Literature DB >> 22037776

The metal-carbonyl···π(aryl) interaction as a supramolecular synthon for the stabilisation of transition metal carbonyl crystal structures.

Julio Zukerman-Schpector1, Ionel Haiduc, Edward R T Tiekink.   

Abstract

M-carbonyl(lone pair)···π(aryl) interactions provide stability to their transition metal crystal structures. This supramolecular synthon usually leads to zero- or one-dimensional aggregation patterns; a rare example of a three-dimensional architecture based on the M-CO(lone pair)···π(aryl) synthon has also been revealed.

Entities:  

Year:  2011        PMID: 22037776     DOI: 10.1039/c1cc15579b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Supramolecular Synthons: Will Giant Rigid Superspheres Do?

Authors:  Eugenia Peresypkina; Alexander Virovets; Manfred Scheer
Journal:  Cryst Growth Des       Date:  2016-02-23       Impact factor: 4.076

2.  Undeca-carbon-yl[(4-methyl-sulfanylphen-yl)di-phenyl-phosphane]triruthenium(0): crystal structure and Hirshfeld surface analysis.

Authors:  Omar Bin Shawkataly; Hafiz Malik Hussien Abdelnasir; Siti Syaida Sirat; Mukesh M Jotani; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-05-15

3.  [μ2-Bis(di-phenyl-phosphan-yl)hexa-ne]bis-[undeca-carbonyl-triangulo-triruthenium(3 Ru-Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis.

Authors:  Omar Bin Shawkataly; Siti Syaida Sirat; Mukesh M Jotani; Edward R T Tiekink
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2017-10-20
  3 in total

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