4-(Dimeth-oxy-meth-yl)phenyl 2,3,4,6-tetra-O-acetyl-β-d-glucopyran-oside.

The enanti-omerically pure title compound, C(23)H(30)O(12), crystallizes in the chiral space group P2(1)2(1)2(1). The O-acetyl-ated-glucopyran-oside moiety adopts a chair conformation. Numerous C-H⋯O inter-actions as well as a C-H⋯π inter-action are present in the crystal structure.

Related literature

For similar compounds, see: Bin et al. (2008 ▶); Ansari et al. (2006 ▶). For the use of sugars as water-solubilizing agents in macrocycle chemistry, see: Sol et al. (1997 ▶); Maillard et al. (1993 ▶); Oulmi et al. (1995 ▶). For the role of sugars in biological systems, especially proteins, see: Floyd et al. (2009 ▶).

Experimental

Crystal data

C23H30O12

M = 498.47

Orthorhombic,

a = 7.9004 (2) Å

b = 10.9961 (3) Å

c = 29.2289 (8) Å

V = 2539.22 (12) Å3

Z = 4

Mo Kα radiation

μ = 0.11 mm−1

T = 173 K

0.45 × 0.32 × 0.10 mm

Data collection

Bruker APEXII CCD diffractometer

13406 measured reflections

3493 independent reflections

2644 reflections with I > 2σ(I)

R int = 0.053

Refinement

R[F 2 > 2σ(F 2)] = 0.042

wR(F 2) = 0.102

S = 0.97

3493 reflections

322 parameters

H-atom parameters constrained

Δρmax = 0.25 e Å−3

Δρmin = −0.20 e Å−3

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: SAINT (Bruker, 2005 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶) and SCHAKAL99 (Keller, 1999 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶) and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S160053681201121X/mw2057sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S160053681201121X/mw2057Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C23H30O12	F(000) = 1056
Mr = 498.47	Dx = 1.304 Mg m−3
Orthorhombic, P212121	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: P 2ac 2ab	Cell parameters from 3488 reflections
a = 7.9004 (2) Å	θ = 2.3–24.0°
b = 10.9961 (3) Å	µ = 0.11 mm−1
c = 29.2289 (8) Å	T = 173 K
V = 2539.22 (12) Å3	Plate, colourless
Z = 4	0.45 × 0.32 × 0.10 mm

Bruker APEXII CCD diffractometer	2644 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.053
Graphite monochromator	θmax = 28.0°, θmin = 2.0°
φ and ω scans	h = −10→10
13406 measured reflections	k = −10→14
3493 independent reflections	l = −38→37

