Literature DB >> 22378689

Copper-catalyzed C-H oxidation/cross-coupling of α-amino carbonyl compounds.

Ji-Cheng Wu1, Ren-Jie Song, Zhi-Qiang Wang, Xiao-Cheng Huang, Ye-Xiang Xie, Jin-Heng Li.   

Abstract

Keeping options open: the new and mild title reaction involving indoles selectively furnishes 1 and 2 with the aid of tert-butyl hydroperoxide (TBHP). The method represents the first example of a copper-catalyzed α arylation of α-amino carbonyl substrates leading to α-aryl α-imino and α-aryl α-oxo carbonyl compounds using a C-H oxidation strategy.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Year:  2012        PMID： 22378689     DOI： 10.1002/anie.201109027

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Vanadium-catalyzed oxidative Strecker reaction: α-C-H cyanation of para-methoxyphenyl (PMP)-protected primary amines.

Authors:  Chen Zhu; Ji-Bao Xia; Chuo Chen
Journal:  Tetrahedron Lett       Date:  2014-01-01       Impact factor: 2.415

2.  Nickel or phenanthroline mediated intramolecular arylation of sp3 C-H bonds using aryl halides.

Authors:  William C Wertjes; Lydia C Wolfe; Peter J Waller; Dipannita Kalyani
Journal:  Org Lett       Date:  2013-11-20       Impact factor: 6.005

3.  Synthesis of Symmetric and Unsymmetric Secondary Amines from the Ligand-Promoted Ruthenium-Catalyzed Deaminative Coupling Reaction of Primary Amines.

Authors:  Pandula T Kirinde Arachchige; Hanbin Lee; Chae S Yi
Journal:  J Org Chem       Date:  2018-04-24       Impact factor: 4.354

4.  Photoredox Cross-Dehydrogenative Coupling of N-Aryl Glycines Mediated by Mesoporous Graphitic Carbon Nitride: An Environmentally Friendly Approach to the Synthesis of Non-Proteinogenic α-Amino Acids (NPAAs) Decorated with Indoles.

Authors:  Lorenzo Poletti; Daniele Ragno; Olga Bortolini; Francesco Presini; Fabio Pesciaioli; Stefano Carli; Stefano Caramori; Alessandra Molinari; Alessandro Massi; Graziano Di Carmine
Journal:  J Org Chem       Date:  2022-05-27       Impact factor: 4.198

5.  One-Pot Three-Component Coupling Reaction of α-Amino Aryl Ketones, Indoles, and Perbromomethane Under Mild Conditions.

Authors:  Hao Lu; Yuxuan Liu; Wei Deng; Renhua Qiu; Jiannan Xiang
Journal:  Front Chem       Date:  2022-02-04       Impact factor: 5.221

6.  Palladium-catalyzed oxidative cross-coupling for the synthesis of α-amino ketones.

Authors:  Xiao-Hong Wei; Zhen-Hua Li; Lian-Biao Zhao; Ping Zhang; Han-Cheng Zhou; Yan-Bin Wang
Journal:  RSC Adv       Date:  2019-10-09       Impact factor: 4.036

7.  Copper-catalyzed diastereoselective aerobic intramolecular dehydrogenative coupling of hydrazones via sp3 C-H functionalization.

Authors:  Xuesong Wu; Mian Wang; Guangwu Zhang; Yan Zhao; Jianyi Wang; Haibo Ge
Journal:  Chem Sci       Date:  2015-07-14       Impact factor: 9.825
  7 in total

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