Ethyl 7-methyl-3-oxo-5-phenyl-2-(2,4,6-trimeth-oxy-benzyl-idene)-2,3-dihydro-5H-thia-zolo[3,2-a]pyrimidine-6-carboxyl-ate.

In the title compound, C(26)H(26)N(2)O(6)S, the benzene ring is positioned axially to the thia-zolopyrimidine ring and bis-ects it with a dihedral angle of 80.94 (7)°. The pyrimidine ring adopts a flattened boat conformation. In the crystal, pairs of bifurcated C-H⋯O hydrogen bonds link the mol-ecules into chains along the c axis.

Related literature

For the pharmacological activity of pyrimidine derivatives, see: Alam et al. (2010 ▶). For a related crystal structure, see: Chen et al. (2012 ▶).

Experimental

Crystal data

C26H26N2O6S

M = 494.55

Monoclinic,

a = 7.5363 (19) Å

b = 18.178 (5) Å

c = 16.973 (4) Å

β = 94.465 (5)°

V = 2318.1 (10) Å3

Z = 4

Mo Kα radiation

μ = 0.19 mm−1

T = 296 K

0.18 × 0.16 × 0.16 mm

Data collection

Bruker SMART APEX CCD detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 1998 ▶) T min = 0.967, T max = 0.971

13918 measured reflections

5055 independent reflections

3500 reflections with I > 2σ(I)

R int = 0.052

Refinement

R[F 2 > 2σ(F 2)] = 0.058

wR(F 2) = 0.168

S = 1.07

5055 reflections

321 parameters

H-atom parameters constrained

Δρmax = 0.59 e Å−3

Δρmin = −0.38 e Å−3

Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT-Plus (Bruker, 1998 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and CAMERON (Watkin et al., 1996 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536812012354/pv2518sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536812012354/pv2518Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536812012354/pv2518Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C26H26N2O6S	F(000) = 1040
Mr = 494.55	Dx = 1.417 Mg m−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 5055 reflections
a = 7.5363 (19) Å	θ = 2.2–27.0°
b = 18.178 (5) Å	µ = 0.19 mm−1
c = 16.973 (4) Å	T = 296 K
β = 94.465 (5)°	Block, yellow
V = 2318.1 (10) Å3	0.18 × 0.16 × 0.16 mm
Z = 4

Bruker SMART APEX CCD detector diffractometer	5055 independent reflections
Radiation source: fine-focus sealed tube	3500 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.052
ω scans	θmax = 27.0°, θmin = 2.2°
Absorption correction: multi-scan (SADABS; Bruker, 1998)	h = −9→6
Tmin = 0.967, Tmax = 0.971	k = −19→23
13918 measured reflections	l = −21→20

