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Literature DB >> 22893591

99TcO4(-): selective recognition and trapping in aqueous solution.

Roger Alberto¹, Greta Bergamaschi, Henrik Braband, Thomas Fox, Valeria Amendola.

Abstract

Too hot to handle: Unprecedented affinity and specificity for (99)TcO(4)(-) in aqueous solution was shown with the p-xylyl azacryptand in the hexaprotonated form. A crystal structure of the complex reveals how the anion fits within the cavity of the cage, and the formation of multiple H-bond interactions with protonated amino groups stabilize the adduct.

Entities: Chemical Disease

Year: 2012 PMID： 22893591 DOI： 10.1002/anie.201205313

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

6 in total

1. Red aqueous room-temperature phosphorescence modulated by anion-π and intermolecular electronic coupling interactions.

Authors: Fengbo Liu; Hai Yang; Dongdong Sun; Fang Gao; Xiongzhi Zhang; Zhiyong Zhao; Xie Han; Simin Liu
Journal: Chem Sci Date: 2022-05-25 Impact factor: 9.969

2. [C-H···anion] interactions mediate the templation and anion binding properties of topologically non-trivial metal-organic structures in aqueous solutions.

Authors: Rana A Bilbeisi; Thirumurugan Prakasam; Matteo Lusi; Roberto El Khoury; Carlos Platas-Iglesias; Loïc J Charbonnière; John-Carl Olsen; Mourad Elhabiri; Ali Trabolsi
Journal: Chem Sci Date: 2016-02-12 Impact factor: 9.825

3. Anion-adaptive crystalline cationic material for ⁹⁹TcO₄^- trapping.

Authors: Lei Mei; Fei-Ze Li; Jian-Hui Lan; Cong-Zhi Wang; Chao Xu; Hao Deng; Qun-Yan Wu; Kong-Qiu Hu; Lin Wang; Zhi-Fang Chai; Jing Chen; John K Gibson; Wei-Qun Shi
Journal: Nat Commun Date: 2019-04-04 Impact factor: 14.919

4. Mechanism unravelling for highly efficient and selective ⁹⁹TcO₄ ^- sequestration utilising crown ether based solvent system from nuclear liquid waste: experimental and computational investigations.

Authors: Kankan Patra; Arijit Sengupta; Anil Boda; Musharaf Ali; V K Mittal; T P Valsala; C P Kaushik
Journal: RSC Adv Date: 2022-01-25 Impact factor: 3.361

5. Selective Anion Extraction and Recovery Using a Fe^II₄ L₄ Cage.

Authors: Dawei Zhang; Tanya K Ronson; Jesús Mosquera; Alexandre Martinez; Jonathan R Nitschke
Journal: Angew Chem Int Ed Engl Date: 2018-02-23 Impact factor: 15.336

6. Mechanism unravelling for ultrafast and selective ⁹⁹TcO₄ ^- uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study.

Authors: Linwei He; Shengtang Liu; Long Chen; Xing Dai; Jie Li; Mingxing Zhang; Fuyin Ma; Chao Zhang; Zaixing Yang; Ruhong Zhou; Zhifang Chai; Shuao Wang
Journal: Chem Sci Date: 2019-02-19 Impact factor: 9.825

6 in total

99TcO4(-): selective recognition and trapping in aqueous solution.

1. Red aqueous room-temperature phosphorescence modulated by anion-π and intermolecular electronic coupling interactions.

2. [C-H···anion] interactions mediate the templation and anion binding properties of topologically non-trivial metal-organic structures in aqueous solutions.

3. Anion-adaptive crystalline cationic material for 99TcO4- trapping.

4. Mechanism unravelling for highly efficient and selective 99TcO4 - sequestration utilising crown ether based solvent system from nuclear liquid waste: experimental and computational investigations.

5. Selective Anion Extraction and Recovery Using a FeII4 L4 Cage.

6. Mechanism unravelling for ultrafast and selective 99TcO4 - uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study.

3. Anion-adaptive crystalline cationic material for ⁹⁹TcO₄^- trapping.

4. Mechanism unravelling for highly efficient and selective ⁹⁹TcO₄ ^- sequestration utilising crown ether based solvent system from nuclear liquid waste: experimental and computational investigations.

5. Selective Anion Extraction and Recovery Using a Fe^II₄ L₄ Cage.

6. Mechanism unravelling for ultrafast and selective ⁹⁹TcO₄ ^- uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study.