Literature DB >> 22407724

Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2)(NCS)(2)]⋅py.

Helena J Shepherd1, Tatiana Palamarciuc, Patrick Rosa, Philippe Guionneau, Gábor Molnár, Jean-François Létard, Azzedine Bousseksou.   

Abstract

A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2)(NCS)(2)]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 22407724     DOI： 10.1002/anie.201108919

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Extreme compressibility in LnFe(CN)6 coordination framework materials via molecular gears and torsion springs.

Authors:  Samuel G Duyker; Vanessa K Peterson; Gordon J Kearley; Andrew J Studer; Cameron J Kepert
Journal:  Nat Chem       Date:  2016-01-11       Impact factor: 24.427

2.  Giant negative linear compressibility in zinc dicyanoaurate.

Authors:  Andrew B Cairns; Jadna Catafesta; Claire Levelut; Jérôme Rouquette; Arie van der Lee; Lars Peters; Amber L Thompson; Vladimir Dmitriev; Julien Haines; Andrew L Goodwin
Journal:  Nat Mater       Date:  2013-01-20       Impact factor: 43.841

3.  Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation.

Authors:  Rafal Kulmaczewski; Laurence J Kershaw Cook; Christopher M Pask; Oscar Cespedes; Malcolm A Halcrow
Journal:  Cryst Growth Des       Date:  2022-02-04       Impact factor: 4.076

4.  Observation of a re-entrant phase transition in the molecular complex tris(μ2-3,5-diiso-propyl-1,2,4-triazolato-κ2N1:N2)trigold(I) under high pressure.

Authors:  Christopher H Woodall; Jeppe Christensen; Jonathan M Skelton; Lauren E Hatcher; Andrew Parlett; Paul R Raithby; Aron Walsh; Stephen C Parker; Christine M Beavers; Simon J Teat; Mourad Intissar; Christian Reber; David R Allan
Journal:  IUCrJ       Date:  2016-08-18       Impact factor: 4.769

Review 5.  A Molecular Approach to Quantum Sensing.

Authors:  Chung-Jui Yu; Stephen von Kugelgen; Daniel W Laorenza; Danna E Freedman
Journal:  ACS Cent Sci       Date:  2021-04-20       Impact factor: 14.553

6.  Hingeless negative linear compression in the mechanochromic gold complex [(C6F5Au)2(μ-1,4-diisocyanobenzene)].

Authors:  Christopher H Woodall; Christine M Beavers; Jeppe Christensen; Lauren E Hatcher; Mourad Intissar; Andrew Parlett; Simon J Teat; Christian Reber; Paul R Raithby
Journal:  Angew Chem Int Ed Engl       Date:  2013-08-02       Impact factor: 15.336

7.  H3O(+) tetrahedron induction in large negative linear compressibility.

Authors:  Hui Wang; Min Feng; Yu-Fang Wang; Zhi-Yuan Gu
Journal:  Sci Rep       Date:  2016-05-17       Impact factor: 4.379

8.  Thermally-Induced Spin Crossover and LIESST Effect in the Neutral [FeII(Mebik)2(NCX)2] Complexes: Variable-Temperature Structural, Magnetic, and Optical Studies (X = S, Se; Mebik = bis(1-methylimidazol-2-yl)ketone).

Authors:  Siddhartha De; Lise-Marie Chamoreau; Hasnaa El Said; Yanling Li; Alexandrine Flambard; Marie-Laure Boillot; Subrata Tewary; Gopalan Rajaraman; Rodrigue Lescouëzec
Journal:  Front Chem       Date:  2018-08-21       Impact factor: 5.221
  8 in total

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