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.058	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.168	H-atom parameters constrained
S = 1.07	w = 1/[σ2(Fo2) + (0.0854P)2] where P = (Fo2 + 2Fc2)/3
5055 reflections	(Δ/σ)max = 0.001
321 parameters	Δρmax = 0.59 e Å−3
0 restraints	Δρmin = −0.38 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
S1	0.73105 (9)	0.14251 (3)	0.58179 (4)	0.02186 (19)
O5	−0.0478 (3)	0.28751 (10)	0.67802 (11)	0.0280 (5)
O2	1.1137 (2)	0.27911 (9)	0.35791 (11)	0.0259 (5)
O4	1.0502 (2)	0.09339 (9)	0.54509 (10)	0.0250 (4)
N1	0.4401 (3)	0.16361 (12)	0.65853 (12)	0.0224 (5)
O1	0.6191 (2)	0.32009 (9)	0.46396 (11)	0.0252 (4)
O6	0.0574 (2)	0.36348 (10)	0.58753 (12)	0.0285 (5)
N2	0.5119 (3)	0.25231 (11)	0.56348 (12)	0.0209 (5)
O3	1.5463 (3)	0.08397 (10)	0.39073 (11)	0.0276 (5)
C16	0.5164 (3)	0.36754 (14)	0.69908 (15)	0.0218 (6)
H16	0.5270	0.3219	0.7237	0.026*
C11	0.4425 (3)	0.37259 (14)	0.62157 (15)	0.0195 (6)
C6	0.2376 (4)	0.26532 (14)	0.62849 (15)	0.0220 (6)
C10	0.0685 (4)	0.30403 (14)	0.63572 (16)	0.0237 (6)
C20	1.3047 (4)	0.08844 (14)	0.46749 (15)	0.0221 (6)
H20	1.3473	0.0459	0.4929	0.027*
C9	0.5401 (4)	0.18888 (13)	0.60625 (15)	0.0207 (6)
C17	0.9132 (3)	0.22160 (13)	0.46628 (15)	0.0201 (6)
H17	0.8968	0.2644	0.4365	0.024*
C7	0.2822 (4)	0.20292 (14)	0.66861 (15)	0.0221 (6)
C2	0.7777 (3)	0.21079 (13)	0.51239 (15)	0.0209 (6)
C5	0.3682 (3)	0.30400 (13)	0.57885 (16)	0.0214 (6)
H5	0.3062	0.3186	0.5284	0.026*
C3	0.6336 (4)	0.26750 (14)	0.50774 (15)	0.0218 (6)
C18	1.0776 (3)	0.18488 (13)	0.45027 (15)	0.0204 (6)
C21	1.3967 (3)	0.12094 (14)	0.40848 (15)	0.0220 (6)
C8	0.1730 (4)	0.16755 (15)	0.72924 (16)	0.0288 (7)
H8A	0.1686	0.1997	0.7739	0.043*
H8B	0.2265	0.1217	0.7460	0.043*
H8C	0.0544	0.1588	0.7063	0.043*
C19	1.1482 (4)	0.12100 (14)	0.48744 (14)	0.0206 (6)
C15	0.5743 (4)	0.43039 (14)	0.73975 (16)	0.0236 (6)
H15	0.6251	0.4268	0.7913	0.028*
C12	0.4283 (4)	0.44127 (14)	0.58605 (16)	0.0242 (6)
H12	0.3805	0.4452	0.5340	0.029*
C22	1.3384 (3)	0.18520 (14)	0.37125 (15)	0.0213 (6)
H22	1.4033	0.2070	0.3331	0.026*
C13	0.4841 (4)	0.50407 (14)	0.62696 (17)	0.0261 (6)
H13	0.4728	0.5499	0.6027	0.031*
C23	1.1808 (4)	0.21644 (13)	0.39216 (15)	0.0216 (6)
C25	1.6375 (4)	0.11104 (16)	0.32485 (17)	0.0328 (7)
H25A	1.5561	0.1127	0.2785	0.049*
H25B	1.7348	0.0789	0.3157	0.049*
H25C	1.6822	0.1596	0.3366	0.049*
C14	0.5563 (4)	0.49832 (14)	0.70364 (16)	0.0247 (6)
H14	0.5934	0.5404	0.7313	0.030*
C26	1.1201 (4)	0.03154 (14)	0.58899 (15)	0.0255 (6)
H26A	1.1362	−0.0087	0.5536	0.038*
H26B	1.0386	0.0173	0.6270	0.038*
H26C	1.2325	0.0444	0.6159	0.038*
C24	1.2289 (4)	0.32127 (14)	0.31204 (16)	0.0267 (6)
H24A	1.3356	0.3335	0.3440	0.040*
H24B	1.1695	0.3657	0.2942	0.040*
H24C	1.2587	0.2929	0.2672	0.040*
C1	−0.0260 (4)	0.48913 (16)	0.6104 (2)	0.0390 (8)
H1A	0.0262	0.4898	0.6638	0.059*
H1B	−0.1234	0.5233	0.6052	0.059*
H1C	0.0620	0.5030	0.5752	0.059*
C4	−0.0928 (4)	0.41300 (15)	0.59001 (19)	0.0325 (7)
H4A	−0.1703	0.3963	0.6294	0.039*
H4B	−0.1606	0.4136	0.5390	0.039*

