Literature DB >> 22569751

Metallic organophosphates as catalysts in asymmetric synthesis: a return journey.

Alejandro Parra1, Silvia Reboredo, Ana M Martín Castro, José Alemán.   

Abstract

This perspective article provides a general overview of the most relevant topics in the applications of chiral metallic organophosphates. A brief introduction along with a historic comparative profile of the BINOL and phosphoric acid analogues are given. Next, a selection of the most outstanding uses of the catalysts according to the employed metal is presented.

Entities:  

Year:  2012        PMID： 22569751     DOI： 10.1039/c2ob25479d

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  3 in total

1.  A Nucleophilic Strategy for Enantioselective Intermolecular α-Amination: Access to Enantioenriched α-Arylamino Ketones.

Authors:  Dillon H Miles; Joan Guasch; F Dean Toste
Journal:  J Am Chem Soc       Date:  2015-06-12       Impact factor: 15.419

2.  Chiral-anion-dependent inversion of diastereo- and enantioselectivity in carbonyl crotylation via ruthenium-catalyzed butadiene hydrohydroxyalkylation.

Authors:  Emma L McInturff; Eiji Yamaguchi; Michael J Krische
Journal:  J Am Chem Soc       Date:  2012-12-12       Impact factor: 15.419

3.  Direct asymmetric N-propargylation of indoles and carbazoles catalyzed by lithium SPINOL phosphate.

Authors:  Yingcheng Wang; Sheng Wang; Wenyu Shan; Zhihui Shao
Journal:  Nat Commun       Date:  2020-01-13       Impact factor: 14.919
  3 in total

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