(4'-Ethynyl-2,2':6',2''-terpyridine)(2,2':6',2''-terpyridine)-ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.

The title heteroleptic bis--terpyridine complex, [Ru(C(15)H(11)N(3))(C(17)H(11)N(3))](PF(6))(2)·2CH(3)CN, crystallized from an acetonitrile solution as a salt containing two hexa-fluoridophosphate counter-ions and two acetonitrile solvent mol-ecules. The Ru(II) atom has a distorted octa-hedral geometry due to the restricted bite angle [157.7 (3)°] of the two mer-arranged N,N',N''-tridendate ligands, viz. 2,2':6',2''-terpyridine (tpy) and 4'-ethynyl-2,2':6',2''-terpyridine (tpy'), which are essentially perpendicular to each other, with a dihedral angle of 87.75 (12)° between their terpyridyl planes. The rod-like acetyl-ene group lies in the same plane as its adjacent terpyridyl moiety, with a maximum deviation of only 0.071 (11) Å from coplanarity with the pyridine rings. The mean Ru-N bond length involving the outer N atoms trans to each other is 2.069 (6) Å at tpy and 2.070 (6) Å at tpy'. The Ru-N bond length involving the central N atom is 1.964 (6) Å at tpy and 1.967 (6) Å at tpy'. Two of the three counter anions were refined as half-occupied.

Related literature

For the crystal structure of a RuII–terpyridine complex containing the {Ru(tpy–C C)} fragment, see: Ruben et al. (2008 ▶). For a comparative discussion, see the Comment section in the Supplementary materials. For bond lengths and angles in related tpy complexes, see: Lashgari et al. (1999 ▶); Scudder et al. (2005 ▶). For the preparation of the starting materials, see: Benniston et al. (2005 ▶); Grosshenny et al. (1997 ▶); Sullivan et al. (1980 ▶); Ziessel et al. (2004 ▶). For general properties of this complex and related systems, see: Grosshenny et al. (1996 ▶); Hammarström & Johansson (2010 ▶); Ruther et al. (2011 ▶); Ziessel et al. (2004 ▶).

Experimental

Crystal data

[Ru(C15H11N3)(C17H11N3)](PF6)2·2C2H3N

M = 963.67

Triclinic,

a = 8.704 (2) Å

b = 8.860 (2) Å

c = 27.277 (7) Å

α = 96.876 (4)°

β = 95.619 (3)°

γ = 93.023 (3)°

V = 2073.9 (10) Å3

Z = 2

Mo Kα radiation

μ = 0.55 mm−1

T = 140 K

0.10 × 0.08 × 0.06 mm

Data collection

Bruker D8 with APEXII CCD diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2007 ▶) T min = 0.947, T max = 0.968

19870 measured reflections

7496 independent reflections

5137 reflections with I > 2σ(I)

R int = 0.081

Refinement

R[F 2 > 2σ(F 2)] = 0.084

wR(F 2) = 0.228

S = 1.25

7496 reflections

596 parameters

H-atom parameters constrained

Δρmax = 1.75 e Å−3

Δρmin = −0.94 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT-Plus (Bruker, 2007 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536812051227/sj5287sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812051227/sj5287Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Ru(C15H11N3)(C17H11N3)](PF6)2·2C2H3N	Z = 2
Mr = 963.67	F(000) = 964
Triclinic, P1	Dx = 1.543 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.704 (2) Å	Cell parameters from 1822 reflections
b = 8.860 (2) Å	θ = 4.7–41.0°
c = 27.277 (7) Å	µ = 0.55 mm−1
α = 96.876 (4)°	T = 140 K
β = 95.619 (3)°	Block, orange
γ = 93.023 (3)°	0.10 × 0.08 × 0.06 mm
V = 2073.9 (10) Å3

Bruker D8 with APEXII CCD diffractometer	7496 independent reflections
Radiation source: fine-focus sealed tube	5137 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.081
ω scans	θmax = 25.3°, θmin = 2.3°
Absorption correction: multi-scan (SADABS; Bruker, 2007)	h = −10→10
Tmin = 0.947, Tmax = 0.968	k = −10→10
19870 measured reflections	l = −32→32

