1-Benzyl-4-chloro-indoline-2,3-dione.

There are two independent mol-ecules in the asymmetric unit of the title compound, C(15)H(10)ClNO(2), which differ in the dihedral angles between the mean planes of the phenyl ring and the 4-chloro-indoline-2,3-dione ring system [59.48 (9) and 79.0 (1)°]. In the crystal, mol-ecules are linked through C-H⋯O hydrogen bonds, forming polymeric chains in [100].

Related literature

For the preparation, see: Bouhfid et al. (2005 ▶). For a related structure and background to isatin derivatives, see: Liu et al. (2011 ▶). For reference bond-length data, see: Allen et al. (1987 ▶).

Experimental

Crystal data

C15H10ClNO2

M = 271.69

Orthorhombic,

a = 22.864 (5) Å

b = 16.600 (3) Å

c = 13.335 (3) Å

V = 5061.2 (18) Å3

Z = 16

Mo Kα radiation

μ = 0.30 mm−1

T = 293 K

0.30 × 0.20 × 0.10 mm

Data collection

Enraf–Nonius CAD-4 diffractometer

Absorption correction: ψ scan (North et al., 1968 ▶) T min = 0.916, T max = 0.971

4623 measured reflections

4623 independent reflections

1929 reflections with I > 2σ(I)

3 standard reflections every 200 reflections intensity decay: 1%

Refinement

R[F 2 > 2σ(F 2)] = 0.064

wR(F 2) = 0.117

S = 1.00

4623 reflections

343 parameters

H-atom parameters constrained

Δρmax = 0.18 e Å−3

Δρmin = −0.20 e Å−3

Data collection: CAD-4 EXPRESS (Enraf–Nonius, 1994 ▶); cell refinement: CAD-4 EXPRESS; data reduction: XCAD4 (Harms & Wocadlo,1995 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: PLATON (Spek, 2009 ▶).

Crystal structure: contains datablock(s) global, I. DOI: 10.1107/S1600536811051816/hb6540sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536811051816/hb6540Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811051816/hb6540Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C15H10ClNO2	F(000) = 2240
Mr = 271.69	Dx = 1.426 Mg m−3
Orthorhombic, Pbca	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ac 2ab	Cell parameters from 25 reflections
a = 22.864 (5) Å	θ = 9–13°
b = 16.600 (3) Å	µ = 0.30 mm−1
c = 13.335 (3) Å	T = 293 K
V = 5061.2 (18) Å3	Block, yellow
Z = 16	0.30 × 0.20 × 0.10 mm

Enraf–Nonius CAD-4 diffractometer	1929 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.000
graphite	θmax = 25.4°, θmin = 1.8°
ω/2θ scans	h = 0→27
Absorption correction: ψ scan (North et al., 1968)	k = 0→20
Tmin = 0.916, Tmax = 0.971	l = 0→16
4623 measured reflections	3 standard reflections every 200 reflections
4623 independent reflections	intensity decay: 1%

