (7)	0.0497 (8)	−0.0007 (5)	0.0042 (6)	0.0067 (6)
O1	0.038 (2)	0.0229 (17)	0.044 (2)	−0.0018 (15)	−0.0006 (16)	−0.0052 (16)
O2	0.0195 (17)	0.0330 (18)	0.0407 (19)	0.0057 (14)	−0.0002 (14)	−0.0011 (16)
O3	0.034 (2)	0.0316 (19)	0.044 (2)	−0.0028 (15)	−0.0102 (16)	−0.0045 (16)
O4	0.0193 (17)	0.0331 (19)	0.057 (2)	−0.0005 (14)	0.0044 (16)	0.0074 (17)
O5	0.0250 (19)	0.0344 (19)	0.059 (2)	−0.0006 (15)	−0.0022 (17)	0.0104 (18)
O6	0.0261 (19)	0.0362 (19)	0.048 (2)	−0.0016 (15)	−0.0019 (16)	0.0101 (17)
O7	0.058 (3)	0.064 (3)	0.057 (3)	−0.004 (2)	−0.008 (2)	0.031 (2)
O8	0.041 (2)	0.0272 (18)	0.051 (2)	−0.0057 (16)	−0.0033 (18)	0.0028 (17)
O9	0.046 (2)	0.0301 (19)	0.042 (2)	−0.0039 (16)	0.0071 (17)	0.0024 (17)
O10	0.120 (5)	0.050 (3)	0.060 (3)	−0.025 (3)	−0.013 (3)	0.034 (2)
N1	0.039 (3)	0.027 (2)	0.046 (3)	−0.0047 (19)	−0.007 (2)	0.007 (2)
N2	0.039 (3)	0.038 (3)	0.051 (3)	−0.007 (2)	0.002 (2)	0.015 (2)
N3	0.061 (3)	0.038 (3)	0.036 (2)	−0.011 (2)	0.009 (2)	−0.010 (2)
N4	0.092 (4)	0.027 (2)	0.058 (3)	0.009 (3)	0.021 (3)	0.007 (2)
N5	0.058 (4)	0.066 (4)	0.088 (4)	−0.031 (3)	0.034 (3)	−0.040 (3)
N6	0.020 (2)	0.043 (2)	0.039 (2)	0.0006 (18)	−0.0016 (18)	0.002 (2)
N7	0.037 (3)	0.042 (3)	0.061 (3)	0.006 (2)	0.006 (2)	−0.009 (2)
N8	0.034 (3)	0.070 (3)	0.041 (3)	−0.002 (2)	−0.007 (2)	0.023 (3)
N9	0.097 (5)	0.057 (4)	0.113 (6)	−0.015 (4)	−0.066 (4)	−0.008 (4)
N10	0.136 (6)	0.035 (3)	0.044 (3)	−0.009 (3)	0.006 (3)	−0.009 (3)
N11	0.149 (7)	0.069 (4)	0.051 (4)	−0.040 (5)	−0.003 (4)	0.004 (3)
N12	0.022 (2)	0.062 (3)	0.067 (3)	0.003 (2)	0.004 (2)	0.040 (3)
N13	0.037 (3)	0.083 (4)	0.052 (3)	−0.012 (3)	0.004 (2)	0.013 (3)
N14	0.035 (3)	0.040 (3)	0.085 (4)	−0.002 (2)	0.014 (3)	0.011 (3)
C1	0.090 (6)	0.053 (4)	0.059 (4)	−0.013 (4)	0.025 (4)	−0.026 (3)
C2	0.087 (5)	0.067 (5)	0.042 (4)	0.001 (4)	−0.007 (3)	−0.001 (3)
C3	0.128 (8)	0.080 (6)	0.097 (7)	0.047 (6)	0.018 (6)	0.027 (5)
C4	0.074 (6)	0.118 (8)	0.131 (9)	0.032 (6)	0.016 (6)	0.037 (7)
C5	0.039 (4)	0.074 (5)	0.097 (6)	−0.001 (3)	−0.005 (4)	0.017 (4)