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.102	H-atom parameters constrained
S = 0.97	w = 1/[σ2(Fo2) + (0.0567P)2] where P = (Fo2 + 2Fc2)/3
3493 reflections	(Δ/σ)max = 0.001
322 parameters	Δρmax = 0.25 e Å−3
0 restraints	Δρmin = −0.20 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R- factor wR and goodness of fit S are based on F2; conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
C1	0.0801 (3)	0.3057 (2)	0.12632 (8)	0.0238 (5)
H1	0.0113	0.2457	0.1086	0.029*
C2	0.2410 (3)	0.3384 (2)	0.10042 (8)	0.0219 (5)
H2	0.3164	0.3905	0.1197	0.026*
C3	0.1944 (3)	0.4037 (2)	0.05649 (8)	0.0225 (5)
H3	0.1373	0.3461	0.0350	0.027*
C4	0.0790 (3)	0.5105 (2)	0.06664 (8)	0.0236 (5)
H4	0.1420	0.5753	0.0836	0.028*
C5	−0.0749 (3)	0.4686 (2)	0.09422 (8)	0.0254 (5)
H5	−0.1399	0.4077	0.0759	0.031*
C6	−0.1907 (3)	0.5704 (2)	0.10783 (9)	0.0313 (6)
H6A	−0.2358	0.6113	0.0802	0.038*
H6B	−0.2873	0.5381	0.1257	0.038*
C7	0.0063 (3)	0.1934 (2)	0.19310 (8)	0.0266 (5)
C8	0.0622 (4)	0.1381 (2)	0.23282 (9)	0.0355 (7)
H8	0.1776	0.1437	0.2417	0.043*
C9	−0.0526 (4)	0.0745 (3)	0.25957 (9)	0.0389 (7)
H9	−0.0149	0.0360	0.2868	0.047*
C10	−0.2229 (4)	0.0663 (2)	0.24709 (9)	0.0349 (6)
C11	−0.2725 (4)	0.1186 (2)	0.20664 (10)	0.0353 (6)
H11	−0.3865	0.1100	0.1968	0.042*
C12	−0.1597 (4)	0.1839 (2)	0.17970 (9)	0.0339 (6)
H12	−0.1971	0.2217	0.1523	0.041*
C13	−0.3436 (4)	−0.0023 (3)	0.27751 (10)	0.0439 (7)
H13	−0.3008	−0.0875	0.2804	0.053*
C14	−0.4138 (6)	0.1676 (3)	0.32407 (12)	0.0660 (11)
H14A	−0.3371	0.2205	0.3068	0.099*
H14B	−0.4181	0.1944	0.3560	0.099*
H14C	−0.5274	0.1718	0.3107	0.099*
C15	−0.6115 (6)	−0.0935 (3)	0.27581 (13)	0.0679 (11)
H15A	−0.5587	−0.1741	0.2746	0.102*
H15B	−0.7182	−0.0950	0.2587	0.102*
H15C	−0.6340	−0.0716	0.3077	0.102*
C16	0.4919 (4)	0.2178 (2)	0.09375 (8)	0.0284 (6)
C17	0.5515 (4)	0.0911 (2)	0.08455 (10)	0.0428 (7)
H17A	0.6752	0.0882	0.0865	0.064*
H17B	0.5154	0.0662	0.0539	0.064*
H17C	0.5027	0.0357	0.1073	0.064*
C18	0.4204 (3)	0.3879 (2)	0.00160 (8)	0.0268 (5)
C19	0.5757 (4)	0.4516 (2)	−0.01518 (10)	0.0395 (7)
H19A	0.6324	0.4009	−0.0381	0.059*
H19B	0.6527	0.4660	0.0106	0.059*
H19C	0.5438	0.5296	−0.0289	0.059*
C20	0.0206 (4)	0.6785 (2)	0.01657 (9)	0.0329 (6)
C21	−0.0371 (5)	0.7100 (3)	−0.03023 (10)	0.0481 (8)
H21A	−0.0692	0.7960	−0.0313	0.072*
H21B	−0.1350	0.6597	−0.0383	0.072*
H21C	0.0548	0.6951	−0.0520	0.072*
C22	−0.1382 (4)	0.7733 (3)	0.13249 (11)	0.0464 (8)
C23	−0.0184 (5)	0.8508 (3)	0.15844 (13)	0.0651 (11)
H23A	0.0782	0.8716	0.1389	0.098*
H23B	0.0216	0.8066	0.1855	0.098*
H23C	−0.0759	0.9255	0.1681	0.098*
O1	−0.0151 (2)	0.41192 (14)	0.13529 (5)	0.0264 (4)
O2	0.1293 (2)	0.25639 (15)	0.16843 (5)	0.0283 (4)
O3	0.3219 (2)	0.22387 (14)	0.09025 (5)	0.0257 (4)
O4	0.5794 (3)	0.30351 (17)	0.10281 (7)	0.0401 (5)
O5	0.3456 (2)	0.45309 (14)	0.03546 (5)	0.0249 (4)
O6	0.3683 (3)	0.29251 (16)	−0.01228 (6)	0.0401 (5)
O7	0.0199 (2)	0.55613 (14)	0.02296 (5)	0.0280 (4)
O8	0.0625 (3)	0.74887 (16)	0.04572 (7)	0.0538 (6)
O9	−0.0958 (3)	0.65541 (15)	0.13508 (6)	0.0370 (5)
O10	−0.2594 (4)	0.8089 (2)	0.11206 (10)	0.0741 (8)
O11	−0.3548 (3)	0.0473 (2)	0.32214 (7)	0.0566 (6)
O12	−0.5013 (3)	−0.00697 (19)	0.25616 (7)	0.0510 (6)