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.064	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.117	H-atom parameters constrained
S = 1.00	w = 1/[σ2(Fo2) + (0.032P)2] where P = (Fo2 + 2Fc2)/3
4623 reflections	(Δ/σ)max = 0.001
343 parameters	Δρmax = 0.18 e Å−3
0 restraints	Δρmin = −0.20 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cl1	0.61720 (4)	0.52555 (7)	0.54905 (10)	0.0902 (4)
C1	0.73389 (14)	0.5069 (2)	0.5352 (3)	0.0438 (9)
N1	0.83104 (11)	0.47219 (17)	0.5229 (2)	0.0506 (8)
O1	0.82562 (10)	0.33371 (14)	0.5350 (2)	0.0681 (8)
O2	0.70097 (10)	0.36781 (14)	0.5538 (2)	0.0628 (8)
C2	0.68738 (15)	0.5601 (2)	0.5384 (3)	0.0522 (10)
C3	0.69793 (18)	0.6420 (2)	0.5343 (3)	0.0644 (12)
H3A	0.6671	0.6785	0.5358	0.077*
C4	0.7549 (2)	0.6687 (2)	0.5278 (3)	0.0649 (12)
H4A	0.7617	0.7239	0.5269	0.078*
C5	0.80188 (17)	0.6178 (2)	0.5228 (3)	0.0540 (11)
H5A	0.8398	0.6375	0.5173	0.065*
C6	0.79077 (15)	0.5362 (2)	0.5261 (3)	0.0452 (9)
C7	0.80405 (15)	0.3997 (2)	0.5335 (3)	0.0490 (10)
C8	0.73753 (16)	0.4189 (2)	0.5423 (3)	0.0489 (10)
C9	0.89331 (15)	0.4816 (2)	0.5095 (3)	0.0576 (11)
H9A	0.9002	0.5207	0.4567	0.069*
H9B	0.9096	0.4306	0.4876	0.069*
C10	0.92469 (15)	0.5083 (2)	0.6021 (3)	0.0525 (10)
C11	0.96343 (16)	0.5718 (2)	0.5974 (3)	0.0721 (13)
H11A	0.9693	0.5990	0.5373	0.086*
C12	0.9933 (2)	0.5946 (3)	0.6822 (5)	0.0975 (17)
H12A	1.0196	0.6373	0.6790	0.117*
C13	0.9849 (2)	0.5558 (4)	0.7704 (5)	0.1020 (19)
H13A	1.0054	0.5717	0.8273	0.122*
C14	0.9457 (2)	0.4926 (3)	0.7757 (4)	0.0911 (15)
H14A	0.9398	0.4657	0.8360	0.109*
C15	0.91552 (17)	0.4698 (2)	0.6912 (3)	0.0674 (12)
H15A	0.8886	0.4279	0.6947	0.081*
O3	0.78599 (12)	0.39116 (16)	0.7763 (2)	0.0807 (9)
O4	0.66106 (12)	0.42670 (16)	0.7850 (2)	0.0824 (9)
N2	0.65413 (13)	0.28816 (19)	0.7866 (2)	0.0596 (9)
Cl2	0.86828 (5)	0.23348 (8)	0.78394 (10)	0.1009 (5)
C16	0.69392 (17)	0.2242 (2)	0.7838 (3)	0.0512 (10)
C17	0.6827 (2)	0.1434 (2)	0.7823 (3)	0.0699 (12)
H17A	0.6444	0.1245	0.7811	0.084*
C18	0.7288 (2)	0.0906 (2)	0.7827 (3)	0.0789 (14)
H18A	0.7214	0.0355	0.7817	0.095*
C19	0.7861 (2)	0.1170 (3)	0.7845 (3)	0.0767 (14)
H19A	0.8167	0.0802	0.7859	0.092*
C20	0.79739 (17)	0.1997 (3)	0.7842 (3)	0.0633 (11)
C21	0.75154 (15)	0.2526 (2)	0.7840 (3)	0.0506 (10)
C22	0.74875 (18)	0.3404 (2)	0.7816 (3)	0.0551 (11)
C23	0.68310 (19)	0.3602 (3)	0.7847 (3)	0.0618 (11)
C24	0.59128 (16)	0.2818 (3)	0.7776 (3)	0.0758 (13)
H24A	0.5827	0.2432	0.7252	0.091*
H24B	0.5764	0.3336	0.7556	0.091*
C25	0.55801 (16)	0.2574 (2)	0.8702 (3)	0.0587 (11)
C26	0.58256 (16)	0.2129 (2)	0.9452 (3)	0.0647 (12)
H26A	0.6223	0.2009	0.9437	0.078*
C27	0.5485 (2)	0.1861 (3)	1.0228 (3)	0.0774 (13)
H27A	0.5653	0.1545	1.0727	0.093*
C28	0.4906 (2)	0.2049 (3)	1.0284 (4)	0.0900 (16)
H28A	0.4677	0.1864	1.0813	0.108*
C29	0.46671 (18)	0.2517 (3)	0.9539 (5)	0.0910 (16)
H29A	0.4275	0.2662	0.9573	0.109*
C30	0.49984 (18)	0.2771 (2)	0.8754 (3)	0.0736 (13)
H30A	0.4830	0.3079	0.8249	0.088*