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.084	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.228	H-atom parameters constrained
S = 1.25	w = 1/[σ2(Fo2) + (0.1P)2] where P = (Fo2 + 2Fc2)/3
7496 reflections	(Δ/σ)max < 0.001
596 parameters	Δρmax = 1.75 e Å−3
0 restraints	Δρmin = −0.94 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.Note: Two of the hexafluorophosphate anions had very large temperature factors when compared to the third. Other characterization by nuclear magnetic resonance, electronic absorption spectroscopy, and electrochemical techniques clearly support the oxidation state +2 for the Ru center. As a result, the two hexafluorophosphate anions were refined at one-half occupancy.

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.60446 (7)	0.66280 (7)	0.71976 (2)	0.0229 (2)
P1	0.5105 (3)	0.2494 (3)	0.86893 (9)	0.0406 (6)
P2	0.0665 (4)	0.3760 (5)	0.58567 (15)	0.0223 (9)	0.50
P3	0.3376 (7)	0.9331 (5)	0.52521 (18)	0.0460 (13)	0.50
F1	0.4111 (7)	0.3779 (7)	0.8487 (2)	0.0662 (17)
F2	0.3720 (7)	0.1889 (8)	0.8960 (2)	0.083 (2)
F3	0.6136 (8)	0.1235 (7)	0.8895 (3)	0.087 (2)
F4	0.6488 (6)	0.3082 (6)	0.8399 (2)	0.0627 (16)
F5	0.5731 (8)	0.3658 (7)	0.9169 (2)	0.080 (2)
F6	0.4524 (7)	0.1353 (6)	0.8207 (2)	0.0699 (18)
F7	0.2344 (13)	0.4242 (15)	0.5732 (4)	0.071 (4)	0.50
F8	0.0213 (12)	0.3542 (11)	0.5289 (3)	0.048 (3)	0.50
F9	−0.0984 (14)	0.3277 (16)	0.5993 (4)	0.074 (4)	0.50
F10	0.1149 (13)	0.3953 (11)	0.6387 (3)	0.048 (3)	0.50
F11	0.0255 (16)	0.5450 (15)	0.5929 (5)	0.086 (4)	0.50
F12	0.1067 (14)	0.2015 (14)	0.5798 (5)	0.078 (4)	0.50
F13	0.2819 (11)	0.7699 (11)	0.5355 (4)	0.052 (3)	0.50
F14	0.4594 (13)	0.9411 (12)	0.5740 (4)	0.055 (3)	0.50
F15	0.2102 (13)	0.9903 (13)	0.5575 (4)	0.061 (3)	0.50
F16	0.3906 (14)	1.1053 (11)	0.5201 (4)	0.051 (3)	0.50
F17	0.2281 (13)	0.9269 (11)	0.4820 (5)	0.066 (4)	0.50
F18	0.4732 (18)	0.8751 (13)	0.4927 (5)	0.080 (4)	0.50
N1	0.6951 (6)	0.8758 (7)	0.7100 (2)	0.0218 (14)
N2	0.6314 (7)	0.6327 (6)	0.6487 (2)	0.0223 (14)
N3	0.5163 (7)	0.4394 (7)	0.7002 (3)	0.0306 (16)
N4	0.8136 (7)	0.5925 (6)	0.7502 (2)	0.0212 (14)
N5	0.5824 (7)	0.6975 (6)	0.7912 (2)	0.0241 (14)
N6	0.3870 (7)	0.7435 (7)	0.7184 (3)	0.0273 (15)
N7	0.9608 (12)	−0.0287 (12)	0.8456 (4)	0.082 (3)
N8	0.0331 (14)	0.6614 (13)	0.9563 (4)	0.088 (3)
C1	0.7199 (8)	1.0006 (9)	0.7444 (3)	0.0273 (18)
H1	0.6942	0.9936	0.7764	0.033*
C2	0.7826 (9)	1.1392 (9)	0.7334 (3)	0.032 (2)
H2	0.7969	1.2236	0.7575	0.039*
