Literature DB >> 22390391

Selective electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complexes.

Peng Kang1, Chen Cheng, Zuofeng Chen, Cynthia K Schauer, Thomas J Meyer, Maurice Brookhart.   

Abstract

Iridium dihydride complexes supported by PCP-type pincer ligands rapidly insert CO(2) to yield κ(2)-formate monohydride products in THF. In acetonitrile/water mixtures, these complexes become efficient and selective catalysts for electrocatalytic reduction of CO(2) to formate. Electrochemical and NMR spectroscopic studies have provided mechanistic details and structures of key intermediates.

Entities:  

Year:  2012        PMID： 22390391     DOI： 10.1021/ja300543s

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  19 in total

Review 1.  Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors:  Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal:  Chem Rev       Date:  2013-06-14       Impact factor: 60.622

2.  Directing the reactivity of metal hydrides for selective CO2 reduction.

Authors:  Bianca M Ceballos; Jenny Y Yang
Journal:  Proc Natl Acad Sci U S A       Date:  2018-11-21       Impact factor: 11.205

3.  Insight into catalytic reduction of CO2 to methane with silanes using Brookhart's cationic Ir(iii) pincer complex.

Authors:  Shaoqin Fang; Hongcai Chen; Haiyan Wei
Journal:  RSC Adv       Date:  2018-03-02       Impact factor: 4.036

4.  CO2 Reduction Catalyzed by Nitrogenase: Pathways to Formate, Carbon Monoxide, and Methane.

Authors:  Nimesh Khadka; Dennis R Dean; Dayle Smith; Brian M Hoffman; Simone Raugei; Lance C Seefeldt
Journal:  Inorg Chem       Date:  2016-08-08       Impact factor: 5.165

5.  Carbon Dioxide Insertion into Bridging Iron Hydrides: Kinetic and Mechanistic Studies.

Authors:  Dae Ho Hong; Leslie J Murray
Journal:  Eur J Inorg Chem       Date:  2019-01-29       Impact factor: 2.524

6.  Access to Metal Centers and Fluxional Hydride Coordination Integral for CO2 Insertion into [Fe3(μ-H)3]3+ Clusters.

Authors:  Dae Ho Hong; Ricardo B Ferreira; Vincent J Catalano; Ricardo García-Serres; Jason Shearer; Leslie J Murray
Journal:  Inorg Chem       Date:  2021-04-26       Impact factor: 5.165

Review 7.  Transition Metal Complexes as Catalysts for the Electroconversion of CO2 : An Organometallic Perspective.

Authors:  Niklas W Kinzel; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2021-01-19       Impact factor: 15.336

8.  Bio-inspired cofacial Fe porphyrin dimers for efficient electrocatalytic CO2 to CO conversion: Overpotential tuning by substituents at the porphyrin rings.

Authors:  Zaki N Zahran; Eman A Mohamed; Yoshinori Naruta
Journal:  Sci Rep       Date:  2016-04-18       Impact factor: 4.379

9.  Carbon Dioxide Utilization by the Five-Membered Ring Products of Cyclometalation Reactions.

Authors:  Iwao Omae
Journal:  Curr Org Chem       Date:  2016-04       Impact factor: 2.180

10.  Oxidation-State-Dependent Binding Properties of the Active Site in a Mo-Containing Formate Dehydrogenase.

Authors:  William E Robinson; Arnau Bassegoda; Erwin Reisner; Judy Hirst
Journal:  J Am Chem Soc       Date:  2017-07-17       Impact factor: 15.419
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