| Literature DB >> 22410674 |
Hiroaki Horie1, Takuya Kurahashi, Seijiro Matsubara.
Abstract
Nickel(0) catalyzed [4+2] cycloaddition of electron-deficient dienes to alkynes and subsequent aromatization gave highly substituted arenes. This formal inverse electron-demand Diels-Alder cycloaddition is attributed to the formation of a seven-membered nickelacycle from a diene and an alkyne. This journal is © The Royal Society of Chemistry 2012Entities:
Year: 2012 PMID： 22410674 DOI： 10.1039/c2cc30801k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222