C3	0.8230 (9)	1.1495 (8)	0.6865 (3)	0.032 (2)
H3	0.8692	1.2396	0.6788	0.039*
C4	0.7941 (9)	1.0242 (9)	0.6506 (3)	0.0291 (19)
H4	0.8165	1.0314	0.6183	0.035*
C5	0.7316 (8)	0.8874 (8)	0.6628 (3)	0.0234 (17)
C6	0.6973 (9)	0.7496 (9)	0.6277 (3)	0.0251 (17)
C7	0.7184 (11)	0.7255 (10)	0.5781 (3)	0.042 (2)
H7	0.7616	0.8050	0.5635	0.050*
C8	0.6785 (13)	0.5893 (11)	0.5496 (3)	0.056 (3)
H8	0.6959	0.5754	0.5163	0.067*
C9	0.6102 (12)	0.4699 (10)	0.5717 (3)	0.048 (3)
H9	0.5808	0.3758	0.5533	0.058*
C10	0.5881 (9)	0.4966 (8)	0.6215 (3)	0.0294 (19)
C11	0.5205 (9)	0.3899 (9)	0.6516 (3)	0.034 (2)
C12	0.4598 (11)	0.2427 (9)	0.6311 (4)	0.051 (3)
H12	0.4632	0.2099	0.5976	0.061*
C13	0.3950 (11)	0.1473 (10)	0.6612 (4)	0.061 (3)
H13	0.3528	0.0503	0.6484	0.073*
C14	0.3951 (10)	0.2002 (10)	0.7107 (4)	0.050 (3)
H14	0.3551	0.1369	0.7319	0.059*
C15	0.4541 (9)	0.3471 (9)	0.7297 (4)	0.038 (2)
H15	0.4505	0.3815	0.7631	0.046*
C16	0.9277 (8)	0.5350 (8)	0.7264 (3)	0.0251 (17)
H16	0.9201	0.5297	0.6920	0.030*
C17	1.0570 (9)	0.4828 (9)	0.7508 (3)	0.0312 (19)
H17	1.1334	0.4413	0.7328	0.037*
C18	1.0729 (9)	0.4920 (9)	0.8014 (3)	0.036 (2)
H18	1.1600	0.4586	0.8184	0.043*
C19	0.9558 (9)	0.5523 (9)	0.8265 (3)	0.033 (2)
H19	0.9635	0.5599	0.8610	0.040*
C20	0.8264 (8)	0.6019 (8)	0.8006 (3)	0.0252 (18)
C21	0.6948 (10)	0.6671 (9)	0.8251 (3)	0.0304 (19)
C22	0.6838 (11)	0.6954 (9)	0.8747 (3)	0.038 (2)
H22	0.7631	0.6723	0.8975	0.045*
C23	0.5526 (12)	0.7590 (9)	0.8908 (3)	0.041 (2)
C24	0.4340 (11)	0.7933 (9)	0.8559 (3)	0.041 (2)
H24	0.3463	0.8378	0.8662	0.049*
C25	0.4506 (9)	0.7593 (9)	0.8058 (3)	0.033 (2)
C26	0.3421 (9)	0.7893 (9)	0.7645 (3)	0.032 (2)
C27	0.2062 (9)	0.8608 (9)	0.7703 (4)	0.042 (2)
H27	0.1808	0.8962	0.8018	0.051*
C28	0.1083 (10)	0.8787 (10)	0.7282 (4)	0.053 (3)
H28	0.0161	0.9257	0.7312	0.063*
C29	0.1501 (9)	0.8255 (9)	0.6820 (4)	0.041 (2)
H29	0.0854	0.8357	0.6536	0.049*
C30	0.2887 (9)	0.7569 (9)	0.6782 (4)	0.035 (2)
H30	0.3144	0.7191	0.6470	0.042*
C31	0.5415 (13)	0.7943 (11)	0.9431 (4)	0.058 (3)
C32	0.5330 (16)	0.8213 (12)	0.9860 (4)	0.072 (4)
H32	0.5263	0.8427	1.0199	0.087*
C33	0.9607 (15)	0.0376 (19)	0.8804 (5)	0.104 (6)
C34	0.958 (2)	0.113 (4)	0.9314 (8)	0.36 (3)
H34A	0.8897	0.0544	0.9486	0.541*
H34B	0.9217	0.2132	0.9303	0.541*
H34C	1.0603	0.1207	0.9485	0.541*
C35	0.1365 (14)	0.5885 (14)	0.9648 (4)	0.063 (3)
C36	0.2593 (15)	0.4921 (15)	0.9767 (5)	0.084 (4)
H36A	0.3438	0.5523	0.9962	0.126*
H36B	0.2941	0.4450	0.9465	0.126*
H36C	0.2220	0.4148	0.9952	0.126*

