| Literature DB >> 22335235 |
Yayoi Sawada1, Seiichi Furumi, Atsuro Takai, Masayuki Takeuchi, Keiichi Noguchi, Ken Tanaka.
Abstract
The highly enantioselective synthesis of helically chiral 1,1'-bitriphenylenes has been achieved via rhodium-catalyzed double [2 + 2 + 2] cycloaddition of biaryl-linked tetraynes with 1,4-diynes (up to 93% ee). Crystal structures and photophysical properties of these helically chiral 1,1'-bitriphenylenes have also been studied.Entities:
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Year: 2012 PMID: 22335235 DOI: 10.1021/ja300278e
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419