| Literature DB >> 23373732 |
Sakuya Horii1, Munefumi Torihata, Tomohiro Nagasawa, Shigefumi Kuwahara.
Abstract
A highly stereoselective synthesis of the racemic oxatetracyclic core of platensimycin has been accomplished from a known bicyclic epoxy lactone by an 11-step sequence that involves a Diels-Alder cyclcoaddition to construct its cis-decalenone structural motif with complete regio- and stereoselectivity and a ring-closing metathesis to establish its whole carbon framework.Entities:
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Year: 2013 PMID： 23373732 DOI： 10.1021/jo302813y
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354