	U11	U22	U33	U12	U13	U23
Ru1	0.0183 (3)	0.0179 (3)	0.0337 (4)	−0.0009 (2)	0.0022 (3)	0.0091 (3)
P1	0.0455 (14)	0.0296 (13)	0.0456 (15)	0.0006 (11)	−0.0040 (11)	0.0080 (11)
P2	0.0167 (19)	0.025 (2)	0.027 (2)	0.0045 (16)	0.0036 (16)	0.0105 (17)
P3	0.072 (4)	0.029 (3)	0.035 (3)	−0.003 (2)	0.010 (3)	−0.005 (2)
F1	0.055 (4)	0.064 (4)	0.086 (4)	0.028 (3)	0.006 (3)	0.025 (3)
F2	0.067 (4)	0.104 (6)	0.080 (5)	−0.027 (4)	0.019 (3)	0.029 (4)
F3	0.072 (5)	0.057 (4)	0.134 (6)	0.011 (3)	−0.018 (4)	0.044 (4)
F4	0.054 (4)	0.055 (4)	0.083 (4)	−0.006 (3)	0.013 (3)	0.021 (3)
F5	0.111 (6)	0.068 (4)	0.052 (4)	−0.030 (4)	−0.008 (4)	0.002 (3)
F6	0.092 (5)	0.045 (4)	0.065 (4)	−0.021 (3)	0.003 (3)	−0.007 (3)
F7	0.055 (8)	0.095 (10)	0.067 (8)	−0.012 (7)	−0.004 (6)	0.038 (7)
F8	0.076 (8)	0.055 (7)	0.009 (5)	−0.040 (6)	0.004 (4)	0.008 (4)
F9	0.062 (8)	0.101 (10)	0.077 (9)	0.020 (7)	0.026 (7)	0.056 (8)
F10	0.083 (8)	0.033 (6)	0.036 (6)	0.015 (5)	0.047 (5)	0.001 (4)
F11	0.085 (10)	0.062 (9)	0.099 (10)	0.021 (7)	−0.043 (8)	0.001 (7)
F12	0.067 (8)	0.060 (8)	0.098 (10)	0.021 (7)	−0.024 (7)	−0.008 (7)
F13	0.035 (6)	0.041 (6)	0.072 (8)	−0.027 (5)	0.016 (5)	−0.023 (5)
F14	0.073 (8)	0.049 (7)	0.047 (7)	0.030 (6)	0.006 (6)	0.006 (5)
F15	0.049 (7)	0.059 (8)	0.073 (8)	0.004 (6)	−0.006 (6)	0.013 (6)
F16	0.080 (9)	0.035 (6)	0.035 (6)	−0.021 (6)	−0.003 (6)	0.002 (5)
F17	0.060 (7)	0.020 (5)	0.109 (10)	−0.015 (5)	−0.032 (7)	0.019 (6)
F18	0.113 (12)	0.050 (8)	0.070 (9)	−0.029 (8)	0.033 (8)	−0.021 (6)
N1	0.014 (3)	0.018 (3)	0.034 (4)	0.006 (2)	−0.001 (3)	0.003 (3)
N2	0.017 (3)	0.013 (3)	0.036 (4)	−0.001 (2)	−0.008 (3)	0.008 (3)
N3	0.023 (4)	0.025 (4)	0.043 (4)	−0.009 (3)	−0.007 (3)	0.015 (3)
N4	0.019 (3)	0.011 (3)	0.032 (4)	−0.001 (2)	−0.002 (3)	0.001 (3)
N5	0.026 (3)	0.011 (3)	0.037 (4)	0.004 (3)	0.009 (3)	0.007 (3)
N6	0.015 (3)	0.020 (3)	0.048 (4)	−0.004 (3)	−0.001 (3)	0.012 (3)
N7	0.078 (7)	0.084 (8)	0.079 (8)	−0.020 (6)	0.031 (6)	−0.024 (6)
N8	0.096 (9)	0.098 (9)	0.065 (7)	0.019 (7)	−0.022 (6)	0.009 (6)
C1	0.022 (4)	0.022 (4)	0.036 (5)	0.003 (3)	0.002 (3)	0.000 (4)
C2	0.035 (5)	0.024 (5)	0.037 (5)	0.013 (4)	−0.002 (4)	0.001 (4)
C3	0.029 (4)	0.010 (4)	0.055 (6)	−0.004 (3)	−0.007 (4)	0.007 (4)
