Literature DB >> 22837402

Quantum rotation of ortho and para-water encapsulated in a fullerene cage.

Carlo Beduz1, Marina Carravetta, Judy Y-C Chen, Maria Concistrè, Mark Denning, Michael Frunzi, Anthony J Horsewill, Ole G Johannessen, Ronald Lawler, Xuegong Lei, Malcolm H Levitt, Yongjun Li, Salvatore Mamone, Yasujiro Murata, Urmas Nagel, Tomoko Nishida, Jacques Ollivier, Stéphane Rols, Toomas Rõõm, Riddhiman Sarkar, Nicholas J Turro, Yifeng Yang.   

Abstract

Inelastic neutron scattering, far-infrared spectroscopy, and cryogenic nuclear magnetic resonance are used to investigate the quantized rotation and ortho-para conversion of single water molecules trapped inside closed fullerene cages. The existence of metastable ortho-water molecules is demonstrated, and the interconversion of ortho-and para-water spin isomers is tracked in real time. Our investigation reveals that the ground state of encapsulated ortho water has a lifted degeneracy, associated with symmetry-breaking of the water environment.

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Year:  2012        PMID： 22837402      PMCID： PMC3420201          DOI： 10.1073/pnas.1210790109

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN： 0027-8424            Impact factor:   11.205


  14 in total

1.  New horizons for magic-angle spinning NMR.

Authors:  Ago Samoson; Tiit Tuherm; Jean Past; Andres Reinhold; Tiit Anupõld; Ivo Heinmaa
Journal:  Top Curr Chem       Date:  2005

2.  Endohedral fullerites: A new class of ferroelectric materials.

Authors: 
Journal:  Phys Rev Lett       Date:  1992-11-09       Impact factor: 9.161

3.  Infrared spectroscopy of endohedral HD and D2 in C60.

Authors:  Min Ge; U Nagel; D Hüvonen; T Rõõm; S Mamone; M H Levitt; M Carravetta; Y Murata; K Komatsu; Xuegong Lei; N J Turro
Journal:  J Chem Phys       Date:  2011-09-21       Impact factor: 3.488

4.  An NMR thermometer for cryogenic magic-angle spinning NMR: the spin-lattice relaxation of (127)I in cesium iodide.

Authors:  Riddhiman Sarkar; Maria Concistrè; Ole G Johannessen; Peter Beckett; Mark Denning; Marina Carravetta; Maitham Al-Mosawi; Carlo Beduz; Yifeng Yang; Malcolm H Levitt
Journal:  J Magn Reson       Date:  2011-08-17       Impact factor: 2.229

5.  Encapsulation of molecular hydrogen in fullerene C60 by organic synthesis.

Authors:  Koichi Komatsu; Michihisa Murata; Yasujiro Murata
Journal:  Science       Date:  2005-01-14       Impact factor: 47.728

6.  A single molecule of water encapsulated in fullerene C₆₀.

Authors:  Kei Kurotobi; Yasujiro Murata
Journal:  Science       Date:  2011-07-29       Impact factor: 47.728

7.  Coupled translation-rotation eigenstates of H(2) in C(60) and C(70) on the spectroscopically optimized interaction potential: Effects of cage anisotropy on the energy level structure and assignments.

Authors:  Minzhong Xu; Francesco Sebastianelli; Brittney R Gibbons; Zlatko Bacić; Ronald Lawler; Nicholas J Turro
Journal:  J Chem Phys       Date:  2009-06-14       Impact factor: 3.488

8.  Biomolecular solid state NMR with magic-angle spinning at 25K.

Authors:  Kent R Thurber; Robert Tycko
Journal:  J Magn Reson       Date:  2008-09-23       Impact factor: 2.229

9.  H2, HD, and D2 inside C60: coupled translation-rotation eigenstates of the endohedral molecules from quantum five-dimensional calculations.