	U11	U22	U33	U12	U13	U23
C1	0.0264 (13)	0.0235 (11)	0.0216 (12)	−0.0017 (11)	−0.0011 (11)	−0.0001 (9)
C2	0.0204 (12)	0.0216 (11)	0.0235 (12)	0.0004 (10)	0.0008 (10)	−0.0046 (9)
C3	0.0225 (12)	0.0197 (11)	0.0253 (12)	−0.0027 (10)	0.0022 (11)	−0.0003 (9)
C4	0.0265 (13)	0.0213 (11)	0.0230 (12)	0.0000 (11)	0.0013 (11)	−0.0005 (9)
C5	0.0247 (13)	0.0257 (11)	0.0259 (12)	0.0010 (10)	−0.0008 (11)	0.0006 (9)
C6	0.0295 (15)	0.0337 (13)	0.0309 (14)	0.0078 (12)	0.0020 (12)	−0.0011 (11)
C7	0.0297 (14)	0.0253 (11)	0.0248 (12)	0.0009 (11)	0.0044 (11)	0.0003 (10)
C8	0.0360 (16)	0.0430 (15)	0.0276 (14)	−0.0015 (13)	−0.0046 (13)	0.0055 (11)
C9	0.046 (2)	0.0437 (16)	0.0270 (14)	0.0015 (14)	−0.0033 (13)	0.0115 (12)
C10	0.0400 (17)	0.0347 (14)	0.0299 (14)	0.0026 (13)	0.0057 (13)	0.0056 (11)
C11	0.0287 (14)	0.0391 (14)	0.0382 (16)	0.0037 (12)	0.0046 (13)	0.0074 (12)
C12	0.0332 (16)	0.0394 (14)	0.0290 (14)	0.0050 (13)	0.0043 (12)	0.0097 (11)
C13	0.0493 (19)	0.0431 (16)	0.0393 (17)	0.0007 (15)	0.0052 (15)	0.0149 (13)
C14	0.074 (3)	0.065 (2)	0.059 (2)	−0.012 (2)	0.029 (2)	−0.0096 (17)
C15	0.076 (3)	0.062 (2)	0.066 (2)	−0.023 (2)	0.017 (2)	0.0088 (18)
C16	0.0278 (14)	0.0338 (13)	0.0237 (13)	0.0067 (12)	−0.0010 (11)	0.0011 (10)
C17	0.0434 (18)	0.0376 (14)	0.0474 (17)	0.0151 (14)	0.0015 (15)	−0.0033 (13)
C18	0.0295 (13)	0.0244 (11)	0.0265 (13)	0.0036 (11)	0.0040 (12)	0.0005 (9)
C19	0.0407 (16)	0.0323 (13)	0.0455 (16)	0.0004 (13)	0.0207 (15)	−0.0010 (12)
C20	0.0327 (15)	0.0252 (12)	0.0409 (15)	0.0023 (11)	0.0092 (13)	0.0066 (11)
C21	0.067 (2)	0.0324 (14)	0.0452 (17)	0.0067 (15)	0.0005 (17)	0.0119 (13)
C22	0.052 (2)	0.0367 (15)	0.0510 (18)	0.0163 (15)	0.0011 (17)	−0.0032 (14)
C23	0.077 (3)	0.0392 (16)	0.079 (3)	0.0126 (19)	−0.018 (2)	−0.0202 (17)
O1	0.0287 (10)	0.0289 (8)	0.0217 (8)	0.0038 (7)	0.0024 (8)	0.0015 (7)
O2	0.0272 (10)	0.0340 (9)	0.0236 (9)	−0.0010 (8)	0.0008 (8)	0.0046 (7)
O3	0.0257 (10)	0.0223 (8)	0.0291 (9)	0.0039 (7)	−0.0011 (8)	−0.0021 (7)
O4	0.0261 (10)	0.0378 (10)	0.0564 (13)	0.0012 (9)	−0.0027 (10)	−0.0023 (9)
O5	0.0251 (9)	0.0213 (7)	0.0283 (9)	−0.0018 (7)	0.0070 (8)	−0.0022 (7)
O6	0.0433 (12)	0.0332 (10)	0.0439 (11)	−0.0046 (9)	0.0128 (10)	−0.0138 (8)
O7	0.0336 (10)	0.0221 (8)	0.0283 (9)	0.0029 (7)	−0.0002 (8)	0.0025 (7)
O8	0.0837 (18)	0.0234 (9)	0.0542 (13)	−0.0053 (11)	−0.0061 (13)	0.0034 (9)
O9	0.0466 (12)	0.0302 (9)	0.0343 (10)	0.0134 (9)	−0.0038 (10)	−0.0072 (7)
O10	0.0699 (18)	0.0433 (12)	0.109 (2)	0.0250 (13)	−0.0303 (16)	−0.0047 (13)
O11	0.0628 (16)	0.0706 (15)	0.0365 (12)	−0.0076 (14)	0.0116 (11)	0.0106 (11)
O12	0.0476 (13)	0.0543 (13)	0.0511 (13)	−0.0148 (12)	0.0048 (11)	0.0135 (10)