C4	0.025 (4)	0.028 (5)	0.036 (5)	−0.001 (3)	0.000 (4)	0.016 (4)
C5	0.020 (4)	0.021 (4)	0.030 (4)	0.003 (3)	0.004 (3)	0.004 (3)
C6	0.026 (4)	0.023 (4)	0.026 (4)	0.002 (3)	0.000 (3)	0.005 (3)
C7	0.063 (6)	0.024 (5)	0.039 (5)	−0.005 (4)	0.004 (5)	0.016 (4)
C8	0.100 (9)	0.043 (6)	0.022 (5)	0.004 (6)	−0.002 (5)	0.000 (4)
C9	0.080 (7)	0.021 (5)	0.037 (6)	−0.003 (5)	−0.023 (5)	0.003 (4)
C10	0.035 (5)	0.014 (4)	0.037 (5)	−0.003 (3)	−0.013 (4)	0.006 (3)
C11	0.030 (5)	0.014 (4)	0.057 (6)	−0.012 (3)	−0.015 (4)	0.018 (4)
C12	0.059 (6)	0.018 (5)	0.070 (7)	−0.007 (4)	−0.031 (5)	0.012 (4)
C13	0.056 (6)	0.024 (5)	0.096 (9)	−0.025 (5)	−0.045 (6)	0.035 (5)
C14	0.041 (6)	0.027 (5)	0.079 (8)	−0.015 (4)	−0.021 (5)	0.031 (5)
C15	0.017 (4)	0.033 (5)	0.066 (6)	−0.011 (4)	−0.010 (4)	0.027 (4)
C16	0.023 (4)	0.011 (4)	0.041 (5)	−0.005 (3)	0.006 (4)	0.003 (3)
C17	0.017 (4)	0.020 (4)	0.056 (6)	0.002 (3)	0.004 (4)	0.004 (4)
C18	0.018 (4)	0.029 (5)	0.059 (6)	0.005 (3)	−0.007 (4)	0.003 (4)
C19	0.037 (5)	0.028 (5)	0.033 (5)	0.005 (4)	−0.003 (4)	0.000 (4)
C20	0.021 (4)	0.013 (4)	0.043 (5)	0.000 (3)	−0.001 (4)	0.009 (3)
C21	0.038 (5)	0.024 (4)	0.028 (5)	−0.006 (4)	0.000 (4)	0.006 (3)
C22	0.052 (6)	0.027 (5)	0.035 (5)	−0.002 (4)	0.002 (4)	0.011 (4)
C23	0.071 (7)	0.020 (4)	0.036 (5)	0.000 (4)	0.019 (5)	0.006 (4)
C24	0.049 (6)	0.027 (5)	0.053 (6)	0.004 (4)	0.028 (5)	0.012 (4)
C25	0.028 (4)	0.021 (4)	0.053 (6)	0.001 (3)	0.015 (4)	0.010 (4)
C26	0.030 (4)	0.020 (4)	0.049 (5)	−0.004 (3)	0.015 (4)	0.013 (4)
C27	0.026 (5)	0.024 (5)	0.081 (7)	0.000 (4)	0.015 (5)	0.015 (5)
C28	0.024 (5)	0.030 (5)	0.111 (9)	0.003 (4)	0.017 (6)	0.025 (6)
C29	0.019 (4)	0.021 (5)	0.085 (7)	−0.008 (3)	−0.008 (5)	0.033 (5)
C30	0.026 (4)	0.015 (4)	0.066 (6)	−0.003 (3)	0.000 (4)	0.017 (4)
C31	0.083 (8)	0.039 (6)	0.058 (7)	0.019 (6)	0.028 (6)	0.011 (5)
C32	0.134 (12)	0.046 (7)	0.047 (7)	0.035 (7)	0.036 (7)	0.013 (5)
C33	0.055 (8)	0.147 (15)	0.089 (11)	0.011 (9)	−0.007 (7)	−0.058 (10)
C34	0.15 (2)	0.60 (6)	0.23 (3)	0.16 (3)	−0.099 (19)	−0.33 (3)
C35	0.072 (8)	0.077 (8)	0.036 (6)	0.026 (7)	−0.009 (5)	−0.003 (5)
C36	0.082 (10)	0.085 (10)	0.085 (9)	0.004 (8)	0.004 (7)	0.013 (7)