	U11	U22	U33	U12	U13	U23
Cl1	0.0555 (7)	0.0927 (9)	0.1224 (10)	0.0131 (6)	0.0004 (7)	0.0070 (8)
C1	0.046 (2)	0.043 (2)	0.042 (2)	0.0025 (19)	0.001 (2)	−0.0029 (19)
N1	0.0396 (17)	0.0442 (18)	0.068 (2)	−0.0015 (15)	0.0006 (17)	−0.0029 (18)
O1	0.0652 (17)	0.0403 (16)	0.099 (2)	0.0090 (14)	−0.0063 (16)	−0.0039 (16)
O2	0.0551 (16)	0.0472 (16)	0.086 (2)	−0.0117 (14)	−0.0087 (16)	−0.0008 (15)
C2	0.059 (2)	0.048 (2)	0.050 (3)	0.007 (2)	0.001 (2)	−0.002 (2)
C3	0.077 (3)	0.052 (3)	0.064 (3)	0.018 (2)	0.000 (3)	0.001 (2)
C4	0.096 (3)	0.048 (3)	0.051 (3)	0.002 (3)	0.001 (3)	−0.002 (2)
C5	0.066 (3)	0.040 (2)	0.056 (3)	−0.008 (2)	0.007 (2)	0.002 (2)
C6	0.050 (2)	0.043 (2)	0.043 (2)	0.0059 (19)	−0.0061 (19)	−0.001 (2)
C7	0.049 (2)	0.043 (2)	0.056 (3)	−0.001 (2)	−0.009 (2)	−0.002 (2)
C8	0.050 (2)	0.046 (3)	0.050 (3)	−0.007 (2)	−0.010 (2)	−0.005 (2)
C9	0.055 (2)	0.054 (3)	0.063 (3)	−0.002 (2)	0.010 (2)	0.000 (2)
C10	0.045 (2)	0.055 (3)	0.058 (3)	0.0001 (19)	0.007 (2)	0.001 (2)
C11	0.056 (3)	0.071 (3)	0.089 (4)	−0.019 (2)	0.008 (3)	−0.004 (3)
C12	0.066 (3)	0.097 (4)	0.129 (5)	−0.017 (3)	−0.007 (4)	−0.031 (4)
C13	0.081 (4)	0.126 (5)	0.099 (5)	0.016 (4)	−0.041 (4)	−0.041 (4)
C14	0.100 (4)	0.100 (4)	0.073 (4)	0.022 (3)	−0.012 (3)	0.006 (3)
C15	0.070 (3)	0.056 (3)	0.076 (3)	0.004 (2)	−0.006 (3)	0.002 (3)
O3	0.090 (2)	0.0580 (18)	0.095 (2)	−0.0212 (17)	0.0114 (19)	0.0033 (18)
O4	0.107 (2)	0.0579 (18)	0.082 (2)	0.0191 (17)	0.0051 (19)	0.0061 (18)
N2	0.057 (2)	0.059 (2)	0.063 (2)	−0.0011 (18)	0.003 (2)	0.003 (2)
Cl2	0.0643 (7)	0.1260 (11)	0.1124 (11)	0.0158 (8)	0.0084 (8)	0.0130 (9)
C16	0.068 (3)	0.042 (2)	0.044 (2)	−0.002 (2)	0.000 (2)	−0.001 (2)
C17	0.097 (3)	0.053 (3)	0.060 (3)	−0.018 (3)	0.010 (3)	−0.008 (3)
C18	0.137 (5)	0.039 (3)	0.060 (3)	0.003 (3)	0.008 (3)	0.000 (2)
C19	0.105 (4)	0.070 (3)	0.055 (3)	0.031 (3)	0.007 (3)	−0.002 (3)
C20	0.072 (3)	0.066 (3)	0.052 (3)	0.011 (2)	0.009 (2)	0.001 (2)
C21	0.061 (2)	0.044 (2)	0.047 (2)	−0.004 (2)	0.003 (2)	−0.0032 (19)
C22	0.073 (3)	0.048 (3)	0.044 (2)	−0.007 (2)	0.006 (2)	0.000 (2)
C23	0.084 (3)	0.052 (3)	0.049 (3)	0.008 (3)	0.007 (2)	0.000 (3)
C24	0.064 (3)	0.099 (3)	0.065 (3)	−0.002 (2)	−0.018 (3)	0.006 (3)
C25	0.047 (2)	0.069 (3)	0.060 (3)	0.002 (2)	−0.010 (2)	−0.005 (2)
C26	0.055 (3)	0.088 (3)	0.051 (3)	0.007 (2)	−0.002 (2)	−0.003 (3)
C27	0.087 (3)	0.082 (3)	0.063 (3)	0.012 (3)	0.012 (3)	−0.001 (3)
C28	0.090 (4)	0.092 (4)	0.088 (4)	−0.016 (3)	0.035 (3)	−0.023 (3)
C29	0.055 (3)	0.091 (4)	0.128 (5)	−0.001 (3)	0.011 (4)	−0.024 (4)
C30	0.057 (3)	0.074 (3)	0.090 (4)	0.002 (2)	−0.021 (3)	0.002 (3)