C6	0.124 (8)	0.084 (6)	0.114 (7)	−0.069 (6)	0.062 (6)	−0.044 (6)
C7	0.023 (3)	0.071 (4)	0.049 (3)	0.000 (3)	−0.004 (2)	0.004 (3)
C8	0.036 (3)	0.053 (4)	0.049 (3)	0.004 (3)	0.008 (3)	0.012 (3)
C9	0.055 (4)	0.058 (4)	0.059 (4)	0.020 (3)	0.014 (3)	−0.014 (3)
C10	0.055 (4)	0.045 (4)	0.096 (6)	−0.006 (3)	0.013 (4)	−0.017 (4)
C11	0.064 (5)	0.132 (8)	0.040 (4)	−0.007 (5)	−0.010 (3)	−0.005 (4)
C12	0.064 (5)	0.078 (5)	0.109 (7)	0.017 (4)	−0.014 (5)	0.052 (5)
C13	0.066 (5)	0.075 (5)	0.144 (9)	−0.005 (4)	−0.054 (6)	0.022 (6)
C14	0.132 (10)	0.147 (10)	0.123 (9)	−0.068 (8)	−0.062 (7)	0.003 (8)
C15	0.102 (6)	0.030 (3)	0.052 (4)	−0.002 (3)	−0.001 (4)	−0.001 (3)
C16	0.246 (14)	0.060 (5)	0.061 (5)	−0.035 (7)	0.036 (7)	−0.039 (4)
C17	0.116 (8)	0.109 (7)	0.075 (6)	−0.042 (6)	0.045 (6)	−0.003 (5)
C18	0.303 (19)	0.158 (11)	0.043 (5)	0.075 (12)	0.014 (8)	0.035 (6)
C19	0.041 (4)	0.067 (5)	0.107 (6)	0.008 (3)	0.008 (4)	0.046 (4)
C20	0.029 (4)	0.124 (7)	0.124 (7)	0.003 (4)	0.005 (4)	0.075 (6)
C21	0.052 (4)	0.098 (6)	0.065 (5)	−0.004 (4)	0.004 (3)	−0.023 (4)
C22	0.061 (5)	0.160 (9)	0.060 (5)	−0.027 (5)	0.015 (4)	0.008 (5)
C23	0.053 (5)	0.057 (4)	0.174 (9)	0.010 (4)	0.020 (5)	0.060 (6)
C24	0.123 (8)	0.076 (6)	0.101 (7)	−0.049 (5)	0.037 (6)	−0.036 (5)
W1	0.02651 (11)	0.02400 (10)	0.01807 (10)	0.00269 (7)	−0.00193 (7)	−0.00178 (7)
Ag1	0.0602 (3)	0.0406 (2)	0.02010 (19)	0.00097 (19)	−0.00104 (18)	0.00200 (16)
S1	0.0613 (9)	0.0251 (6)	0.0294 (6)	0.0055 (6)	−0.0003 (6)	−0.0031 (5)
S2	0.0463 (8)	0.0273 (6)	0.0261 (6)	−0.0009 (5)	0.0009 (5)	−0.0064 (5)
S3	0.0315 (7)	0.0569 (9)	0.0306 (7)	0.0133 (6)	−0.0067 (5)	−0.0023 (6)
S4	0.0310 (7)	0.0575 (9)	0.0307 (7)	−0.0069 (6)	0.0018 (5)	−0.0040 (6)

Sm1—O3	2.298 (3)	C6—H6A	0.9600
Sm1—O2	2.303 (3)	C6—H6B	0.9600
Sm1—O4	2.309 (3)	C6—H6C	0.9600
Sm1—O1	2.328 (3)	C7—H7A	0.9600
Sm1—O9	2.512 (4)	C7—H7B	0.9600
Sm1—O8	2.529 (3)	C7—H7C	0.9600
Sm1—O6	2.531 (3)	C8—H8A	0.9600
Sm1—O5	2.532 (4)	C8—H8B	0.9600
Sm1—N2	2.944 (5)	C8—H8C	0.9600