	U11	U22	U33	U12	U13	U23
S1	0.0216 (4)	0.0219 (4)	0.0231 (4)	−0.0004 (3)	0.0078 (3)	0.0010 (3)
O5	0.0244 (11)	0.0318 (11)	0.0296 (11)	−0.0015 (9)	0.0135 (9)	−0.0016 (8)
O2	0.0233 (11)	0.0237 (10)	0.0322 (11)	0.0035 (8)	0.0118 (8)	0.0075 (8)
O4	0.0284 (11)	0.0222 (10)	0.0262 (10)	0.0018 (8)	0.0128 (8)	0.0051 (7)
N1	0.0211 (13)	0.0240 (11)	0.0229 (12)	−0.0026 (10)	0.0072 (10)	−0.0004 (9)
O1	0.0235 (11)	0.0232 (10)	0.0299 (11)	0.0014 (8)	0.0095 (8)	0.0031 (8)
O6	0.0181 (10)	0.0291 (10)	0.0396 (12)	0.0037 (8)	0.0111 (9)	0.0051 (8)
N2	0.0177 (12)	0.0211 (11)	0.0250 (12)	−0.0024 (9)	0.0081 (9)	−0.0007 (9)
O3	0.0245 (11)	0.0334 (11)	0.0265 (10)	0.0095 (9)	0.0123 (8)	0.0050 (8)
C16	0.0200 (14)	0.0208 (13)	0.0256 (14)	0.0003 (11)	0.0082 (11)	0.0020 (10)
C11	0.0128 (13)	0.0232 (13)	0.0239 (14)	−0.0011 (10)	0.0098 (11)	−0.0023 (10)
C6	0.0184 (14)	0.0207 (13)	0.0275 (14)	−0.0013 (11)	0.0064 (11)	−0.0046 (11)
C10	0.0211 (15)	0.0229 (14)	0.0277 (15)	−0.0056 (11)	0.0059 (12)	−0.0064 (11)
C20	0.0225 (15)	0.0243 (13)	0.0196 (13)	0.0023 (11)	0.0016 (11)	0.0010 (10)
C9	0.0201 (14)	0.0191 (13)	0.0232 (14)	−0.0026 (11)	0.0038 (11)	−0.0048 (10)
C17	0.0221 (15)	0.0196 (13)	0.0194 (13)	−0.0020 (11)	0.0062 (11)	−0.0012 (10)
C7	0.0189 (14)	0.0244 (14)	0.0237 (14)	−0.0079 (11)	0.0065 (11)	−0.0064 (11)
C2	0.0201 (14)	0.0184 (13)	0.0246 (14)	−0.0011 (11)	0.0050 (11)	−0.0018 (10)
C5	0.0159 (14)	0.0240 (13)	0.0251 (14)	0.0008 (11)	0.0072 (11)	−0.0012 (11)
C3	0.0207 (15)	0.0243 (14)	0.0211 (14)	−0.0032 (11)	0.0066 (11)	−0.0026 (11)
C18	0.0190 (14)	0.0204 (13)	0.0227 (14)	−0.0009 (11)	0.0069 (11)	−0.0019 (10)
C21	0.0173 (14)	0.0273 (14)	0.0215 (13)	0.0023 (11)	0.0029 (11)	−0.0024 (11)
C8	0.0292 (17)	0.0258 (14)	0.0334 (16)	−0.0049 (12)	0.0143 (13)	−0.0007 (12)
C19	0.0215 (14)	0.0233 (13)	0.0177 (13)	−0.0036 (11)	0.0064 (11)	−0.0015 (10)
C15	0.0204 (14)	0.0284 (14)	0.0228 (14)	0.0002 (12)	0.0060 (11)	−0.0034 (11)
C12	0.0212 (15)	0.0286 (14)	0.0234 (14)	0.0015 (11)	0.0057 (11)	0.0042 (11)
C22	0.0173 (14)	0.0282 (14)	0.0191 (13)	−0.0023 (11)	0.0059 (11)	−0.0022 (10)
C13	0.0258 (16)	0.0161 (13)	0.0376 (17)	0.0012 (11)	0.0095 (13)	0.0043 (11)
C23	0.0215 (15)	0.0187 (13)	0.0252 (14)	−0.0018 (11)	0.0051 (11)	−0.0014 (10)
C25	0.0297 (17)	0.0396 (17)	0.0311 (16)	0.0119 (14)	0.0146 (13)	0.0078 (13)
C14	0.0207 (15)	0.0222 (14)	0.0323 (15)	−0.0028 (11)	0.0096 (12)	−0.0053 (11)
C26	0.0276 (16)	0.0230 (14)	0.0265 (15)	0.0008 (12)	0.0063 (12)	0.0031 (11)
C24	0.0296 (16)	0.0240 (14)	0.0276 (15)	−0.0031 (12)	0.0091 (13)	0.0065 (11)
C1	0.0296 (18)	0.0357 (17)	0.053 (2)	0.0054 (14)	0.0103 (15)	0.0013 (15)
C4	0.0186 (15)	0.0355 (16)	0.0447 (18)	0.0046 (13)	0.0103 (13)	0.0040 (13)