Authors:  Minzhong Xu; Francesco Sebastianelli; Zlatko Bacić; Ronald Lawler; Nicholas J Turro
Journal:  J Chem Phys       Date:  2008-08-14       Impact factor: 3.488

10.  Rotor in a cage: Infrared spectroscopy of an endohedral hydrogen-fullerene complex.

Authors:  S Mamone; Min Ge; D Hüvonen; U Nagel; A Danquigny; F Cuda; M C Grossel; Y Murata; K Komatsu; M H Levitt; T Rõõm; M Carravetta
Journal:  J Chem Phys       Date:  2009-02-28       Impact factor: 3.488
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  13 in total

1.  On the chemical behavior of C60 hosting H2O and other isoelectronic neutral molecules.

Authors:  Annia Galano; Adriana Pérez-González; Lourdes del Olmo; Misaela Francisco-Marquez; Jorge Rafael León-Carmona
Journal:  J Mol Model       Date:  2014-08-14       Impact factor: 1.810

2.  The dipolar endofullerene HF@C60.

Authors:  Andrea Krachmalnicoff; Richard Bounds; Salvatore Mamone; Shamim Alom; Maria Concistrè; Benno Meier; Karel Kouřil; Mark E Light; Mark R Johnson; Stéphane Rols; Anthony J Horsewill; Anna Shugai; Urmas Nagel; Toomas Rõõm; Marina Carravetta; Malcolm H Levitt; Richard J Whitby
Journal:  Nat Chem       Date:  2016-07-11       Impact factor: 24.427

3.  Collisional cross-section of water molecules in vapour studied by means of 1H relaxation in NMR.

Authors:  Daniele Mammoli; Estel Canet; Roberto Buratto; Pascal Miéville; Lothar Helm; Geoffrey Bodenhausen
Journal:  Sci Rep       Date:  2016-12-23       Impact factor: 4.379

4.  Synthesis and Properties of Open Fullerenes Encapsulating Ammonia and Methane.

Authors:  Sally Bloodworth; John Gräsvik; Shamim Alom; Karel Kouřil; Stuart J Elliott; Neil J Wells; Anthony J Horsewill; Salvatore Mamone; Mónica Jiménez-Ruiz; Stéphane Rols; Urmas Nagel; Toomas Rõõm; Malcolm H Levitt; Richard J Whitby
Journal:  Chemphyschem       Date:  2018-01-04       Impact factor: 3.102

5.  Probing the interaction between the encapsulated water molecule and the fullerene cages in H2O@C60- and H2O@C59N.

Authors:  Guo-Zhu Zhu; Yuan Liu; Yoshifumi Hashikawa; Qian-Fan Zhang; Yasujiro Murata; Lai-Sheng Wang
Journal:  Chem Sci       Date:  2018-06-04       Impact factor: 9.825

6.  First Synthesis and Characterization of CH4 @C60.

Authors:  Sally Bloodworth; Gabriela Sitinova; Shamim Alom; Sara Vidal; George R Bacanu; Stuart J Elliott; Mark E Light; Julie M Herniman; G John Langley; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-12       Impact factor: 15.336

7.  A Solid-State Intramolecular Wittig Reaction Enables Efficient Synthesis of Endofullerenes Including Ne@C60 , 3 He@C60 , and HD@C60.

Authors:  Gabriela Hoffman; Mark C Walkey; John Gräsvik; George R Bacanu; Shamim Alom; Sally Bloodworth; Mark E Light; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2021-03-04       Impact factor: 15.336

8.  Electrical detection of ortho-para conversion in fullerene-encapsulated water.

Authors:  Benno Meier; Salvatore Mamone; Maria Concistrè; Javier Alonso-Valdesueiro; Andrea Krachmalnicoff; Richard J Whitby; Malcolm H Levitt
Journal:  Nat Commun       Date:  2015-08-24       Impact factor: 14.919

9.  Nuclear magnetic resonance of hydrogen molecules trapped inside C70 fullerene cages.

Authors:  Salvatore Mamone; Maria Concistrè; Ivo Heinmaa; Marina Carravetta; Ilya Kuprov; Gary Wall; Mark Denning; Xuegong Lei; Judy Y-C Chen; Yongjun Li; Yasujiro Murata; Nicholas J Turro; Malcolm H Levitt
Journal:  Chemphyschem       Date:  2013-06-20       Impact factor: 3.102

10.  Dielectric ordering of water molecules arranged in a dipolar lattice.

Authors:  M A Belyanchikov; M Savinov; Z V Bedran; P Bednyakov; P Proschek; J Prokleska; V A Abalmasov; J Petzelt; E S Zhukova; V G Thomas; A Dudka; A Zhugayevych; A S Prokhorov; V B Anzin; R K Kremer; J K H Fischer; P Lunkenheimer; A Loidl; E Uykur; M Dressel; B Gorshunov
Journal:  Nat Commun       Date:  2020-08-06       Impact factor: 14.919
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