Literature DB >> 22344371

Access to catenated and branched polyphosphorus ligands and coordination complexes via a tri(pyrazolyl)phosphane.

Kai-Oliver Feldmann1, Roland Fröhlich, Jan J Weigand.   

Abstract

We report a convenient and smooth protocol for the high-yielding synthesis of a triphosphane and an iso-tetraphosphane from a readily accessible tri(pyrazolyl)phosphane. The products are obtained from a one-pot reaction at room temperature and form complexes with the Fe(CO)(4)-fragment.

Entities:  

Year:  2012        PMID： 22344371     DOI： 10.1039/c2cc18030h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  P-P Condensation and P-N/P-P Bond Metathesis: Facile Synthesis of Cationic Tri- and Tetraphosphanes.

Authors:  Clemens Taube; Kai Schwedtmann; Medena Noikham; Ekasith Somsook; Felix Hennersdorf; Robert Wolf; Jan J Weigand
Journal:  Angew Chem Int Ed Engl       Date:  2019-12-30       Impact factor: 15.336

2.  Coordination Chemistry and Methylation of Mixed-Substituted Tetraphosphetanes (RP-PtBu)2 (R=Ph, Py).

Authors:  Robin Schoemaker; Philipp Kossatz; Kai Schwedtmann; Felix Hennersdorf; Jan J Weigand
Journal:  Chemistry       Date:  2020-08-17       Impact factor: 5.236

3.  Controlled scrambling reactions to polyphosphanes via bond metathesis reactions.

Authors:  Robin Schoemaker; Kai Schwedtmann; Antonio Franconetti; Antonio Frontera; Felix Hennersdorf; Jan J Weigand
Journal:  Chem Sci       Date:  2019-10-17       Impact factor: 9.825
  3 in total

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