Ru1—N2	1.964 (6)	C8—C9	1.411 (13)
Ru1—N5	1.967 (6)	C9—C10	1.385 (12)
Ru1—N6	2.057 (6)	C10—C11	1.461 (11)
Ru1—N1	2.064 (6)	C11—C12	1.410 (11)
Ru1—N3	2.073 (6)	C12—C13	1.384 (13)
Ru1—N4	2.083 (6)	C13—C14	1.374 (14)
P1—F2	1.577 (6)	C14—C15	1.394 (12)
P1—F6	1.583 (6)	C16—C17	1.381 (10)
P1—F1	1.585 (6)	C17—C18	1.364 (11)
P1—F3	1.588 (6)	C18—C19	1.378 (11)
P1—F5	1.596 (6)	C19—C20	1.389 (11)
P1—F4	1.602 (6)	C20—C21	1.489 (11)
P2—F10	1.453 (11)	C21—C22	1.360 (11)
P2—F8	1.547 (9)	C22—C23	1.386 (12)
P2—F11	1.551 (13)	C23—C24	1.404 (13)
P2—F9	1.568 (12)	C23—C31	1.438 (13)
P2—F7	1.581 (12)	C24—C25	1.388 (11)
P2—F12	1.597 (12)	C25—C26	1.457 (12)
P3—F17	1.435 (12)	C26—C27	1.385 (11)
P3—F15	1.551 (13)	C27—C28	1.390 (13)
P3—F13	1.567 (11)	C28—C29	1.381 (13)
P3—F16	1.597 (11)	C29—C30	1.387 (11)
P3—F14	1.610 (12)	C31—C32	1.175 (13)
P3—F18	1.613 (15)	C33—C34	1.47 (2)
F16—F18i	1.278 (16)	C35—C36	1.439 (16)
F18—F16i	1.278 (16)	C1—H1	0.93
N1—C1	1.355 (9)	C2—H2	0.93
N1—C5	1.370 (9)	C3—H3	0.93
N2—C10	1.353 (9)	C4—H4	0.93
N2—C6	1.368 (9)	C7—H7	0.93
N3—C15	1.344 (10)	C8—H8	0.93
N3—C11	1.350 (10)	C9—H9	0.93
N4—C16	1.330 (9)	C12—H12	0.93
N4—C20	1.361 (9)	C13—H13	0.93
N5—C21	1.338 (10)	C14—H14	0.93
N5—C25	1.370 (10)	C15—H15	0.93
N6—C30	1.344 (10)	C16—H16	0.93
N6—C26	1.373 (10)	C17—H17	0.93
N7—C33	1.054 (13)	C18—H18	0.93
N8—C35	1.157 (14)	C19—H19	0.93
C1—C2	1.395 (11)	C22—H22	0.93
C2—C3	1.371 (11)	C24—H24	0.93
C3—C4	1.383 (11)	C27—H27	0.93
C4—C5	1.392 (10)	C28—H28	0.93
C5—C6	1.456 (10)	C29—H29	0.93
C6—C7	1.376 (11)	C30—H30	0.93
C7—C8	1.363 (12)	C32—H32	0.93
N2—Ru1—N5	178.3 (3)	N2—C6—C7	118.3 (7)