Cl1—C2	1.710 (4)	O3—C22	1.200 (4)
C1—C2	1.383 (4)	O4—C23	1.213 (4)
C1—C6	1.394 (4)	N2—C23	1.368 (4)
C1—C8	1.465 (4)	N2—C16	1.399 (4)
N1—C7	1.359 (4)	N2—C24	1.446 (4)
N1—C6	1.407 (4)	Cl2—C20	1.715 (4)
N1—C9	1.444 (4)	C16—C17	1.366 (4)
O1—C7	1.202 (4)	C16—C21	1.399 (4)
O2—C8	1.201 (4)	C17—C18	1.372 (5)
C2—C3	1.382 (4)	C17—H17A	0.9300
C3—C4	1.378 (5)	C18—C19	1.381 (5)
C3—H3A	0.9300	C18—H18A	0.9300
C4—C5	1.369 (5)	C19—C20	1.397 (5)
C4—H4A	0.9300	C19—H19A	0.9300
C5—C6	1.379 (4)	C20—C21	1.368 (5)
C5—H5A	0.9300	C21—C22	1.459 (5)
C7—C8	1.558 (4)	C22—C23	1.537 (5)
C9—C10	1.496 (5)	C24—C25	1.506 (5)
C9—H9A	0.9700	C24—H24A	0.9700
C9—H9B	0.9700	C24—H24B	0.9700
C10—C15	1.365 (5)	C25—C26	1.364 (5)
C10—C11	1.378 (4)	C25—C30	1.371 (5)
C11—C12	1.374 (6)	C26—C27	1.369 (5)
C11—H11A	0.9300	C26—H26A	0.9300
C12—C13	1.354 (6)	C27—C28	1.363 (5)
C12—H12A	0.9300	C27—H27A	0.9300
C13—C14	1.381 (6)	C28—C29	1.374 (6)
C13—H13A	0.9300	C28—H28A	0.9300
C14—C15	1.375 (5)	C29—C30	1.359 (5)
C14—H14A	0.9300	C29—H29A	0.9300
C15—H15A	0.9300	C30—H30A	0.9300
C2—C1—C6	119.8 (3)	C23—N2—C16	110.4 (3)
C2—C1—C8	132.7 (3)	C23—N2—C24	122.9 (4)
C6—C1—C8	107.5 (3)	C16—N2—C24	126.1 (3)
C7—N1—C6	111.6 (3)	C17—C16—N2	128.6 (4)
C7—N1—C9	123.8 (3)	C17—C16—C21	120.6 (4)
C6—N1—C9	124.6 (3)	N2—C16—C21	110.9 (3)
C3—C2—C1	119.5 (3)	C16—C17—C18	118.8 (4)
C3—C2—Cl1	119.8 (3)	C16—C17—H17A	120.6
C1—C2—Cl1	120.7 (3)	C18—C17—H17A	120.6
C4—C3—C2	118.9 (4)	C17—C18—C19	121.8 (4)
C4—C3—H3A	120.5	C17—C18—H18A	119.1
C2—C3—H3A	120.5	C19—C18—H18A	119.1
C5—C4—C3	123.1 (4)	C18—C19—C20	119.2 (4)
C5—C4—H4A	118.4	C18—C19—H19A	120.4
C3—C4—H4A	118.4	C20—C19—H19A	120.4
C4—C5—C6	117.4 (4)	C21—C20—C19	119.3 (4)
C4—C5—H5A	121.3	C21—C20—Cl2	121.0 (3)
C6—C5—H5A	121.3	C19—C20—Cl2	119.7 (4)
C5—C6—C1	121.2 (3)	C20—C21—C16	120.3 (4)
C5—C6—N1	128.4 (3)	C20—C21—C22	132.4 (4)
C1—C6—N1	110.4 (3)	C16—C21—C22	107.2 (3)
O1—C7—N1	128.5 (3)	O3—C22—C21	132.2 (4)
