Literature DB >> 22032761

Directing the reactivity of [HFe4N(CO)12]- toward H+ or CO2 reduction by understanding the electrocatalytic mechanism.

M Diego Rail1, Louise A Berben.   

Abstract

Selective reactivity of an electrocatalytically generated catalyst-hydride intermediate toward the hydrogen evolution reaction (HER) or reduction of CO(2) is key for a CO(2) reduction electrocatalyst. Under appropriate conditions, Et(4)N[Fe(4)N(CO)(12)] (Et(4)N-1) is a catalyst for the HER or for CO(2) conversion at -1.25 V vs SCE using a glassy carbon electrode.

Entities:  

Year:  2011        PMID： 22032761     DOI： 10.1021/ja208312t

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  9 in total

1.  Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes.

Authors:  Kristian E Dalle; Julien Warnan; Jane J Leung; Bertrand Reuillard; Isabell S Karmel; Erwin Reisner
Journal:  Chem Rev       Date:  2019-02-15       Impact factor: 60.622

2.  CO2 Reduction Catalyzed by Nitrogenase: Pathways to Formate, Carbon Monoxide, and Methane.

Authors:  Nimesh Khadka; Dennis R Dean; Dayle Smith; Brian M Hoffman; Simone Raugei; Lance C Seefeldt
Journal:  Inorg Chem       Date:  2016-08-08       Impact factor: 5.165

Review 3.  Transition Metal Complexes as Catalysts for the Electroconversion of CO2 : An Organometallic Perspective.

Authors:  Niklas W Kinzel; Christophe Werlé; Walter Leitner
Journal:  Angew Chem Int Ed Engl       Date:  2021-01-19       Impact factor: 15.336

4.  Bio-inspired cofacial Fe porphyrin dimers for efficient electrocatalytic CO2 to CO conversion: Overpotential tuning by substituents at the porphyrin rings.

Authors:  Zaki N Zahran; Eman A Mohamed; Yoshinori Naruta
Journal:  Sci Rep       Date:  2016-04-18       Impact factor: 4.379

5.  Fe4S4 Cubane Type Cluster Immobilized on a Graphene Support: A High Performance H2 Evolution Catalysis in Acidic Water.

Authors:  Ameerunisha Begum; Aasif Hassan Sheikh; Golam Moula; Sabyasachi Sarkar
Journal:  Sci Rep       Date:  2017-12-05       Impact factor: 4.379

6.  A pendant proton shuttle on [Fe4N(CO)12]- alters product selectivity in formate vs. H2 production via the hydride [H-Fe4N(CO)12].

Authors:  Natalia D Loewen; Emily J Thompson; Michael Kagan; Carolina L Banales; Thomas W Myers; James C Fettinger; Louise A Berben
Journal:  Chem Sci       Date:  2016-01-05       Impact factor: 9.825

7.  Quantum chemical studies of redox properties and conformational changes of a four-center iron CO2 reduction electrocatalyst.

Authors:  Hyesu Jang; Yudong Qiu; Marshall E Hutchings; Minh Nguyen; Louise A Berben; Lee-Ping Wang
Journal:  Chem Sci       Date:  2018-01-29       Impact factor: 9.825

8.  A bioinspired molybdenum-copper molecular catalyst for CO2 electroreduction.

Authors:  Ahmed Mouchfiq; Tanya K Todorova; Subal Dey; Marc Fontecave; Victor Mougel
Journal:  Chem Sci       Date:  2020-05-18       Impact factor: 9.825

9.  Spectroscopic X-ray and Mössbauer Characterization of M6 and M5 Iron(Molybdenum)-Carbonyl Carbide Clusters: High Carbide-Iron Covalency Enhances Local Iron Site Electron Density Despite Cluster Oxidation.

Authors:  Jeremy McGale; George E Cutsail; Chris Joseph; Michael J Rose; Serena DeBeer
Journal:  Inorg Chem       Date:  2019-09-25       Impact factor: 5.165
  9 in total

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