| Literature DB >> 22374838 |
Shinobu Aoyagi1, Yuki Sado, Eiji Nishibori, Hiroshi Sawa, Hiroshi Okada, Hiromi Tobita, Yasuhiko Kasama, Ryo Kitaura, Hisanori Shinohara.
Abstract
Rock solid: fullerene-encapsulated Li(+) (Li(+)@C(60)) is an alkaline cation owing to the spherical shape and positive charge. Li(+)@C(60) crystallizes as a rock-salt-type crystal in the presence of PF(6)(-). The orientations of C(60) and PF(6)(-) (orange) are perfectly ordered below 370 K, and Li(+) (purple) hops within the cage. At temperatures below 100 K two Li(+) units are localized at two polar positions within each C(60) .Entities:
Year: 2012 PMID： 22374838 DOI： 10.1002/anie.201108551
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336