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Literature DB >> 22256899

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines.

Shiguang Pan¹, Kohei Endo, Takanori Shibata.

Abstract

A cationic Ir(I)-C(3)-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

Entities: Chemical

Mesh：

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Year: 2012 PMID： 22256899 DOI： 10.1021/ol203318z

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

6 in total

1. A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination.

Authors: Saki Ichikawa; Shaolin Zhu; Stephen L Buchwald
Journal: Angew Chem Int Ed Engl Date: 2018-06-12 Impact factor: 15.336

2. Hydroamination versus Allylic Amination in Iridium-Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity.

Authors: Seung Wook Kim; Thomas Wurm; Gilmar A Brito; Woo-Ok Jung; Jason R Zbieg; Craig E Stivala; Michael J Krische
Journal: J Am Chem Soc Date: 2018-07-10 Impact factor: 15.419

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines.

1. A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination.

2. Hydroamination versus Allylic Amination in Iridium-Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity.

3. Gold(I)-catalyzed stereoconvergent, intermolecular enantioselective hydroamination of allenes.

4. Enantioselective hydroamination of unactivated terminal alkenes.

Review 5. Catalytic Enantioselective Functionalization of Unactivated Terminal Alkenes.

6. Catalytic asymmetric addition of an amine N-H bond across internal alkenes.