S1—C9	1.745 (3)	C2—C3	1.495 (4)
S1—C2	1.765 (3)	C5—H5	0.9800
O5—C10	1.213 (3)	C18—C19	1.406 (4)
O2—C23	1.359 (3)	C18—C23	1.423 (3)
O2—C24	1.433 (3)	C21—C22	1.383 (4)
O4—C19	1.367 (3)	C8—H8A	0.9600
O4—C26	1.427 (3)	C8—H8B	0.9600
N1—C9	1.292 (3)	C8—H8C	0.9600
N1—C7	1.410 (3)	C15—C14	1.381 (4)
O1—C3	1.211 (3)	C15—H15	0.9300
O6—C10	1.354 (3)	C12—C13	1.385 (4)
O6—C4	1.449 (3)	C12—H12	0.9300
N2—C9	1.370 (3)	C22—C23	1.387 (3)
N2—C3	1.395 (3)	C22—H22	0.9300
N2—C5	1.473 (3)	C13—C14	1.375 (4)
O3—C21	1.367 (3)	C13—H13	0.9300
O3—C25	1.443 (3)	C25—H25A	0.9600
C16—C15	1.387 (4)	C25—H25B	0.9600
C16—C11	1.391 (4)	C25—H25C	0.9600
C16—H16	0.9300	C14—H14	0.9300
C11—C12	1.387 (3)	C26—H26A	0.9600
C11—C5	1.527 (3)	C26—H26B	0.9600
C6—C7	1.352 (4)	C26—H26C	0.9600
C6—C10	1.469 (4)	C24—H24A	0.9600
C6—C5	1.517 (3)	C24—H24B	0.9600
C20—C19	1.385 (3)	C24—H24C	0.9600
C20—C21	1.393 (3)	C1—C4	1.504 (4)
C20—H20	0.9300	C1—H1A	0.9600
C17—C2	1.348 (3)	C1—H1B	0.9600
C17—C18	1.451 (3)	C1—H1C	0.9600
C17—H17	0.9300	C4—H4A	0.9700
C7—C8	1.511 (3)	C4—H4B	0.9700
C9—S1—C2	91.72 (12)	C7—C8—H8C	109.5
C23—O2—C24	117.4 (2)	H8A—C8—H8C	109.5
C19—O4—C26	117.7 (2)	H8B—C8—H8C	109.5
C9—N1—C7	116.5 (2)	O4—C19—C20	122.4 (2)
C10—O6—C4	119.3 (2)	O4—C19—C18	114.7 (2)
C9—N2—C3	116.3 (2)	C20—C19—C18	122.9 (2)
C9—N2—C5	121.9 (2)	C14—C15—C16	120.0 (3)
C3—N2—C5	121.7 (2)	C14—C15—H15	120.0
C21—O3—C25	117.0 (2)	C16—C15—H15	120.0
C15—C16—C11	120.2 (2)	C13—C12—C11	120.9 (3)
C15—C16—H16	119.9	C13—C12—H12	119.5
C11—C16—H16	119.9	C11—C12—H12	119.5
C12—C11—C16	118.8 (2)	C21—C22—C23	118.5 (2)
C12—C11—C5	121.0 (2)	C21—C22—H22	120.8
C16—C11—C5	120.0 (2)	C23—C22—H22	120.8
C7—C6—C10	122.9 (2)	C14—C13—C12	119.6 (2)
C7—C6—C5	121.5 (2)	C14—C13—H13	120.2
