Literature DB >> 23192306

6,6'-Dihydroxy terpyridine: a proton-responsive bifunctional ligand and its application in catalytic transfer hydrogenation of ketones.

Cameron M Moore1, Nathaniel K Szymczak.   

Abstract

The ligand 6,6'-dihydroxy terpyridine (dhtp) is presented as a bifunctional ligand capable of directing proton transfer events with metal-coordinated substrates. Solid-state analysis of a Ru(II)-dhtp complex reveals directed hydrogen-bonding interactions of the hydroxyl groups of dhtp with a Ru-bound chloride ligand. The utility of dhtp was demonstrated by chemoselective transfer hydrogenation of ketones.

Entities:  

Year:  2012        PMID： 23192306     DOI： 10.1039/c2cc36927c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  12 in total

1.  Terpyridine-metal complexes: Applications in catalysis and supramolecular chemistry.

Authors:  Chiyu Wei; Ying He; Xiaodong Shi; Zhiguang Song
Journal:  Coord Chem Rev       Date:  2019-01-28       Impact factor: 22.315

2.  Diiron Dithiolate Hydrides Complemented with Proton-Responsive Phosphine-Amine Ligands.

Authors:  Michaela R Carlson; Ryan Gilbert-Wilson; Danielle R Gray; Joyee Mitra; Thomas B Rauchfuss; Casseday P Richers
Journal:  Eur J Inorg Chem       Date:  2017-07-05       Impact factor: 2.524

3.  Hydrazine Capture and N-N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids.

Authors:  John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal:  J Am Chem Soc       Date:  2017-12-11       Impact factor: 15.419

4.  Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

Authors:  Deidra L Gerlach; Sopheavy Siek; Dalton B Burks; Jamie M Tesh; Courtney R Thompson; Robert M Vasquez; Nicholas J White; Matthias Zeller; Douglas B Grotjahn; Elizabeth T Papish
Journal:  Inorganica Chim Acta       Date:  2017-07-01       Impact factor: 2.545

5.  Manganese-Hydroxido Complexes Supported by a Urea/Phosphinic Amide Tripodal Ligand.

Authors:  Victoria F Oswald; Andrew C Weitz; Saborni Biswas; Joseph W Ziller; Michael P Hendrich; A S Borovik
Journal:  Inorg Chem       Date:  2018-10-09       Impact factor: 5.165

6.  Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex.

Authors:  Eric W Dahl; Nathaniel K Szymczak
Journal:  Angew Chem Int Ed Engl       Date:  2016-01-28       Impact factor: 15.336

7.  Hydrogen-bonded nickel(I) complexes.

Authors:  Jessica R Wilson; Matthias Zeller; Nathaniel K Szymczak
Journal:  Chem Commun (Camb)       Date:  2021-01-26       Impact factor: 6.222

8.  Intramolecular N-H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex.

Authors:  Jesse V Gavette; Christina M Klug; Lev N Zakharov; Matthew P Shores; Michael M Haley; Darren W Johnson
Journal:  Chem Commun (Camb)       Date:  2014-07-11       Impact factor: 6.222

9.  Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions.

Authors:  Sandra Y de Boer; Ties J Korstanje; Stefan R La Rooij; Rogier Kox; Joost N H Reek; Jarl Ivar van der Vlugt
Journal:  Organometallics       Date:  2017-04-06       Impact factor: 3.876

10.  Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand.

Authors:  Sander Oldenhof; Martin Lutz; Bas de Bruin; Jarl Ivar van der Vlugt; Joost N H Reek
Journal:  Chem Sci       Date:  2014-10-22       Impact factor: 9.825
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