| Literature DB >> 21438578 |
Rose E Ruther1, Matthew L Rigsby, James B Gerken, Stephanie R Hogendoorn, Elizabeth C Landis, Shannon S Stahl, Robert J Hamers.
Abstract
We demonstrate a modular "click"-based functionalization scheme that allows inexpensive conductive diamond samples to serve as an ultrastable platform for surface-tethered electrochemically active molecules stable out to ∼1.3 V vs Ag/AgCl. We have cycled surface-tethered Ru(tpy)(2) to this potential more than 1 million times with little or no degradation in propylene carbonate and only slightly reduced stability in water and acetonitrile.Entities:
Year: 2011 PMID: 21438578 DOI: 10.1021/ja200210t
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419