Literature DB >> 22183065

Self-adaptation of manganese-chloride arrangement toward high spin Mn5(μ-Cl)4 cluster-based metal-organic framework with S = 15/2.

Shao-Hsuan Lin1, Chen-I Yang, Ting-Shen Kuo, Ming-Hsi Chiang, Kung-Chung Hsu, Kuang-Lieh Lu.   

Abstract

The self-adaptation of manganese-chloride arrangement with the tripodal ligand 1,3,5-tris(benzimidazoyl-1-ylmethyl)-2,4,6-trimethylbenzene (Me(3)-TBzIm) afforded a rare 3D metal-organic framework, [Mn(5)Cl(10)(Me(3)-TBzIm)(4)](n) (1) showing a high spin ground state with S = 15/2.

Entities:  

Year:  2011        PMID: 22183065     DOI: 10.1039/c2dt11760f

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Experimental and theoretical investigation of intramolecular cooperativity in cyclic benzene trimer motif.

Authors:  Chakka Kiran Kumar; Shankar Deval Sathiyashivan; Dhanraj T Masram; K V Jovan Jose; Malaichamy Sathiyendiran
Journal:  RSC Adv       Date:  2019-01-04       Impact factor: 4.036

  1 in total

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