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Literature DB >> 21905190

Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity.

Robert Langer¹, Yael Diskin-Posner, Gregory Leitus, Linda J W Shimon, Yehoshoa Ben-David, David Milstein.

Abstract

A highly active iron catalyst for the hydrogenation of carbon dioxide and bicarbonates works under remarkably low pressures and achieves activities similar to some of the best noble metal catalysts. A mechanism is proposed involving the direct attack of an iron trans-dihydride on carbon dioxide, followed by ligand exchange and dihydrogen coordination.

Entities: Chemical

Year: 2011 PMID： 21905190 DOI： 10.1002/anie.201104542

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

25 in total

1. Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals.

Authors: Zhiyao Lu; Valeriy Cherepakhin; Ivan Demianets; Paul J Lauridsen; Travis J Williams
Journal: Chem Commun (Camb) Date: 2018-07-10 Impact factor: 6.222

2. Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures.

Authors: Jonathan F Hull; Yuichiro Himeda; Wan-Hui Wang; Brian Hashiguchi; Roy Periana; David J Szalda; James T Muckerman; Etsuko Fujita
Journal: Nat Chem Date: 2012-03-18 Impact factor: 24.427

3. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

Authors: Deidra L Gerlach; Sopheavy Siek; Dalton B Burks; Jamie M Tesh; Courtney R Thompson; Robert M Vasquez; Nicholas J White; Matthias Zeller; Douglas B Grotjahn; Elizabeth T Papish
Journal: Inorganica Chim Acta Date: 2017-07-01 Impact factor: 2.545

4. Computational studies on the hydride transfer barrier for the catalytic hydrogenation of CO₂ by different Ni(II) complexes.

Authors: Santu Biswas; Animesh Chowdhury; Prodyut Roy; Anup Pramanik; Pranab Sarkar
Journal: J Mol Model Date: 2018-08-07 Impact factor: 1.810

Low-pressure hydrogenation of carbon dioxide catalyzed by an iron pincer complex exhibiting noble metal activity.

1. Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals.

2. Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures.

3. Ruthenium (II) and Iridium (III) Complexes of N-Heterocyclic Carbene and Pyridinol Derived Bidentate Chelates: Synthesis, Characterization, and Reactivity.

4. Computational studies on the hydride transfer barrier for the catalytic hydrogenation of CO₂ by different Ni(II) complexes.

5. Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex.

6. Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal-Ligand Cooperation.

7. Tuning Ruthenium Carbene Complexes for Selective P-H Activation through Metal-Ligand Cooperation.

8. A Convenient Synthetic Protocol to 1,2-Bis(dialkylphosphino)ethanes.

9. Photocatalytic Formic Acid Conversion on CdS Nanocrystals with Controllable Selectivity for H2 or CO.

10. Synthesis and reactivity of BINEPINE-based chiral Fe(II) PNP pincer complexes.