Literature DB >> 22918262

Multicomponent and sequential organocatalytic reactions: diversity with atom-economy and enantiocontrol.

Charles M Marson1.   

Abstract

Reactions in which several components are combined in sequence, and without isolation of intermediates, are greatly sought because of the inherent molecular diversity, efficiency, and atom-economy. However, organocatalytic reactions, employing an organic catalyst to assemble products of high enantiomeric excess (a single optical isomer), are also cutting-edge methodology. This tutorial review covers the overlap of these two areas, outling the structural diversity and stereocontrol arising from one-pot combinations of at least three components, powerful approaches with great potential that minimise formation of by-products and operating costs.

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Year:  2012        PMID： 22918262     DOI： 10.1039/c2cs35183h

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  11 in total

1.  Toward the Ideal Synthesis and Transformative Therapies: The Roles of Step Economy and Function Oriented Synthesis.

Authors:  Paul A Wender
Journal:  Tetrahedron       Date:  2013-06-07       Impact factor: 2.457

2.  Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates.

Authors:  Xinfang Xu; Peter Y Zavalij; Michael P Doyle
Journal:  Angew Chem Int Ed Engl       Date:  2013-10-02       Impact factor: 15.336

3.  One-pot organocatalytic/multicomponent approach for the preparation of novel enantioenriched non-natural selenium-based peptoids and peptide-peptoid conjugates.

Authors:  Alexander F de la Torre; Akbar Ali; Fábio Z Galetto; Antonio L Braga; José A C Delgado; Márcio W Paixão
Journal:  Mol Divers       Date:  2019-02-18       Impact factor: 2.943

Review 4.  The ever-expanding role of asymmetric covalent organocatalysis in scalable, natural product synthesis.

Authors:  Mikail E Abbasov; Daniel Romo
Journal:  Nat Prod Rep       Date:  2014-10       Impact factor: 13.423

Review 5.  Recent advances in the green synthesis of Betti bases and their applications: a review.

Authors:  Ramsha Iftikhar; Muhammad Kamran; Aleesha Iftikhar; Sadia Parveen; Naila Naeem; Nazia Jamil
Journal:  Mol Divers       Date:  2022-04-21       Impact factor: 2.943

6.  Asymmetric synthesis of 1H-pyrrol-3(2H)-ones from 2,3-diketoesters by combination of aldol condensation with benzilic acid rearrangement.

Authors:  Qiang Sha; Hadi Arman; Michael P Doyle
Journal:  Chem Commun (Camb)       Date:  2016-01-04       Impact factor: 6.222

7.  A new paradigm for designing ring construction strategies for green organic synthesis: implications for the discovery of multicomponent reactions to build molecules containing a single ring.

Authors:  John Andraos
Journal:  Beilstein J Org Chem       Date:  2016-11-16       Impact factor: 2.883

8.  Bran-New Four-Molecule and Five-Molecule Cascade Reactions for One-Pot Synthesis of Pyrano[3,2-c]chromen-5-ones and Spiro[benzo[b][1,4]diazepine-2,2'-pyrano[3,2-c]chromen]-5'-ones under Catalyst- and Solvent-Free Conditions.

Authors:  Guoxun Zhu; Zhou Yi; Jie Zhou; Zhiyong Chen; Pengran Guo; Yanying Huang; Jianghan Chen; Huacan Song; Wei Yi
Journal:  ACS Omega       Date:  2018-10-18

9.  Novel cellulose supported 1,2-bis(4-aminophenylthio)ethane Ni(ii) complex (NiII(BAPTE)(NO3)2-Cell) as an efficient nanocatalyst for the synthesis of spirooxindole derivatives.

Authors:  Raziyeh Keshavarz; Mahnaz Farahi
Journal:  RSC Adv       Date:  2022-01-27       Impact factor: 3.361

10.  Synthesis of α,α'-trans-oxepanes through an organocatalytic oxa-conjugate addition reaction.

Authors:  Megan L Lanier; Amanda C Kasper; Hyoungsu Kim; Jiyong Hong
Journal:  Org Lett       Date:  2014-04-11       Impact factor: 6.005
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