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Literature DB >> 23252771

Metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts.

Abstract

An efficient, high-yielding, and transition-metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts has been developed. The mild reaction conditions tolerate a range of functional groups, and unsymmetrical diaryliodonium salts show high chemoselectivity.

Entities: Chemical

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Year: 2012 PMID： 23252771 DOI： 10.1021/ol303248h

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

13 in total

1. Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors: Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal: Chem Rev Date: 2019-06-25 Impact factor: 60.622

Review 2. Synthesis and applications of sodium sulfinates (RSO₂Na): a powerful building block for the synthesis of organosulfur compounds.

Authors: Raju Jannapu Reddy; Arram Haritha Kumari
Journal: RSC Adv Date: 2021-03-01 Impact factor: 3.361

3. An Aminative Rearrangement of O-(Arenesulfonyl)hydroxylamines: Facile Access to ortho-Sulfonyl Anilines.

Authors: Charlotte Morrill; James E Gillespie; Robert J Phipps
Journal: Angew Chem Int Ed Engl Date: 2022-07-07 Impact factor: 16.823

Review 4. Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

Authors: Shuai Liang; Kamil Hofman; Marius Friedrich; Julian Keller; Georg Manolikakes
Journal: ChemSusChem Date: 2021-10-13 Impact factor: 9.140

5. Alkyl Sulfinates: Formal Nucleophiles for Synthesizing TosMIC Analogs.

Authors: J Armando Lujan-Montelongo; Angel Ojeda Estevez; Fraser F Fleming
Journal: European J Org Chem Date: 2015-03

6. Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu^I/Cu^III Manifold in Copper Catalysis.

Authors: Naoko Ichiishi; Allan J Canty; Brian F Yates; Melanie S Sanford
Journal: Organometallics Date: 2014-09-22 Impact factor: 3.876

Metal-free synthesis of diaryl sulfones from arylsulfinic acid salts and diaryliodonium salts.

1. Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Review 2. Synthesis and applications of sodium sulfinates (RSO₂Na): a powerful building block for the synthesis of organosulfur compounds.

3. An Aminative Rearrangement of O-(Arenesulfonyl)hydroxylamines: Facile Access to ortho-Sulfonyl Anilines.

Review 4. Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

5. Alkyl Sulfinates: Formal Nucleophiles for Synthesizing TosMIC Analogs.

6. Mechanistic Investigations of Cu-Catalyzed Fluorination of Diaryliodonium Salts: Elaborating the Cu^I/Cu^III Manifold in Copper Catalysis.

7. Palladium-catalyzed three-component diaryl sulfone synthesis exploiting the sulfur dioxide surrogate DABSO.

8. One-pot, three-component arylalkynyl sulfone synthesis.

9. Catalyst-free arylation of sulfonamides via visible light-mediated deamination.

10. DABSO-based, three-component, one-pot sulfone synthesis.

Review 2. Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds.

Review 4. Recent Progress and Emerging Technologies towards a Sustainable Synthesis of Sulfones.

Review 2. Synthesis and applications of sodium sulfinates (RSO₂Na): a powerful building block for the synthesis of organosulfur compounds.