Literature DB >> 30714652

Phosphahelicenes: From Chiroptical and Photophysical Properties to OLED Applications.

Keihann Yavari1, Wylliam Delaunay2, Nicolas De Rycke2,3, Thibault Reynaldo2, Paul Aillard1, Monika Srebro-Hooper4, Victoria Y Chang5, Gilles Muller5, Denis Tondelier6, Bernard Geffroy7, Arnaud Voituriez1, Angela Marinetti1, Muriel Hissler2, Jeanne Crassous2.   

Abstract

Herein, the experimental physicochemical and chiroptical properties of a series of phosphahelicenes are reported, focusing on their UV/Vis absorption, luminescence, electronic circular dichroism, optical rotations, and circularly polarized luminescence. Furthermore, detailed analysis of absorption and ECD spectra performed with the help of quantum-chemical calculations allowed us to highlight general features of these helicenic phosphines. Finally, due to well-suited electrochemical properties and thermal stability, the systems were successfully used as emitters in organic light-emitting diodes.
© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  OLEDs; circular dichroism; luminescence; phosphahelicenes; quantum chemical calculations

Year:  2019        PMID： 30714652      PMCID： PMC7063663          DOI： 10.1002/chem.201806140

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  50 in total

1.  2,2'-Biphospholes: building blocks for tuning the HOMO-LUMO gap of π-systems using covalent bonding and metal coordination.

Authors:  Hui Chen; Wylliam Delaunay; Liujian Yu; Damien Joly; Zuoyong Wang; Jin Li; Zisu Wang; Christophe Lescop; Denis Tondelier; Bernard Geffroy; Zheng Duan; Muriel Hissler; François Mathey; Régis Réau
Journal:  Angew Chem Int Ed Engl       Date:  2011-11-14       Impact factor: 15.336

2.  enantio-Enriched CPL-active helicene-bipyridine-rhenium complexes.

Authors:  Nidal Saleh; Monika Srebro; Thibault Reynaldo; Nicolas Vanthuyne; Loïc Toupet; Victoria Y Chang; Gilles Muller; J A Gareth Williams; Christian Roussel; Jochen Autschbach; Jeanne Crassous
Journal:  Chem Commun (Camb)       Date:  2015-03-04       Impact factor: 6.222

3.  Toward functional pi-conjugated organophosphorus materials: design of phosphole-based oligomers for electroluminescent devices.

Authors:  Hai-Ching Su; Omrane Fadhel; Chih-Jen Yang; Ting-Yi Cho; Claire Fave; Muriel Hissler; Chung-Chih Wu; Régis Réau
Journal:  J Am Chem Soc       Date:  2006-01-25       Impact factor: 15.419

4.  Synthesis of New Phosphahelicene Scaffolds and Development of Gold(I)-Catalyzed Enantioselective Allenene Cyclizations.

Authors:  Paul Aillard; Pascal Retailleau; Arnaud Voituriez; Angela Marinetti
Journal:  Chemistry       Date:  2015-07-14       Impact factor: 5.236

5.  Delocalization error and "functional tuning" in Kohn-Sham calculations of molecular properties.

Authors:  Jochen Autschbach; Monika Srebro
Journal:  Acc Chem Res       Date:  2014-06-26       Impact factor: 22.384

6.  π-Conjugated phospholes and their incorporation into devices: components with a great deal of potential.

Authors:  M P Duffy; W Delaunay; P-A Bouit; M Hissler
Journal:  Chem Soc Rev       Date:  2016-05-25       Impact factor: 54.564

7.  Enantiopure Cycloiridiated Complexes Bearing a Pentahelicenic N-Heterocyclic Carbene and Displaying Long-Lived Circularly Polarized Phosphorescence.

Authors:  Nora Hellou; Monika Srebro-Hooper; Ludovic Favereau; Francesco Zinna; Elsa Caytan; Loïc Toupet; Vincent Dorcet; Marion Jean; Nicolas Vanthuyne; J A Gareth Williams; Lorenzo Di Bari; Jochen Autschbach; Jeanne Crassous
Journal:  Angew Chem Int Ed Engl       Date:  2017-06-12       Impact factor: 15.336

Review 8.  Computing chiroptical properties with first-principles theoretical methods: background and illustrative examples.

Authors:  Jochen Autschbach
Journal:  Chirality       Date:  2009       Impact factor: 2.437

9.  Facile synthetic route to highly luminescent sila[7]helicene.

Authors:  Hiromi Oyama; Koji Nakano; Takunori Harada; Reiko Kuroda; Masanobu Naito; Kazuyuki Nobusawa; Kyoko Nozaki
Journal:  Org Lett       Date:  2013-04-15       Impact factor: 6.005

10.  Exciton coupling in diketopyrrolopyrrole-helicene derivatives leads to red and near-infrared circularly polarized luminescence.

Authors:  Kais Dhbaibi; Ludovic Favereau; Monika Srebro-Hooper; Marion Jean; Nicolas Vanthuyne; Francesco Zinna; Bassem Jamoussi; Lorenzo Di Bari; Jochen Autschbach; Jeanne Crassous
Journal:  Chem Sci       Date:  2017-11-15       Impact factor: 9.825
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  4 in total

1.  Synthesis of triphenylene-fused phosphole oxides via C-H functionalizations.

Authors:  Md Shafiqur Rahman; Naohiko Yoshikai
Journal:  Beilstein J Org Chem       Date:  2020-03-27       Impact factor: 2.883

2.  Synthesis, Characterization, and Thin-Film Transistor Response of Benzo[i]pentahelicene-3,6-dione.

Authors:  Maria Paola Bracciale; Guhyun Kwon; Dongil Ho; Choongik Kim; Maria Laura Santarelli; Assunta Marrocchi
Journal:  Molecules       Date:  2022-01-27       Impact factor: 4.411

3.  Induced axial chirality by a tight belt: naphthalene chromophores fixed in a 2,5-substituted cofacial para-phenylene-ethynylene framework.

Authors:  Eric Sidler; Juraj Malinčík; Alessandro Prescimone; Marcel Mayor
Journal:  J Mater Chem C Mater       Date:  2021-07-28       Impact factor: 7.393

4.  Spatiotemporal Mapping of Efficient Chiral Induction by Helicene-Type Additives in Copolymer Thin Films.

Authors:  Marius Morgenroth; Mirko Scholz; Laure Guy; Kawon Oum; Thomas Lenzer
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-23       Impact factor: 16.823
  4 in total

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