N2—Ru1—N6	101.3 (3)	N2—C6—C5	112.5 (6)
N5—Ru1—N6	79.4 (3)	C7—C6—C5	129.1 (7)
N2—Ru1—N1	79.0 (2)	C8—C7—C6	122.4 (8)
N5—Ru1—N1	99.5 (2)	C7—C8—C9	118.6 (9)
N6—Ru1—N1	89.9 (2)	C10—C9—C8	118.2 (8)
N2—Ru1—N3	78.8 (3)	N2—C10—C9	121.4 (7)
N5—Ru1—N3	102.6 (3)	N2—C10—C11	111.3 (7)
N6—Ru1—N3	92.4 (2)	C9—C10—C11	127.3 (7)
N1—Ru1—N3	157.7 (3)	N3—C11—C12	121.0 (8)
N2—Ru1—N4	100.9 (2)	N3—C11—C10	117.0 (7)
N5—Ru1—N4	78.3 (2)	C12—C11—C10	122.1 (9)
N6—Ru1—N4	157.7 (3)	C13—C12—C11	119.6 (10)
N1—Ru1—N4	94.5 (2)	C14—C13—C12	118.0 (9)
N3—Ru1—N4	91.7 (2)	C13—C14—C15	121.1 (9)
F2—P1—F6	90.3 (4)	N3—C15—C14	120.6 (9)
F2—P1—F1	91.5 (4)	N4—C16—C17	122.4 (8)
F6—P1—F1	90.6 (4)	C18—C17—C16	120.1 (8)
F2—P1—F3	89.5 (4)	C17—C18—C19	118.0 (8)
F6—P1—F3	90.3 (4)	C18—C19—C20	120.4 (8)
F1—P1—F3	178.7 (4)	N4—C20—C19	120.6 (7)
F2—P1—F5	91.2 (4)	N4—C20—C21	115.9 (6)
F6—P1—F5	178.4 (4)	C19—C20—C21	123.5 (7)
F1—P1—F5	89.4 (4)	N5—C21—C22	122.1 (8)
F3—P1—F5	89.7 (4)	N5—C21—C20	110.8 (7)
F2—P1—F4	178.3 (4)	C22—C21—C20	127.0 (8)
F6—P1—F4	88.0 (3)	C21—C22—C23	119.0 (8)
F1—P1—F4	88.2 (3)	C22—C23—C24	119.8 (8)
F3—P1—F4	90.8 (4)	C22—C23—C31	119.7 (9)
F5—P1—F4	90.4 (4)	C24—C23—C31	120.5 (9)
F10—P2—F8	177.8 (6)	C25—C24—C23	118.6 (8)
F10—P2—F11	86.5 (6)	N5—C25—C24	120.0 (8)
F8—P2—F11	94.6 (7)	N5—C25—C26	113.5 (7)
F10—P2—F9	86.5 (6)	C24—C25—C26	126.4 (8)
F8—P2—F9	95.4 (6)	N6—C26—C27	121.9 (8)
F11—P2—F9	89.2 (8)	N6—C26—C25	114.4 (7)
F10—P2—F7	92.1 (6)	C27—C26—C25	123.7 (8)
F8—P2—F7	85.9 (6)	C26—C27—C28	118.8 (9)
F11—P2—F7	91.1 (8)	C29—C28—C27	119.0 (8)
F9—P2—F7	178.6 (6)	C28—C29—C30	119.9 (9)
F10—P2—F12	92.2 (6)	N6—C30—C29	121.8 (9)
F8—P2—F12	86.8 (6)	C32—C31—C23	179.1 (11)
