Literature DB >> 23361381

Kinetic trapping of the host-guest association intermediate and its transformation into a thermodynamic inclusion complex.

Oksana Danylyuk1, Vladimir P Fedin, Volodymyr Sashuk.   

Abstract

The molecular recognition and self-assembly between host cucurbit[6]uril and guest adrenaline led to kinetic trapping and crystallization of the intermediate exclusion complex, which was characterized by X-ray diffraction. The crystalline kinetic complex undergoes slow spontaneous dissolution and subsequently recrystallizes as a thermodynamic inclusion complex.

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Year:  2013        PMID: 23361381     DOI: 10.1039/c3cc37868c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  4 in total

1.  Directly Functionalized Cucurbit[7]uril as a Biosensor for the Selective Detection of Protein Interactions by 129 Xe hyperCEST NMR.

Authors:  Ashley E Truxal; Liping Cao; Lyle Isaacs; David E Wemmer; Alexander Pines
Journal:  Chemistry       Date:  2019-03-29       Impact factor: 5.236

2.  Rotaxane Probes for the Detection of Hydrogen Peroxide by 129 Xe HyperCEST NMR Spectroscopy.

Authors:  Sarah H Klass; Ashley E Truxal; Tahoe A Fiala; Joseph Kelly; Dang Nguyen; Joel A Finbloom; David E Wemmer; Alexander Pines; Matthew B Francis
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-11       Impact factor: 15.336

3.  Structural conversion of three copper(ii) complexes with snapshot observations based on the different crystal colours and morphology.

Authors:  Hao Su; Zhongkui Li; Junrui Tan; Hongwei Ma; Li Yan; Hui Li
Journal:  RSC Adv       Date:  2020-11-26       Impact factor: 4.036

4.  Nanoscale Control of Amyloid Self-Assembly Using Protein Phase Transfer by Host-Guest Chemistry.

Authors:  Tae Su Choi; Hong Hee Lee; Young Ho Ko; Kwang Seob Jeong; Kimoon Kim; Hugh I Kim
Journal:  Sci Rep       Date:  2017-07-18       Impact factor: 4.379

  4 in total

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