Literature DB >> 22733139

Transition metal-catalyzed fluorination of multi carbon-carbon bonds: new strategies for fluorinated heterocycles.

Guosheng Liu1.   

Abstract

Transition metal catalysts have been developed for introducing fluorine into organic compounds. Recent progress in this area is reviewed with an emphasis on the selective fluorination of alkenes, alkynes and allenes. Regio- and stereoselective fluorination reactions are highlighted.

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Year:  2012        PMID： 22733139     DOI： 10.1039/c2ob25702e

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  8 in total

1.  Copper-catalyzed decarboxylative trifluoromethylation of allylic bromodifluoroacetates.

Authors:  Brett R Ambler; Ryan A Altman
Journal:  Org Lett       Date:  2013-10-11       Impact factor: 6.005

Review 2.  Decarboxylative fluorination strategies for accessing medicinally- relevant products.

Authors:  Yupu Qiao; Lingui Zhu; Brett R Ambler; Ryan A Altman
Journal:  Curr Top Med Chem       Date:  2014       Impact factor: 3.295

3.  Silver-catalyzed vinylogous fluorination of vinyl diazoacetates.

Authors:  Changming Qin; Huw M L Davies
Journal:  Org Lett       Date:  2013-11-14       Impact factor: 6.005

4.  Catalytic Intramolecular Aminofluorination, Oxyfluorination, and Carbofluorination with a Stable and Versatile Hypervalent Fluoroiodine Reagent.

Authors:  Weiming Yuan; Kálmán J Szabó
Journal:  Angew Chem Int Ed Engl       Date:  2015-06-09       Impact factor: 15.336

5.  Asymmetric palladium-catalyzed directed intermolecular fluoroarylation of styrenes.

Authors:  Eric P A Talbot; Talita de A Fernandes; Jeffrey M McKenna; F Dean Toste
Journal:  J Am Chem Soc       Date:  2014-03-11       Impact factor: 15.419

6.  Aminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles.

Authors:  Antonio Arcadi; Emanuela Pietropaolo; Antonello Alvino; Véronique Michelet
Journal:  Beilstein J Org Chem       Date:  2014-02-20       Impact factor: 2.883

7.  Access to benzo-fused nine-membered heterocyclic alkenes with a trifluoromethyl carbinol moiety via a double decarboxylative formal ring-expansion process under palladium catalysis.

Authors:  Pulakesh Das; Satoshi Gondo; Punna Nagender; Hiroto Uno; Etsuko Tokunaga; Norio Shibata
Journal:  Chem Sci       Date:  2018-02-23       Impact factor: 9.825

8.  Metal-free trifluoromethylation of aromatic and heteroaromatic aldehydes and ketones.

Authors:  Yupu Qiao; Tuda Si; Ming-Hsiu Yang; Ryan A Altman
Journal:  J Org Chem       Date:  2014-07-15       Impact factor: 4.354
  8 in total

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