F11—P2—F12	178.3 (8)	N7—C33—C34	173 (2)
F9—P2—F12	89.6 (7)	N8—C35—C36	176.8 (15)
F7—P2—F12	90.1 (7)	N1—C1—H1	119
F17—P3—F15	88.9 (8)	C2—C1—H1	119
F17—P3—F13	92.5 (6)	C1—C2—H2	121
F15—P3—F13	85.6 (6)	C3—C2—H2	120
F17—P3—F16	90.7 (6)	C2—C3—H3	121
F15—P3—F16	89.8 (7)	C4—C3—H3	120
F13—P3—F16	174.3 (6)	C3—C4—H4	120
F17—P3—F14	179.5 (8)	C5—C4—H4	120
F15—P3—F14	90.6 (6)	C6—C7—H7	119
F13—P3—F14	87.7 (6)	C8—C7—H7	119
F16—P3—F14	89.1 (6)	C7—C8—H8	121
F17—P3—F18	92.4 (8)	C9—C8—H8	121
F15—P3—F18	178.6 (8)	C8—C9—H9	121
F13—P3—F18	94.8 (6)	C10—C9—H9	121
F16—P3—F18	89.8 (6)	C11—C12—H12	120
F14—P3—F18	88.1 (7)	C13—C12—H12	120
F18i—F16—P3	115.0 (10)	C12—C13—H13	121
F16i—F18—P3	149.8 (10)	C14—C13—H13	121
C1—N1—C5	118.6 (6)	C13—C14—H14	120
C1—N1—Ru1	127.3 (5)	C15—C14—H14	119
C5—N1—Ru1	114.1 (5)	N3—C15—H15	120
C10—N2—C6	121.0 (7)	C14—C15—H15	120
C10—N2—Ru1	119.9 (5)	N4—C16—H16	119
C6—N2—Ru1	119.1 (5)	C17—C16—H16	119
C15—N3—C11	119.8 (7)	C16—C17—H17	120
C15—N3—Ru1	127.2 (6)	C18—C17—H17	120
C11—N3—Ru1	113.0 (5)	C17—C18—H18	121
C16—N4—C20	118.5 (6)	C19—C18—H18	121
C16—N4—Ru1	127.9 (5)	C18—C19—H19	120
C20—N4—Ru1	113.5 (5)	C20—C19—H19	120
C21—N5—C25	120.5 (7)	C21—C22—H22	121
C21—N5—Ru1	121.4 (5)	C23—C22—H22	120
C25—N5—Ru1	118.1 (5)	C23—C24—H24	121
C30—N6—C26	118.4 (7)	C25—C24—H24	121
C30—N6—Ru1	127.3 (6)	C26—C27—H27	121
C26—N6—Ru1	114.4 (5)	C28—C27—H27	121
N1—C1—C2	122.2 (7)	C27—C28—H28	120
C3—C2—C1	119.2 (7)	C29—C28—H28	121
C2—C3—C4	119.2 (7)	C28—C29—H29	120
C3—C4—C5	120.3 (7)	C30—C29—H29	120
N1—C5—C4	120.6 (7)	N6—C30—H30	119
N1—C5—C6	115.2 (6)	C29—C30—H30	119
C4—C5—C6	124.2 (7)	C31—C32—H32	180