C10—C6—C5	115.4 (2)	C12—C13—H13	120.2
O5—C10—O6	122.8 (2)	O2—C23—C22	122.1 (2)
O5—C10—C6	127.0 (3)	O2—C23—C18	115.4 (2)
O6—C10—C6	110.2 (2)	C22—C23—C18	122.5 (2)
C19—C20—C21	118.4 (2)	O3—C25—H25A	109.5
C19—C20—H20	120.8	O3—C25—H25B	109.5
C21—C20—H20	120.8	H25A—C25—H25B	109.5
N1—C9—N2	126.0 (2)	O3—C25—H25C	109.5
N1—C9—S1	121.8 (2)	H25A—C25—H25C	109.5
N2—C9—S1	112.16 (18)	H25B—C25—H25C	109.5
C2—C17—C18	137.5 (2)	C13—C14—C15	120.4 (2)
C2—C17—H17	111.2	C13—C14—H14	119.8
C18—C17—H17	111.2	C15—C14—H14	119.8
C6—C7—N1	122.9 (2)	O4—C26—H26A	109.5
C6—C7—C8	124.9 (2)	O4—C26—H26B	109.5
N1—C7—C8	112.1 (2)	H26A—C26—H26B	109.5
C17—C2—C3	116.7 (2)	O4—C26—H26C	109.5
C17—C2—S1	133.6 (2)	H26A—C26—H26C	109.5
C3—C2—S1	109.77 (18)	H26B—C26—H26C	109.5
N2—C5—C6	108.7 (2)	O2—C24—H24A	109.5
N2—C5—C11	110.9 (2)	O2—C24—H24B	109.5
C6—C5—C11	110.2 (2)	H24A—C24—H24B	109.5
N2—C5—H5	109.0	O2—C24—H24C	109.5
C6—C5—H5	109.0	H24A—C24—H24C	109.5
C11—C5—H5	109.0	H24B—C24—H24C	109.5
O1—C3—N2	122.7 (2)	C4—C1—H1A	109.5
O1—C3—C2	127.4 (2)	C4—C1—H1B	109.5
N2—C3—C2	109.9 (2)	H1A—C1—H1B	109.5
C19—C18—C23	115.8 (2)	C4—C1—H1C	109.5
C19—C18—C17	126.5 (2)	H1A—C1—H1C	109.5
C23—C18—C17	117.7 (2)	H1B—C1—H1C	109.5
O3—C21—C22	123.6 (2)	O6—C4—C1	109.3 (2)
O3—C21—C20	114.5 (2)	O6—C4—H4A	109.8
C22—C21—C20	121.9 (2)	C1—C4—H4A	109.8
C7—C8—H8A	109.5	O6—C4—H4B	109.8
C7—C8—H8B	109.5	C1—C4—H4B	109.8
H8A—C8—H8B	109.5	H4A—C4—H4B	108.3
C15—C16—C11—C12	0.1 (4)	C5—N2—C3—O1	−6.9 (4)
C15—C16—C11—C5	−176.1 (2)	C9—N2—C3—C2	−3.8 (3)
C4—O6—C10—O5	4.6 (4)	C5—N2—C3—C2	172.4 (2)
C4—O6—C10—C6	−175.1 (2)	C17—C2—C3—O1	4.5 (4)
C7—C6—C10—O5	1.9 (4)	S1—C2—C3—O1	−176.6 (2)
C5—C6—C10—O5	−172.4 (3)	C17—C2—C3—N2	−174.8 (2)
C7—C6—C10—O6	−178.4 (2)	S1—C2—C3—N2	4.1 (3)
C5—C6—C10—O6	7.3 (3)	C2—C17—C18—C19	−3.3 (5)
