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Literature DB >> 22280096

Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes.

Tendai Gadzikwa¹, Rosalba Bellini, Henk L Dekker, Joost N H Reek.

Abstract

A chiral supramolecular ligand has been assembled and applied to the rhodium-catalyzed asymmetric hydroformylation of unfunctionalized internal alkenes. Spatial confinement of the metal center within a chiral pocket results in reversed regioselectivity and remarkable enantioselectivities.

Year: 2012 PMID： 22280096 DOI： 10.1021/ja211455j

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

13 in total

1. ORGANIC CHEMISTRY. Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines.

Authors: Yang Yang; Shi-Liang Shi; Dawen Niu; Peng Liu; Stephen L Buchwald
Journal: Science Date: 2015-07-03 Impact factor: 47.728

2. Ligand scaffold optimization of a supramolecular hydrogenation catalyst: Analyzing the influence of key structural subunits on reactivity and selectivity.

Authors: Nathan C Thacker; Shin A Moteki; James M Takacs
Journal: ACS Catal Date: 2012-11-05 Impact factor: 13.084

Self-assembly of a confined rhodium catalyst for asymmetric hydroformylation of unfunctionalized internal alkenes.

1. ORGANIC CHEMISTRY. Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines.

2. Ligand scaffold optimization of a supramolecular hydrogenation catalyst: Analyzing the influence of key structural subunits on reactivity and selectivity.

Review 3. Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes.

4. Distal-selective hydroformylation using scaffolding catalysis.

5. Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction.

Review 6. Supramolecular Approaches To Control Activity and Selectivity in Hydroformylation Catalysis.

7. Silicon-oriented regio- and enantioselective rhodium-catalyzed hydroformylation.

8. Ligand Template Strategies for Catalyst Encapsulation.

9. Synthesis and Characterization of Self-Assembled Chiral Fe^II ₂ L₃ Cages.

10. Selective Co-Encapsulation Inside an M₆ L₄ Cage.