| Literature DB >> 23073224 |
Simone G Weber1, David Zahner, Frank Rominger, Bernd F Straub.
Abstract
A sterically shielded cationic NHC gold complex IPr**Au-BArF(24) without solvent coordination has been prepared in situ in CH(2)Cl(2). The monovalent transition metal electrophile, a "soft proton", heterolytically activates the C-B bond of the weakly coordinating counterion tetrakis[3,5-bis(trifluoromethyl)phenyl]borate at room temperature.Entities:
Year: 2012 PMID： 23073224 DOI： 10.1039/c2cc36171j
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222