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Literature DB >> 22621405

Total syntheses of graphisin A and sydowinin B.

Abstract

Efficient syntheses of the highly substituted benzophenone graphisin A and the xanthone sydowinin B are described. Key steps involve aryl anion addition to substituted benzaldehyde derivatives, subsequent methyl ester installation, and dehydrative cyclization. Oxidation of graphisin A led to a spirodienone derived from a highly substituted benzoquinone intermediate.

Entities: Chemical Species

Mesh：

Substances：

Year: 2012 PMID： 22621405 PMCID： PMC3367002 DOI： 10.1021/ol301107m

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

17 in total

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Journal: Angew Chem Int Ed Engl Date: 2010-10-04 Impact factor: 15.336

Review 2. Chemistry and biology of mycotoxins and related fungal metabolites.

Authors: Stefan Bräse; Arantxa Encinas; Julia Keck; Carl F Nising
Journal: Chem Rev Date: 2009-09 Impact factor: 60.622

3. Iron-mediated synthetic routes to unsymmetrically substituted, sterically congested benzophenones

Authors:
Journal: J Org Chem Date: 2000-08-25 Impact factor: 4.354

Review 4. Synthesis of xanthones: an overview.

Authors: M E Sousa; M M M Pinto
Journal: Curr Med Chem Date: 2005 Impact factor: 4.530

5. Xanthone natural products via N-heterocyclic carbene catalysis: total synthesis of atroviridin.

Authors: Yumiko Suzuki; Yoshinori Fukuta; Shinya Ota; Masayo Kamiya; Masayuki Sato
Journal: J Org Chem Date: 2011-04-18 Impact factor: 4.354

6. Total Synthesis of Tovophyllin B.

Authors: Valer Jeso; K C Nicolaou
Journal: Tetrahedron Lett Date: 2009-03-18 Impact factor: 2.415

7. New mono- and dimeric members of the secalonic acid family: blennolides A-G isolated from the fungus Blennoria sp.

Authors: Wen Zhang; Karsten Krohn; Ulrich Flörke; Gennaro Pescitelli; Lorenzo Di Bari; Sándor Antus; Tibor Kurtán; Joachim Rheinheimer; Siegfried Draeger; Barbara Schulz
Journal: Chemistry Date: 2008 Impact factor: 5.236

8. Acremonidins, new polyketide-derived antibiotics produced by Acremonium sp., LL-Cyan 416.

Authors: Haiyin He; Ramunas Bigelis; Eric H Solum; Michael Greenstein; Guy T Carter
Journal: J Antibiot (Tokyo) Date: 2003-11 Impact factor: 2.649

9. Studies toward the total synthesis of mumbaistatin, a highly potent glucose-6-phosphate translocase inhibitor. Synthesis of a mumbaistatin analogue.

Authors: Florian Kaiser; Lothar Schwink; Janna Velder; Hans-Günther Schmalz
Journal: J Org Chem Date: 2002-12-27 Impact factor: 4.354