Literature DB >> 22266945

Ligand denticity controls enantiomeric preference in DNA-based asymmetric catalysis.

Arnold J Boersma1, Bas de Bruin, Ben L Feringa, Gerard Roelfes.   

Abstract

DNA-based catalysis can be used to control the enantioselectivity of copper-catalysed Diels-Alder and Friedel-Crafts reactions to produce either enantiomer of the product by changing the denticity of the ligand coordinated to the Cu(II) ion, even though the DNA adopts a right handed helical conformation only. This journal is © The Royal Society of Chemistry 2012

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Year:  2012        PMID： 22266945     DOI： 10.1039/c2cc17350f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Protein design: toward functional metalloenzymes.

Authors:  Fangting Yu; Virginia M Cangelosi; Melissa L Zastrow; Matteo Tegoni; Jefferson S Plegaria; Alison G Tebo; Catherine S Mocny; Leela Ruckthong; Hira Qayyum; Vincent L Pecoraro
Journal:  Chem Rev       Date:  2014-03-24       Impact factor: 60.622

2.  A Localized Enantioselective Catalytic Site on Short DNA Sequences and Their Amphiphiles.

Authors:  Jun Guo; Danyu Wang; Evangelia Pantatosaki; Huihui Kuang; George K Papadopoulos; Michael Tsapatsis; Efrosini Kokkoli
Journal:  JACS Au       Date:  2022-01-20

Review 3.  DNA as a chiral scaffold for asymmetric synthesis.

Authors:  Soyoung Park; Hiroshi Sugiyama
Journal:  Molecules       Date:  2012-10-31       Impact factor: 4.411
  3 in total

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