C1—O2	1.400 (3)	C13—H13	1.0000
C1—O1	1.414 (3)	C14—O11	1.404 (4)
C1—C2	1.522 (3)	C14—H14A	0.9800
C1—H1	1.0000	C14—H14B	0.9800
C2—O3	1.444 (3)	C14—H14C	0.9800
C2—C3	1.516 (3)	C15—O12	1.412 (4)
C2—H2	1.0000	C15—H15A	0.9800
C3—O5	1.449 (3)	C15—H15B	0.9800
C3—C4	1.516 (3)	C15—H15C	0.9800
C3—H3	1.0000	C16—O4	1.198 (3)
C4—O7	1.449 (3)	C16—O3	1.348 (3)
C4—C5	1.530 (3)	C16—C17	1.495 (3)
C4—H4	1.0000	C17—H17A	0.9800
C5—O1	1.433 (3)	C17—H17B	0.9800
C5—C6	1.500 (3)	C17—H17C	0.9800
C5—H5	1.0000	C18—O6	1.198 (3)
C6—O9	1.439 (3)	C18—O5	1.357 (3)
C6—H6A	0.9900	C18—C19	1.495 (4)
C6—H6B	0.9900	C19—H19A	0.9800
C7—C12	1.373 (4)	C19—H19B	0.9800
C7—C8	1.383 (4)	C19—H19C	0.9800
C7—O2	1.394 (3)	C20—O8	1.198 (3)
C8—C9	1.387 (4)	C20—O7	1.359 (3)
C8—H8	0.9500	C20—C21	1.483 (4)
C9—C10	1.397 (4)	C21—H21A	0.9800
C9—H9	0.9500	C21—H21B	0.9800
C10—C11	1.372 (4)	C21—H21C	0.9800
C10—C13	1.506 (4)	C22—O10	1.195 (4)
C11—C12	1.390 (4)	C22—O9	1.341 (3)
C11—H11	0.9500	C22—C23	1.482 (5)
C12—H12	0.9500	C23—H23A	0.9800
C13—O12	1.395 (4)	C23—H23B	0.9800
C13—O11	1.417 (4)	C23—H23C	0.9800
O2—C1—O1	107.73 (17)	O11—C13—H13	107.8
O2—C1—C2	107.29 (19)	C10—C13—H13	107.8
O1—C1—C2	109.94 (18)	O11—C14—H14A	109.5
O2—C1—H1	110.6	O11—C14—H14B	109.5
O1—C1—H1	110.6	H14A—C14—H14B	109.5
C2—C1—H1	110.6	O11—C14—H14C	109.5
O3—C2—C3	110.26 (18)	H14A—C14—H14C	109.5
O3—C2—C1	105.40 (17)	H14B—C14—H14C	109.5
C3—C2—C1	109.29 (19)	O12—C15—H15A	109.5
O3—C2—H2	110.6	O12—C15—H15B	109.5
C3—C2—H2	110.6	H15A—C15—H15B	109.5
C1—C2—H2	110.6	O12—C15—H15C	109.5
O5—C3—C4	106.76 (17)	H15A—C15—H15C	109.5
O5—C3—C2	109.66 (19)	H15B—C15—H15C	109.5
C4—C3—C2	110.31 (18)	O4—C16—O3	123.5 (2)
O5—C3—H3	110.0	O4—C16—C17	126.2 (3)
C4—C3—H3	110.0	O3—C16—C17	110.2 (2)
C2—C3—H3	110.0	C16—C17—H17A	109.5
O7—C4—C3	106.83 (17)	C16—C17—H17B	109.5
