| Literature DB >> 23163918 |
Simon Duttwyler1, Anna M Butterfield, Jay S Siegel.
Abstract
The arenium acid [mesitylene-H](+) has been shown to be an extraordinarily active H/D exchange catalyst for the perdeuteration of polycyclic aromatic hydrocarbons. The reactions take place under ambient conditions in C6D6 as an inexpensive deuterium source. High isolated yields and excellent degrees of deuterium incorporation were achieved using the substrates p-terphenyl, fluoranthene, pyrene, triphenylene, and corannulene.Entities:
Mesh：
Substances：
Year: 2012 PMID： 23163918 DOI： 10.1021/jo302201a
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354