OBJECTIVES: The aim of this study was to formulate materials with high color stability and reduced degradation by using photoinitiator systems derived from phosphine oxides alternative to the traditional camphorquinone (CQ)/amine system. METHODS: Materials were formulated with the monomers BisGMA and TEGDMA as organic matrix. The photoinitiators tested were CQ+amine (EDMAB), phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO), BAPO+EDMAB, diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide (TPO) and TPO+EDMAB. A 60% mass of silanated glass filler particles was added. Degree of CC conversion was evaluated by Fourier-transformed infrared spectroscopy 10min after photopolymerization. The color properties were evaluated by a digital spectrophotometer, applying the CIELab parameters, either before photoactivation, immediately after photoactivation, 24h after dry storage, and one month after water immersion. Water sorption and solubility were assessed by mass gain or loss after storage in water for 30 days. Data were analyzed using ANOVA and Tukey's test (5%). RESULTS: Degree of conversion did not differ statistically among all the tested formulations. Regarding color, only groups with TPO presented satisfactory color stability after one month of water storage (ΔE<3.3). Water sorption and water stability did not differ among the groups. CONCLUSIONS: Degree of conversion, water sorption and water solubility did not differ among all the tested groups. The TPO-based groups were the only materials with satisfactory color stability after one month of water storage. CLINICAL SIGNIFICANCE: The use of a photoinitiator system containing TPO might improve the color stability of resin composites compared with the traditional CQ/amine system while attaining similar physico-chemical properties for the composite.
OBJECTIVES: The aim of this study was to formulate materials with high color stability and reduced degradation by using photoinitiator systems derived from phosphine oxides alternative to the traditional camphorquinone (CQ)/amine system. METHODS: Materials were formulated with the monomers BisGMA and TEGDMA as organic matrix. The photoinitiators tested were CQ+amine (EDMAB), phenylbis(2,4,6-trimethylbenzoyl)phosphine oxide (BAPO), BAPO+EDMAB, diphenyl(2,4,6-trimethylbenzoyl)-phosphine oxide (TPO) and TPO+EDMAB. A 60% mass of silanated glass filler particles was added. Degree of CC conversion was evaluated by Fourier-transformed infrared spectroscopy 10min after photopolymerization. The color properties were evaluated by a digital spectrophotometer, applying the CIELab parameters, either before photoactivation, immediately after photoactivation, 24h after dry storage, and one month after water immersion. Water sorption and solubility were assessed by mass gain or loss after storage in water for 30 days. Data were analyzed using ANOVA and Tukey's test (5%). RESULTS: Degree of conversion did not differ statistically among all the tested formulations. Regarding color, only groups with TPO presented satisfactory color stability after one month of water storage (ΔE<3.3). Water sorption and water stability did not differ among the groups. CONCLUSIONS: Degree of conversion, water sorption and water solubility did not differ among all the tested groups. The TPO-based groups were the only materials with satisfactory color stability after one month of water storage. CLINICAL SIGNIFICANCE: The use of a photoinitiator system containing TPO might improve the color stability of resin composites compared with the traditional CQ/amine system while attaining similar physico-chemical properties for the composite.
Authors: Mário Thadeo R Cruzeiro; Fernando A Moraes; Marina R Kaizer; Mário Lúcio Moreira; Yu Zhang; Rafael R Moraes; Sergio S Cava Journal: J Prosthet Dent Date: 2017-04-03 Impact factor: 3.426
Authors: Leina Nakanishi; Marina R Kaizer; Suzane Brandeburski; Sergio S Cava; Alvaro Della Bona; Yu Zhang; Rafael R Moraes Journal: Dent Mater Date: 2020-08-03 Impact factor: 5.304
Authors: Dayane Carvalho Ramos Salles de Oliveira; Eduardo José Souza-Junior; Adam Dobson; Ana Rosa Costa Correr; William Cunha Brandt; Mário Alexandre Coelho Sinhoreti Journal: J Appl Oral Sci Date: 2016 Nov-Dec Impact factor: 2.698
Authors: Carla Dos Reis Lima; Danilo Bandeira da Silva; Rafael Pino Vitti; Milton Edson Miranda; William Cunha Brandt Journal: Clin Cosmet Investig Dent Date: 2019-08-29
Authors: Louis A van der Elst; Merve Gokce Kurtoglu; Troy Leffel; Mengxin Zheng; Alexander Gumennik Journal: Adv Eng Mater Date: 2020-10-21 Impact factor: 4.122