Sm1—N1	2.954 (4)	C9—H9A	0.9600
P1—O1	1.477 (3)	C9—H9B	0.9600
P1—N5	1.622 (5)	C9—H9C	0.9600
P1—N3	1.635 (5)	C10—H10A	0.9600
P1—N4	1.646 (6)	C10—H10B	0.9600
P2—O2	1.495 (3)	C10—H10C	0.9600
P2—N8	1.616 (5)	C11—H11A	0.9600
P2—N6	1.631 (4)	C11—H11B	0.9600
P2—N7	1.639 (5)	C11—H11C	0.9600
P3—O3	1.474 (4)	C12—H12A	0.9600
P3—N10	1.589 (6)	C12—H12B	0.9600
P3—N11	1.615 (7)	C12—H12C	0.9600
P3—N9	1.656 (7)	C13—H13A	0.9600
P4—O4	1.498 (3)	C13—H13B	0.9600
P4—N14	1.621 (5)	C13—H13C	0.9600
P4—N12	1.622 (5)	C14—H14A	0.9600
P4—N13	1.654 (6)	C14—H14B	0.9600
O5—N1	1.274 (6)	C14—H14C	0.9600
O6—N1	1.269 (5)	C15—H15A	0.9600
O7—N1	1.223 (6)	C15—H15B	0.9600
O8—N2	1.268 (6)	C15—H15C	0.9600
O9—N2	1.265 (6)	C16—H16A	0.9600
O10—N2	1.211 (6)	C16—H16B	0.9600
N3—C2	1.443 (8)	C16—H16C	0.9600
N3—C1	1.491 (7)	C17—H17A	0.9600
N4—C3	1.391 (10)	C17—H17B	0.9600
N4—C4	1.479 (10)	C17—H17C	0.9600
N5—C5	1.450 (9)	C18—H18A	0.9600
N5—C6	1.475 (9)	C18—H18B	0.9600
N6—C8	1.467 (7)	C18—H18C	0.9600
N6—C7	1.469 (6)	C19—H19A	0.9600
N7—C9	1.452 (7)	C19—H19B	0.9600
N7—C10	1.477 (8)	C19—H19C	0.9600
N8—C11	1.417 (9)	C20—H20A	0.9600
N8—C12	1.473 (8)	C20—H20B	0.9600
N9—C13	1.418 (10)	C20—H20C	0.9600
N9—C14	1.479 (10)	C21—H21A	0.9600
N10—C15	1.477 (8)	C21—H21B	0.9600
N10—C16	1.494 (9)	C21—H21C	0.9600
N11—C17	1.446 (11)	C22—H22A	0.9600
N11—C18	1.512 (12)	C22—H22B	0.9600
N12—C19	1.441 (8)	C22—H22C	0.9600
N12—C20	1.460 (8)	C23—H23A	0.9600
N13—C21	1.462 (9)	C23—H23B	0.9600
N13—C22	1.462 (8)	C23—H23C	0.9600
N14—C23	1.453 (9)	C24—H24A	0.9600
N14—C24	1.454 (10)	C24—H24B	0.9600
C1—H1A	0.9600	C24—H24C	0.9600
C1—H1B	0.9600	W1—S3	2.1936 (14)
C1—H1C	0.9600	W1—S4	2.2030 (14)
C2—H2A	0.9600	W1—S2	2.2039 (12)
C2—H2B	0.9600	W1—S1	2.2105 (14)
C2—H2C	0.9600	W1—Ag1	2.9461 (6)
C3—H3A	0.9600	W1—Ag1i	2.9645 (7)
C3—H3B	0.9600	Ag1—S1	2.4918 (14)
C3—H3C	0.9600	Ag1—S2	2.5698 (14)
C4—H4A	0.9600	Ag1—S4ii	2.6167 (16)
C4—H4B	0.9600	Ag1—S3ii	2.6202 (16)
C4—H4C	0.9600	Ag1—W1ii	2.9645 (7)
C5—H5A	0.9600	S3—Ag1i	2.6202 (16)
