'N' front and center: The facile construction of C-N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.
'N' front and center: The facile construction of C-n class="Chemical">N bonds by the generation of nitrogen-centred radicals from N-fluorobenzenesulfonimide results in the aminative difuctionalization of alkenes. The first copper-catalyzed intermolecular aminocyanation of alkenes and diamination of styrenes were realized. Si-F and B-F interactions play a significant role in the reaction.
Authors: De-Wei Gao; Ekaterina V Vinogradova; Sri Krishna Nimmagadda; Jose M Medina; Yiyang Xiao; Radu M Suciu; Benjamin F Cravatt; Keary M Engle Journal: J Am Chem Soc Date: 2018-06-22 Impact factor: 15.419
Authors: Shuklendu D Karyakarte; Fatima C Sequeira; Garrick H Zibreg; Guoqing Huang; Josiah P Matthew; Marina M M Ferreira; Sherry R Chemler Journal: Tetrahedron Lett Date: 2015-06-03 Impact factor: 2.415