Literature DB >> 22409600

Palladium-catalyzed one-pot diarylamine formation from nitroarenes and cyclohexanones.

Yanjun Xie1, Saiwen Liu, Yong Liu, Yuqing Wen, Guo-Jun Deng.   

Abstract

The first palladium-catalyzed diarylamine formation from nitroarenes and cyclohexanone derivatives using borrowed hydrogen is described. Various diarylamines were selectively obtained in good to excellent yields. The reaction tolerated a wide range of functionalities. The nitro reduction, cyclohexanone dehydrogenation, and imine formation and reduction were realized in a cascade without an external reducing reagent and oxidant.

Entities:  

Year:  2012        PMID： 22409600     DOI： 10.1021/ol3002442

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  9 in total

1.  Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products.

Authors:  Andrei V Iosub; Shannon S Stahl
Journal:  ACS Catal       Date:  2016-10-24       Impact factor: 13.084

2.  Palladium-catalyzed aerobic oxidative dehydrogenation of cyclohexenes to substituted arene derivatives.

Authors:  Andrei V Iosub; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2015-03-09       Impact factor: 15.419

3.  Aerobic oxidative Heck/dehydrogenation reactions of cyclohexenones: efficient access to meta-substituted phenols.

Authors:  Yusuke Izawa; Changwu Zheng; Shannon S Stahl
Journal:  Angew Chem Int Ed Engl       Date:  2013-02-19       Impact factor: 15.336

4.  Catalytic Aerobic Dehydrogenation of Nitrogen Heterocycles Using Heterogeneous Cobalt Oxide Supported on Nitrogen-Doped Carbon.

Authors:  Andrei V Iosub; Shannon S Stahl
Journal:  Org Lett       Date:  2015-09-02       Impact factor: 6.005

5.  Pd-catalyzed Semmler-Wolff reactions for the conversion of substituted cyclohexenone oximes to primary anilines.

Authors:  Wan Pyo Hong; Andrei V Iosub; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-09-04       Impact factor: 15.419

6.  Aerobic dehydrogenation of cyclohexanone to cyclohexenone catalyzed by Pd(DMSO)2(TFA)2: evidence for ligand-controlled chemoselectivity.

Authors:  Tianning Diao; Doris Pun; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-05-24       Impact factor: 15.419

7.  Aerobic dehydrogenation of cyclohexanone to phenol catalyzed by Pd(TFA)2/2-dimethylaminopyridine: evidence for the role of Pd nanoparticles.

Authors:  Doris Pun; Tianning Diao; Shannon S Stahl
Journal:  J Am Chem Soc       Date:  2013-05-24       Impact factor: 15.419

8.  Versatile routes for synthesis of diarylamines through acceptorless dehydrogenative aromatization catalysis over supported gold-palladium bimetallic nanoparticles.

Authors:  Kento Taniguchi; Xiongjie Jin; Kazuya Yamaguchi; Kyoko Nozaki; Noritaka Mizuno
Journal:  Chem Sci       Date:  2016-12-01       Impact factor: 9.825

9.  Au-Pd alloy nanoparticles supported on layered double hydroxide for heterogeneously catalyzed aerobic oxidative dehydrogenation of cyclohexanols and cyclohexanones to phenols.

Authors:  Xiongjie Jin; Kento Taniguchi; Kazuya Yamaguchi; Noritaka Mizuno
Journal:  Chem Sci       Date:  2016-05-06       Impact factor: 9.825
  9 in total

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