C5—H5B	0.9600	S4—Ag1i	2.6167 (16)
C5—H5C	0.9600
O3—Sm1—O2	92.45 (12)	N5—C5—H5C	109.5
O3—Sm1—O4	88.58 (13)	H5A—C5—H5C	109.5
O2—Sm1—O4	157.31 (12)	H5B—C5—H5C	109.5
O3—Sm1—O1	158.08 (12)	N5—C6—H6A	109.5
O2—Sm1—O1	94.44 (12)	N5—C6—H6B	109.5
O4—Sm1—O1	92.95 (12)	H6A—C6—H6B	109.5
O3—Sm1—O9	128.05 (12)	N5—C6—H6C	109.5
O2—Sm1—O9	79.75 (12)	H6A—C6—H6C	109.5
O4—Sm1—O9	81.80 (13)	H6B—C6—H6C	109.5
O1—Sm1—O9	73.74 (12)	N6—C7—H7A	109.5
O3—Sm1—O8	77.56 (12)	N6—C7—H7B	109.5
O2—Sm1—O8	77.52 (12)	H7A—C7—H7B	109.5
O4—Sm1—O8	80.58 (12)	N6—C7—H7C	109.5
O1—Sm1—O8	124.27 (12)	H7A—C7—H7C	109.5
O9—Sm1—O8	50.53 (12)	H7B—C7—H7C	109.5
O3—Sm1—O6	79.60 (12)	N6—C8—H8A	109.5
O2—Sm1—O6	75.82 (12)	N6—C8—H8B	109.5
O4—Sm1—O6	126.53 (12)	H8A—C8—H8B	109.5
O1—Sm1—O6	81.97 (12)	N6—C8—H8C	109.5
O9—Sm1—O6	143.84 (12)	H8A—C8—H8C	109.5
O8—Sm1—O6	143.82 (12)	H8B—C8—H8C	109.5
O3—Sm1—O5	78.65 (12)	N7—C9—H9A	109.5
O2—Sm1—O5	126.25 (12)	N7—C9—H9B	109.5
O4—Sm1—O5	76.16 (12)	H9A—C9—H9B	109.5
O1—Sm1—O5	80.49 (12)	N7—C9—H9C	109.5
O9—Sm1—O5	144.96 (12)	H9A—C9—H9C	109.5
O8—Sm1—O5	146.92 (12)	H9B—C9—H9C	109.5
O6—Sm1—O5	50.43 (11)	N7—C10—H10A	109.5
O3—Sm1—N2	102.91 (13)	N7—C10—H10B	109.5
O2—Sm1—N2	76.03 (13)	H10A—C10—H10B	109.5
O4—Sm1—N2	81.64 (13)	N7—C10—H10C	109.5
O1—Sm1—N2	98.95 (13)	H10A—C10—H10C	109.5
O9—Sm1—N2	25.25 (12)	H10B—C10—H10C	109.5
O8—Sm1—N2	25.35 (12)	N8—C11—H11A	109.5
O6—Sm1—N2	151.82 (12)	N8—C11—H11B	109.5
O5—Sm1—N2	157.72 (12)	H11A—C11—H11B	109.5
O3—Sm1—N1	75.58 (12)	N8—C11—H11C	109.5
O2—Sm1—N1	100.93 (12)	H11A—C11—H11C	109.5
O4—Sm1—N1	101.28 (13)	H11B—C11—H11C	109.5
O1—Sm1—N1	82.68 (12)	N8—C12—H12A	109.5
O9—Sm1—N1	156.37 (12)	N8—C12—H12B	109.5
O8—Sm1—N1	153.01 (12)	H12A—C12—H12B	109.5
O6—Sm1—N1	25.26 (11)	N8—C12—H12C	109.5
O5—Sm1—N1	25.38 (12)	H12A—C12—H12C	109.5
N2—Sm1—N1	176.61 (13)	H12B—C12—H12C	109.5
O1—P1—N5	109.6 (3)	N9—C13—H13A	109.5
O1—P1—N3	108.9 (2)	N9—C13—H13B	109.5
N5—P1—N3	115.6 (3)	H13A—C13—H13B	109.5
O1—P1—N4	115.9 (3)	N9—C13—H13C	109.5
N5—P1—N4	103.3 (3)	H13A—C13—H13C	109.5
