| Literature DB >> 21879702 |
Shi-Chuan Tuo1, Jian-Liang Ye, Ai-E Wang, Su-Yu Huang, Pei-Qiang Huang.
Abstract
A 10-step asymmetric synthesis of 9-epi-sessilifoliamide J (20), together with sessilifoliamide J (6), has been accomplished from the key chiral building block 11 via a threo-selective vinylogous Mannich reaction and a Ley oxidation-SmI(2)-mediated coupling lactonization. The absolute configuration of the natural sessilifoliamide J was established.Entities:
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Year: 2011 PMID： 21879702 DOI： 10.1021/ol202140y
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005