Designer spin pseudomolecule implemented with trapped ions in a magnetic gradient.

We report on the experimental investigation of an individual pseudomolecule using trapped ions with adjustable magnetically induced J-type coupling between spin states. Resonances of individual spins are well separated and are addressed with high fidelity. Quantum gates are carried out using microwave radiation in the presence of thermal excitation of the pseudomolecule's vibrations. Demonstrating controlled-NOT gates between non-nearest neighbors serves as a proof-of-principle of a quantum bus employing a spin chain. Combining advantageous features of nuclear magnetic resonance experiments and trapped ions, respectively, opens up a new avenue toward scalable quantum information processing.