N3—P1—N4	103.6 (3)	H13B—C13—H13C	109.5
O2—P2—N8	111.1 (2)	N9—C14—H14A	109.5
O2—P2—N6	108.1 (2)	N9—C14—H14B	109.5
N8—P2—N6	109.6 (2)	H14A—C14—H14B	109.5
O2—P2—N7	111.1 (2)	N9—C14—H14C	109.5
N8—P2—N7	107.4 (3)	H14A—C14—H14C	109.5
N6—P2—N7	109.5 (2)	H14B—C14—H14C	109.5
O3—P3—N10	110.2 (3)	N10—C15—H15A	109.5
O3—P3—N11	109.9 (3)	N10—C15—H15B	109.5
N10—P3—N11	109.7 (4)	H15A—C15—H15B	109.5
O3—P3—N9	108.2 (3)	N10—C15—H15C	109.5
N10—P3—N9	109.7 (3)	H15A—C15—H15C	109.5
N11—P3—N9	109.1 (4)	H15B—C15—H15C	109.5
O4—P4—N14	119.3 (2)	N10—C16—H16A	109.5
O4—P4—N12	107.6 (2)	N10—C16—H16B	109.5
N14—P4—N12	105.3 (3)	H16A—C16—H16B	109.5
O4—P4—N13	108.0 (2)	N10—C16—H16C	109.5
N14—P4—N13	102.2 (3)	H16A—C16—H16C	109.5
N12—P4—N13	114.8 (3)	H16B—C16—H16C	109.5
P1—O1—Sm1	163.2 (2)	N11—C17—H17A	109.5
P2—O2—Sm1	167.6 (2)	N11—C17—H17B	109.5
P3—O3—Sm1	167.8 (2)	H17A—C17—H17B	109.5
P4—O4—Sm1	158.3 (2)	N11—C17—H17C	109.5
N1—O5—Sm1	96.2 (3)	H17A—C17—H17C	109.5
N1—O6—Sm1	96.4 (3)	H17B—C17—H17C	109.5
N2—O8—Sm1	96.0 (3)	N11—C18—H18A	109.5
N2—O9—Sm1	96.9 (3)	N11—C18—H18B	109.5
O7—N1—O6	121.9 (5)	H18A—C18—H18B	109.5
O7—N1—O5	122.1 (5)	N11—C18—H18C	109.5
O6—N1—O5	116.1 (4)	H18A—C18—H18C	109.5
O7—N1—Sm1	171.9 (4)	H18B—C18—H18C	109.5
O6—N1—Sm1	58.4 (2)	N12—C19—H19A	109.5
O5—N1—Sm1	58.4 (2)	N12—C19—H19B	109.5
O10—N2—O9	121.3 (5)	H19A—C19—H19B	109.5
O10—N2—O8	122.3 (5)	N12—C19—H19C	109.5
O9—N2—O8	116.3 (4)	H19A—C19—H19C	109.5
O10—N2—Sm1	174.3 (4)	H19B—C19—H19C	109.5
O9—N2—Sm1	57.9 (2)	N12—C20—H20A	109.5
O8—N2—Sm1	58.7 (2)	N12—C20—H20B	109.5
C2—N3—C1	114.1 (5)	H20A—C20—H20B	109.5
C2—N3—P1	120.9 (4)	N12—C20—H20C	109.5
C1—N3—P1	120.6 (4)	H20A—C20—H20C	109.5
C3—N4—C4	107.7 (7)	H20B—C20—H20C	109.5
C3—N4—P1	125.6 (5)	N13—C21—H21A	109.5
C4—N4—P1	121.5 (5)	N13—C21—H21B	109.5
C5—N5—C6	115.8 (6)	H21A—C21—H21B	109.5
C5—N5—P1	121.6 (5)	N13—C21—H21C	109.5
C6—N5—P1	120.3 (5)	H21A—C21—H21C	109.5
C8—N6—C7	114.5 (4)	H21B—C21—H21C	109.5
C8—N6—P2	119.8 (3)	N13—C22—H22A	109.5
C7—N6—P2	122.6 (4)	N13—C22—H22B	109.5
