A rearrangement reaction of biarylphosphine-supported Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.
A rearrangement reaction of biarylphosphine-supported n class="Gene">Pd(II) complexes was employed to synthesize 1,3,5-triaryl 2,4,6-triisopropylbenzene compounds, a class of molecules that has not previously been reported. The strain of the central hexasubstituted ring was investigated via X-ray crystallography.
Authors: Yoann M Chabre; Patrick P Brisebois; Leïla Abbassi; Sheena C Kerr; John V Fahy; Isabelle Marcotte; René Roy Journal: J Org Chem Date: 2010-12-29 Impact factor: 4.354