O1—C7—C8	125.9 (3)	O3—C22—C23	123.0 (4)
N1—C7—C8	105.6 (3)	C21—C22—C23	104.8 (3)
O2—C8—C1	132.3 (4)	O4—C23—N2	126.5 (4)
O2—C8—C7	123.0 (3)	O4—C23—C22	126.9 (4)
C1—C8—C7	104.8 (3)	N2—C23—C22	106.6 (3)
N1—C9—C10	113.7 (3)	N2—C24—C25	117.0 (3)
N1—C9—H9A	108.8	N2—C24—H24A	108.1
C10—C9—H9A	108.8	C25—C24—H24A	108.1
N1—C9—H9B	108.8	N2—C24—H24B	108.1
C10—C9—H9B	108.8	C25—C24—H24B	108.1
H9A—C9—H9B	107.7	H24A—C24—H24B	107.3
C15—C10—C11	119.7 (4)	C26—C25—C30	119.4 (4)
C15—C10—C9	120.4 (4)	C26—C25—C24	122.7 (4)
C11—C10—C9	119.8 (4)	C30—C25—C24	117.9 (4)
C12—C11—C10	119.5 (4)	C25—C26—C27	119.8 (4)
C12—C11—H11A	120.2	C25—C26—H26A	120.1
C10—C11—H11A	120.2	C27—C26—H26A	120.1
C13—C12—C11	120.8 (5)	C28—C27—C26	121.3 (5)
C13—C12—H12A	119.6	C28—C27—H27A	119.4
C11—C12—H12A	119.6	C26—C27—H27A	119.4
C12—C13—C14	119.8 (5)	C27—C28—C29	118.4 (5)
C12—C13—H13A	120.1	C27—C28—H28A	120.8
C14—C13—H13A	120.1	C29—C28—H28A	120.8
C15—C14—C13	119.5 (5)	C30—C29—C28	120.7 (4)
C15—C14—H14A	120.2	C30—C29—H29A	119.6
C13—C14—H14A	120.2	C28—C29—H29A	119.6
C10—C15—C14	120.5 (4)	C29—C30—C25	120.4 (4)
C10—C15—H15A	119.8	C29—C30—H30A	119.8
C14—C15—H15A	119.8	C25—C30—H30A	119.8
C6—C1—C2—C3	−1.2 (6)	C23—N2—C16—C17	−178.5 (4)
C8—C1—C2—C3	177.0 (4)	C24—N2—C16—C17	−7.2 (6)
C6—C1—C2—Cl1	179.7 (3)	C23—N2—C16—C21	2.4 (5)
C8—C1—C2—Cl1	−2.1 (6)	C24—N2—C16—C21	173.7 (4)
C1—C2—C3—C4	−0.5 (6)	N2—C16—C17—C18	−178.0 (4)
Cl1—C2—C3—C4	178.6 (3)	C21—C16—C17—C18	1.1 (6)
C2—C3—C4—C5	1.7 (6)	C16—C17—C18—C19	0.0 (7)
C3—C4—C5—C6	−1.1 (6)	C17—C18—C19—C20	−1.1 (7)
C4—C5—C6—C1	−0.7 (6)	C18—C19—C20—C21	1.2 (7)
C4—C5—C6—N1	−179.5 (3)	C18—C19—C20—Cl2	−178.7 (4)
C2—C1—C6—C5	1.8 (6)	C19—C20—C21—C16	−0.1 (6)
C8—C1—C6—C5	−176.8 (3)	Cl2—C20—C21—C16	179.7 (3)
C2—C1—C6—N1	−179.2 (3)	C19—C20—C21—C22	−178.6 (4)
C8—C1—C6—N1	2.2 (4)	Cl2—C20—C21—C22	1.3 (7)
C7—N1—C6—C5	176.6 (4)	C17—C16—C21—C20	−1.0 (6)
