Literature DB >> 23050595

Synthesis of (±)-γ-rubromycin via a new hypoiodite-catalytic oxidative cycloetherification.

Liping Wei1, Jijun Xue, Hongbiao Liu, Wenjing Wang, Ying Li.   

Abstract

A new synthesis of γ-rubromycin is presented through a new oxidative, bisbenzannulated spiroketalization as a key step which is catalyzed by an in situ generated hypoiodite species, developed previously by our group. This key transformation has high efficiency and convenient conditions. This is a new and efficient catalytic application for organohypoiodine reagents.

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Year:  2012        PMID: 23050595     DOI: 10.1021/ol3024874

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  2 in total

1.  Solvent-dependent divergent functions of Sc(OTf)₃ in stereoselective epoxide-opening spiroketalizations.

Authors:  Indrajeet Sharma; Jacqueline M Wurst; Derek S Tan
Journal:  Org Lett       Date:  2014-04-17       Impact factor: 6.005

2.  Characterization of Streptomyces piniterrae sp. nov. and Identification of the Putative Gene Cluster Encoding the Biosynthesis of Heliquinomycins.

Authors:  Xiaoxin Zhuang; Zhiyan Wang; Chenghui Peng; Can Su; Congting Gao; Yongjiang Wang; Shengxiong Huang; Chongxi Liu
Journal:  Microorganisms       Date:  2020-03-31
  2 in total

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