Literature DB >> 22085308

A unique non-catenane interlocked self-assembled supramolecular architecture and its photophysical properties.

Vaishali Vajpayee1, Young Ho Song, Timothy R Cook, Hyunuk Kim, Youngil Lee, Peter J Stang, Ki-Whan Chi.   

Abstract

A novel, interlocked, self-assembled (M(2)L(2))(2) molecular architecture was constructed from an arene-Ru acceptor and a 1,4-di(pyridin-4-yl)buta-1,3-diyne donor. Two M(2)L(2) units, with cavities of ~7.21 Å, spontaneously interlock, with one unit encapsulating a twin in a non-catenane fashion. The dimeric host-guest complex thus formed is unique among two-dimensional self-assemblies and is stabilized by π-π interactions between the M(2)L(2) units.
© 2011 American Chemical Society

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Year:  2011        PMID: 22085308      PMCID: PMC3235908          DOI: 10.1021/ja208495u

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  56 in total

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Journal:  J Am Chem Soc       Date:  2011-06-23       Impact factor: 15.419

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  5 in total

1.  Growth Inhibitory Activity of a Bis-benzimidazole-Bridged Arene Ruthenium Metalla-Rectangle and Prism.

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  5 in total

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