O7—C4—C5	108.2 (2)	H17A—C17—H17B	109.5
C3—C4—C5	110.31 (18)	C16—C17—H17C	109.5
O7—C4—H4	110.5	H17A—C17—H17C	109.5
C3—C4—H4	110.5	H17B—C17—H17C	109.5
C5—C4—H4	110.5	O6—C18—O5	124.0 (2)
O1—C5—C6	107.67 (18)	O6—C18—C19	125.5 (2)
O1—C5—C4	108.10 (19)	O5—C18—C19	110.4 (2)
C6—C5—C4	113.56 (19)	C18—C19—H19A	109.5
O1—C5—H5	109.1	C18—C19—H19B	109.5
C6—C5—H5	109.1	H19A—C19—H19B	109.5
C4—C5—H5	109.1	C18—C19—H19C	109.5
O9—C6—C5	108.3 (2)	H19A—C19—H19C	109.5
O9—C6—H6A	110.0	H19B—C19—H19C	109.5
C5—C6—H6A	110.0	O8—C20—O7	122.9 (2)
O9—C6—H6B	110.0	O8—C20—C21	126.2 (2)
C5—C6—H6B	110.0	O7—C20—C21	110.9 (2)
H6A—C6—H6B	108.4	C20—C21—H21A	109.5
C12—C7—C8	120.7 (2)	C20—C21—H21B	109.5
C12—C7—O2	123.8 (2)	H21A—C21—H21B	109.5
C8—C7—O2	115.5 (2)	C20—C21—H21C	109.5
C7—C8—C9	119.1 (3)	H21A—C21—H21C	109.5
C7—C8—H8	120.5	H21B—C21—H21C	109.5
C9—C8—H8	120.5	O10—C22—O9	123.0 (3)
C8—C9—C10	121.0 (2)	O10—C22—C23	125.4 (3)
C8—C9—H9	119.5	O9—C22—C23	111.6 (3)
C10—C9—H9	119.5	C22—C23—H23A	109.5
C11—C10—C9	118.2 (3)	C22—C23—H23B	109.5
C11—C10—C13	122.5 (3)	H23A—C23—H23B	109.5
C9—C10—C13	119.2 (2)	C22—C23—H23C	109.5
C10—C11—C12	121.5 (3)	H23A—C23—H23C	109.5
C10—C11—H11	119.3	H23B—C23—H23C	109.5
C12—C11—H11	119.3	C1—O1—C5	112.28 (16)
C7—C12—C11	119.4 (2)	C7—O2—C1	117.00 (19)
C7—C12—H12	120.3	C16—O3—C2	117.93 (19)
C11—C12—H12	120.3	C18—O5—C3	118.07 (18)
O12—C13—O11	111.7 (3)	C20—O7—C4	117.55 (19)
O12—C13—C10	108.7 (2)	C22—O9—C6	117.8 (2)
O11—C13—C10	113.0 (2)	C14—O11—C13	114.9 (2)
O12—C13—H13	107.8	C13—O12—C15	113.2 (3)
O2—C1—C2—O3	67.0 (2)	C11—C10—C13—O11	−121.4 (3)
O1—C1—C2—O3	−176.06 (17)	C9—C10—C13—O11	60.5 (4)
O2—C1—C2—C3	−174.46 (17)	O2—C1—O1—C5	−178.82 (18)
O1—C1—C2—C3	−57.6 (2)	C2—C1—O1—C5	64.6 (2)
O3—C2—C3—O5	−74.1 (2)	C6—C5—O1—C1	173.20 (19)
C1—C2—C3—O5	170.47 (17)	C4—C5—O1—C1	−63.7 (2)
