| Literature DB >> 22332783 |
Yaojia Jiang1, Wei Chuen Chan, Cheol-Min Park.
Abstract
An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement of α-oximino ketenes derived from α-diazo oxime ethers provides 2H-azirines bearing quaternary centers and allows for subsequent rearrangement to highly substituted pyrroles in excellent yields.Entities:
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Year: 2012 PMID： 22332783 DOI： 10.1021/ja300552c
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419