C9—N1—C6—C5	−3.8 (6)	N2—C16—C21—C20	178.2 (4)
C7—N1—C6—C1	−2.4 (4)	C17—C16—C21—C22	177.8 (3)
C9—N1—C6—C1	177.2 (3)	N2—C16—C21—C22	−3.0 (5)
C6—N1—C7—O1	−179.3 (4)	C20—C21—C22—O3	2.6 (8)
C9—N1—C7—O1	1.1 (6)	C16—C21—C22—O3	−176.0 (4)
C6—N1—C7—C8	1.4 (4)	C20—C21—C22—C23	−179.0 (4)
C9—N1—C7—C8	−178.2 (3)	C16—C21—C22—C23	2.4 (4)
C2—C1—C8—O2	−0.8 (8)	C16—N2—C23—O4	179.0 (4)
C6—C1—C8—O2	177.5 (4)	C24—N2—C23—O4	7.4 (7)
C2—C1—C8—C7	−179.6 (4)	C16—N2—C23—C22	−0.8 (4)
C6—C1—C8—C7	−1.3 (4)	C24—N2—C23—C22	−172.4 (3)
O1—C7—C8—O2	1.7 (6)	O3—C22—C23—O4	−2.2 (7)
N1—C7—C8—O2	−179.0 (3)	C21—C22—C23—O4	179.2 (4)
O1—C7—C8—C1	−179.3 (4)	O3—C22—C23—N2	177.6 (4)
N1—C7—C8—C1	−0.1 (4)	C21—C22—C23—N2	−1.0 (4)
C7—N1—C9—C10	−102.9 (4)	C23—N2—C24—C25	−109.5 (4)
C6—N1—C9—C10	77.5 (4)	C16—N2—C24—C25	80.3 (5)
N1—C9—C10—C15	49.4 (5)	N2—C24—C25—C26	−25.9 (6)
N1—C9—C10—C11	−131.1 (3)	N2—C24—C25—C30	158.0 (4)
C15—C10—C11—C12	1.2 (6)	C30—C25—C26—C27	2.3 (6)
C9—C10—C11—C12	−178.3 (4)	C24—C25—C26—C27	−173.8 (4)
C10—C11—C12—C13	−0.3 (7)	C25—C26—C27—C28	−1.9 (6)
C11—C12—C13—C14	−0.2 (8)	C26—C27—C28—C29	0.0 (7)
C12—C13—C14—C15	−0.1 (7)	C27—C28—C29—C30	1.5 (7)
C11—C10—C15—C14	−1.6 (6)	C28—C29—C30—C25	−1.1 (7)
C9—C10—C15—C14	177.9 (4)	C26—C25—C30—C29	−0.8 (6)
C13—C14—C15—C10	1.1 (7)	C24—C25—C30—C29	175.5 (4)

D—H···A	D—H	H···A	D···A	D—H···A
C3—H3A···O1i	0.93	2.58	3.228 (4)	127
C4—H4A···O2i	0.93	2.56	3.473 (4)	167
C18—H18A···O3ii	0.93	2.40	3.329 (4)	173
C19—H19A···O4ii	0.93	2.60	3.382 (6)	142
C26—H26A···O2iii	0.93	2.59	3.350 (4)	140
C29—H29A···O1iv	0.93	2.59	3.505 (5)	169

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C3—H3A⋯O1i	0.93	2.58	3.228 (4)	127
C4—H4A⋯O2i	0.93	2.56	3.473 (4)	167
C18—H18A⋯O3ii	0.93	2.40	3.329 (4)	173
C19—H19A⋯O4ii	0.93	2.60	3.382 (6)	142
C26—H26A⋯O2iii	0.93	2.59	3.350 (4)	140
C29—H29A⋯O1iv	0.93	2.59	3.505 (5)	169

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) .