C7—N1—C9—N2	4.1 (4)	C2—C17—C18—C23	177.7 (3)
C7—N1—C9—S1	−175.11 (18)	C25—O3—C21—C22	−5.5 (4)
C3—N2—C9—N1	−177.5 (2)	C25—O3—C21—C20	174.1 (2)
C5—N2—C9—N1	6.3 (4)	C19—C20—C21—O3	−178.0 (2)
C3—N2—C9—S1	1.8 (3)	C19—C20—C21—C22	1.7 (4)
C5—N2—C9—S1	−174.44 (18)	C26—O4—C19—C20	4.1 (4)
C2—S1—C9—N1	180.0 (2)	C26—O4—C19—C18	−175.8 (2)
C2—S1—C9—N2	0.7 (2)	C21—C20—C19—O4	−179.4 (2)
C10—C6—C7—N1	176.5 (2)	C21—C20—C19—C18	0.6 (4)
C5—C6—C7—N1	−9.6 (4)	C23—C18—C19—O4	177.6 (2)
C10—C6—C7—C8	−4.2 (4)	C17—C18—C19—O4	−1.4 (4)
C5—C6—C7—C8	169.8 (2)	C23—C18—C19—C20	−2.4 (4)
C9—N1—C7—C6	−2.2 (4)	C17—C18—C19—C20	178.6 (2)
C9—N1—C7—C8	178.3 (2)	C11—C16—C15—C14	0.9 (4)
C18—C17—C2—C3	179.5 (3)	C16—C11—C12—C13	−0.8 (4)
C18—C17—C2—S1	0.9 (5)	C5—C11—C12—C13	175.3 (2)
C9—S1—C2—C17	175.9 (3)	O3—C21—C22—C23	177.6 (2)
C9—S1—C2—C3	−2.7 (2)	C20—C21—C22—C23	−1.9 (4)
C9—N2—C5—C6	−15.9 (3)	C11—C12—C13—C14	0.6 (4)
C3—N2—C5—C6	168.1 (2)	C24—O2—C23—C22	−13.5 (4)
C9—N2—C5—C11	105.4 (3)	C24—O2—C23—C18	167.1 (2)
C3—N2—C5—C11	−70.6 (3)	C21—C22—C23—O2	−179.4 (2)
C7—C6—C5—N2	17.4 (3)	C21—C22—C23—C18	0.0 (4)
C10—C6—C5—N2	−168.2 (2)	C19—C18—C23—O2	−178.5 (2)
C7—C6—C5—C11	−104.3 (3)	C17—C18—C23—O2	0.6 (3)
C10—C6—C5—C11	70.0 (3)	C19—C18—C23—C22	2.0 (4)
C12—C11—C5—N2	115.6 (3)	C17—C18—C23—C22	−178.8 (2)
C16—C11—C5—N2	−68.3 (3)	C12—C13—C14—C15	0.3 (4)
C12—C11—C5—C6	−123.9 (3)	C16—C15—C14—C13	−1.1 (4)
C16—C11—C5—C6	52.1 (3)	C10—O6—C4—C1	121.5 (3)
C9—N2—C3—O1	176.8 (2)

D—H···A	D—H	H···A	D···A	D—H···A
C24—H24C···O5i	0.96	2.63	3.537 (3)	158
C25—H25A···O5i	0.96	2.57	3.319 (3)	135

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C24—H24C⋯O5i	0.96	2.63	3.537 (3)	158
C25—H25A⋯O5i	0.96	2.57	3.319 (3)	135

Symmetry code: (i) .