C9—N7—C10	114.7 (5)	H22A—C22—H22B	109.5
C9—N7—P2	125.0 (4)	N13—C22—H22C	109.5
C10—N7—P2	119.0 (4)	H22A—C22—H22C	109.5
C11—N8—C12	114.7 (6)	H22B—C22—H22C	109.5
C11—N8—P2	120.9 (5)	N14—C23—H23A	109.5
C12—N8—P2	123.8 (5)	N14—C23—H23B	109.5
C13—N9—C14	112.7 (8)	H23A—C23—H23B	109.5
C13—N9—P3	123.3 (5)	N14—C23—H23C	109.5
C14—N9—P3	123.4 (7)	H23A—C23—H23C	109.5
C15—N10—C16	115.5 (5)	H23B—C23—H23C	109.5
C15—N10—P3	119.7 (5)	N14—C24—H24A	109.5
C16—N10—P3	123.4 (5)	N14—C24—H24B	109.5
C17—N11—C18	121.9 (9)	H24A—C24—H24B	109.5
C17—N11—P3	119.2 (6)	N14—C24—H24C	109.5
C18—N11—P3	118.8 (8)	H24A—C24—H24C	109.5
C19—N12—C20	113.5 (5)	H24B—C24—H24C	109.5
C19—N12—P4	121.5 (4)	S3—W1—S4	110.05 (5)
C20—N12—P4	122.1 (4)	S3—W1—S2	108.01 (5)
C21—N13—C22	112.5 (6)	S4—W1—S2	108.55 (5)
C21—N13—P4	118.9 (4)	S3—W1—S1	108.19 (6)
C22—N13—P4	120.2 (5)	S4—W1—S1	108.69 (6)
C23—N14—C24	113.4 (7)	S2—W1—S1	113.33 (5)
C23—N14—P4	123.4 (5)	S3—W1—Ag1	125.32 (4)
C24—N14—P4	119.8 (5)	S4—W1—Ag1	124.62 (4)
N3—C1—H1A	109.5	S2—W1—Ag1	57.73 (4)
N3—C1—H1B	109.5	S1—W1—Ag1	55.61 (3)
H1A—C1—H1B	109.5	S3—W1—Ag1i	58.81 (4)
N3—C1—H1C	109.5	S4—W1—Ag1i	58.66 (4)
H1A—C1—H1C	109.5	S2—W1—Ag1i	148.29 (4)
H1B—C1—H1C	109.5	S1—W1—Ag1i	98.38 (3)
N3—C2—H2A	109.5	Ag1—W1—Ag1i	153.978 (9)
N3—C2—H2B	109.5	S1—Ag1—S2	93.54 (4)
H2A—C2—H2B	109.5	S1—Ag1—S4ii	120.91 (5)
N3—C2—H2C	109.5	S2—Ag1—S4ii	120.21 (5)
H2A—C2—H2C	109.5	S1—Ag1—S3ii	120.75 (5)
H2B—C2—H2C	109.5	S2—Ag1—S3ii	117.31 (5)
N4—C3—H3A	109.5	S4ii—Ag1—S3ii	86.93 (5)
N4—C3—H3B	109.5	S1—Ag1—W1	47.06 (3)
H3A—C3—H3B	109.5	S2—Ag1—W1	46.48 (3)
N4—C3—H3C	109.5	S4ii—Ag1—W1	137.29 (4)
H3A—C3—H3C	109.5	S3ii—Ag1—W1	135.70 (4)
H3B—C3—H3C	109.5	S1—Ag1—W1ii	151.26 (4)
N4—C4—H4A	109.5	S2—Ag1—W1ii	115.17 (3)
N4—C4—H4B	109.5	S4ii—Ag1—W1ii	45.97 (3)
H4A—C4—H4B	109.5	S3ii—Ag1—W1ii	45.74 (3)
N4—C4—H4C	109.5	W1—Ag1—W1ii	161.657 (17)
H4A—C4—H4C	109.5	W1—S1—Ag1	77.33 (4)
H4B—C4—H4C	109.5	W1—S2—Ag1	75.78 (4)
N5—C5—H5A	109.5	W1—S3—Ag1i	75.44 (4)
N5—C5—H5B	109.5	W1—S4—Ag1i	75.37 (4)
H5A—C5—H5B	109.5