| Literature DB >> 23143019 |
Tigran S Kurtikyan1, Vardan A Hayrapetyan, Garik G Martirosyan, Robert K Ghazaryan, Alexei V Iretskii, Hailiang Zhao, Kristine Pierloot, Peter C Ford.
Abstract
Reaction of NO with amorphous Mn(TPP) layers gives two Mn(TPP)(NO) isomers with linear and bent Mn-N-O geometries that reversibly interconvert with changes in temperature. DFT computations predict that the linear complex is the singlet ground state while the bent structure is a triplet state.Entities:
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Year: 2012 PMID： 23143019 DOI： 10.1039/c2cc37337h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222