Literature DB >> 22407787

Electrostatics at the origin of the stability of phosphate-phosphate complexes locked by hydrogen bonds.

Ignasi Mata1, Ibon Alkorta, Elies Molins, Enrique Espinosa.   

Abstract

Stronger than you'd think: Ab initio calculations reveal that hydrogen bonds can lock phosphates into stable gas-phase complexes, showing that hydrogen bonding can overcome anion-anion repulsion. These complexes present a large energetic barrier of dissociation. The stability of the complexes can be explained in terms of the electrostatic interaction in the hydrogen-bond region.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22407787     DOI： 10.1002/cphc.201200068

Source DB:  PubMed          Journal:  Chemphyschem        ISSN： 1439-4235            Impact factor:   3.102


  9 in total

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Authors:  Jana M Holthoff; Robert Weiss; Sergiy V Rosokha; Stefan M Huber
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Authors:  Elisabeth M Fatila; Maren Pink; Eric B Twum; Jonathan A Karty; Amar H Flood
Journal:  Chem Sci       Date:  2018-02-20       Impact factor: 9.825

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Authors:  Jana M Holthoff; Elric Engelage; Robert Weiss; Stefan M Huber
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Authors:  Lasse Hunger; Loai Al-Sheakh; Dzmitry H Zaitsau; Sergey P Verevkin; Andreas Appelhagen; Alexander Villinger; Ralf Ludwig
Journal:  Chemistry       Date:  2022-07-13       Impact factor: 5.020

5.  Efficient stabilisation of a dihydrogenphosphate tetramer and a dihydrogenpyrophosphate dimer by a cyclic pseudopeptide containing 1,4-disubstituted 1,2,3-triazole moieties.

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Journal:  Chem Sci       Date:  2017-07-12       Impact factor: 9.825

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Journal:  Int J Mol Sci       Date:  2020-10-28       Impact factor: 5.923

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Authors:  Miquel Nuez-Martinez; Catarina I G Pinto; Joana F Guerreiro; Filipa Mendes; Fernanda Marques; Amanda Muñoz-Juan; Jewel Ann Maria Xavier; Anna Laromaine; Valeria Bitonto; Nicoletta Protti; Simonetta Geninatti Crich; Francesc Teixidor; Clara Viñas
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9.  Thermodynamically Stable Cationic Dimers in Carboxyl-Functionalized Ionic Liquids: The Paradoxical Case of "Anti-Electrostatic" Hydrogen Bonding.

Authors:  Loai Al-Sheakh; Sebastian Fritsch; Andreas Appelhagen; Alexander Villinger; Ralf Ludwig
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  9 in total

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