Literature DB >> 23355412

Copper-catalyzed intermolecular aminocyanation and diamination of alkenes.

Hongwei Zhang1, Weiya Pu, Tao Xiong, Yan Li, Xue Zhou, Kai Sun, Qun Liu, Qian Zhang.   

Abstract

'N' front and center: The facile construction of C-N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2013        PMID： 23355412     DOI： 10.1002/anie.201209142

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  28 in total

1.  Pd-catalyzed aryl C-H imidation with arene as the limiting reagent.

Authors:  Gregory B Boursalian; Ming-Yu Ngai; Katarzyna N Hojczyk; Tobias Ritter
Journal:  J Am Chem Soc       Date:  2013-09-03       Impact factor: 15.419

2.  Direct Access to Versatile Electrophiles via Catalytic Oxidative Cyanation of Alkenes.

Authors:  De-Wei Gao; Ekaterina V Vinogradova; Sri Krishna Nimmagadda; Jose M Medina; Yiyang Xiao; Radu M Suciu; Benjamin F Cravatt; Keary M Engle
Journal:  J Am Chem Soc       Date:  2018-06-22       Impact factor: 15.419

3.  Copper-promoted synthesis of 1,4-benzodiazepinones via alkene diamination.

Authors:  Shuklendu D Karyakarte; Fatima C Sequeira; Garrick H Zibreg; Guoqing Huang; Josiah P Matthew; Marina M M Ferreira; Sherry R Chemler
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

4.  Copper-Catalyzed Modular Amino Oxygenation of Alkenes: Access to Diverse 1,2-Amino Oxygen-Containing Skeletons.

Authors:  Brett N Hemric; Andy W Chen; Qiu Wang
Journal:  J Org Chem       Date:  2019-01-17       Impact factor: 4.354

5.  Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay.

Authors:  Wen Zhang; Fei Wang; Scott D McCann; Dinghai Wang; Pinhong Chen; Shannon S Stahl; Guosheng Liu
Journal:  Science       Date:  2016-09-02       Impact factor: 47.728

6.  Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration.

Authors:  Yungeun Kwon; Qiu Wang
Journal:  Org Lett       Date:  2020-05-08       Impact factor: 6.005

7.  Intramolecular aminocyanation of alkenes by N-CN bond cleavage.

Authors:  Zhongda Pan; Sarah M Pound; Naveen R Rondla; Christopher J Douglas
Journal:  Angew Chem Int Ed Engl       Date:  2014-04-09       Impact factor: 15.336

8.  Copper-Catalyzed Alkene Diamination: Synthesis of Chiral 2-Aminomethyl Indolines and Pyrrolidines.

Authors:  Benjamin W Turnpenny; Sherry R Chemler
Journal:  Chem Sci       Date:  2014-05-01       Impact factor: 9.825

9.  Copper-catalyzed oxidative amination and allylic amination of alkenes.

Authors:  Timothy W Liwosz; Sherry R Chemler
Journal:  Chemistry       Date:  2013-07-22       Impact factor: 5.236

10.  Cu(I)-catalyzed sequential diamination and dehydrogenation of terminal olefins: a facile approach to imidazolinones.

Authors:  Yingguang Zhu; Yian Shi
Journal:  Chemistry       Date:  2014-09-11       Impact factor: 5.236
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