O3—C2—C3—C4	168.59 (18)	C12—C7—O2—C1	−4.1 (3)
C1—C2—C3—C4	53.2 (2)	C8—C7—O2—C1	175.4 (2)
O5—C3—C4—O7	69.5 (2)	O1—C1—O2—C7	76.8 (2)
C2—C3—C4—O7	−171.43 (18)	C2—C1—O2—C7	−164.91 (18)
O5—C3—C4—C5	−173.12 (18)	O4—C16—O3—C2	−3.5 (4)
C2—C3—C4—C5	−54.0 (3)	C17—C16—O3—C2	176.82 (19)
O7—C4—C5—O1	174.03 (16)	C3—C2—O3—C16	101.6 (2)
C3—C4—C5—O1	57.5 (2)	C1—C2—O3—C16	−140.5 (2)
O7—C4—C5—C6	−66.6 (2)	O6—C18—O5—C3	0.7 (3)
C3—C4—C5—C6	176.9 (2)	C19—C18—O5—C3	−178.8 (2)
O1—C5—C6—O9	60.3 (2)	C4—C3—O5—C18	−143.3 (2)
C4—C5—C6—O9	−59.4 (3)	C2—C3—O5—C18	97.2 (2)
C12—C7—C8—C9	−1.2 (4)	O8—C20—O7—C4	−2.4 (4)
O2—C7—C8—C9	179.4 (2)	C21—C20—O7—C4	177.8 (2)
C7—C8—C9—C10	−0.4 (4)	C3—C4—O7—C20	−135.4 (2)
C8—C9—C10—C11	2.7 (4)	C5—C4—O7—C20	105.8 (2)
C8—C9—C10—C13	−179.2 (3)	O10—C22—O9—C6	6.9 (5)
C9—C10—C11—C12	−3.5 (4)	C23—C22—O9—C6	−173.9 (3)
C13—C10—C11—C12	178.5 (3)	C5—C6—O9—C22	148.1 (2)
C8—C7—C12—C11	0.4 (4)	O12—C13—O11—C14	−61.7 (3)
O2—C7—C12—C11	179.8 (2)	C10—C13—O11—C14	61.2 (4)
C10—C11—C12—C7	2.0 (4)	O11—C13—O12—C15	−69.5 (3)
C11—C10—C13—O12	3.2 (4)	C10—C13—O12—C15	165.2 (3)
C9—C10—C13—O12	−174.9 (3)

D—H···A	D—H	H···A	D···A	D—H···A
C2—H2···O11i	1.00	2.44	3.347 (3)	151
C12—H12···O4ii	0.95	2.45	3.321 (3)	152
C19—H19A···O3iii	0.98	2.54	3.510 (3)	171
C19—H19C···O8iv	0.98	2.49	3.414 (3)	157
C21—H21C···O10iv	0.98	2.29	3.252 (4)	168
C23—H23C···Cgv	0.98	2.71	3.615 (4)	153

Table 1

Hydrogen-bond geometry (Å, °)

Cg is the centroid of the C7–C12 ring.

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C2—H2⋯O11i	1.00	2.44	3.347 (3)	151
C12—H12⋯O4ii	0.95	2.45	3.321 (3)	152
C19—H19A⋯O3iii	0.98	2.54	3.510 (3)	171
C19—H19C⋯O8iv	0.98	2.49	3.414 (3)	157
C21—H21C⋯O10iv	0.98	2.29	3.252 (4)	168
C23—H23C⋯Cgv	0.98	2.71	3.615 (4)	153

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .