Literature DB >> 23153301

Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes.

Phillip J Milner1, Thomas J Maimone, Mingjuan Su, Jiahao Chen, Peter Müller, Stephen L Buchwald.   

Abstract

A series of monoligated L·Pd(II)(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd(II)-mediated insertion of an aryl group into an unactivated arene.

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Year:  2012        PMID： 23153301      PMCID： PMC3530617          DOI： 10.1021/ja310351e

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  74 in total

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