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Literature DB >> 21877719

"Nanoscale lattice fence" in a metal-organic framework: interplay between hinged topology and highly anisotropic thermal response.

Lucas D DeVries¹, Paul M Barron, Evan P Hurley, Chunhua Hu, Wonyoung Choe.

Abstract

A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI(2) exhibits a 3D "lattice fence" topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hinged structure model presented here can also be applied to other "lattice fence" topologies with little or no modification, depending on the symmetry of the molecular building blocks.

Entities: Chemical Species

Year: 2011 PMID： 21877719 DOI： 10.1021/ja2032822

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

6 in total

1. A Chlorin-Based Nanoscale Metal-Organic Framework for Photodynamic Therapy of Colon Cancers.

Authors: Kuangda Lu; Chunbai He; Wenbin Lin
Journal: J Am Chem Soc Date: 2015-06-12 Impact factor: 15.419

Review 2. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors: Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal: Chem Rev Date: 2012-11-02 Impact factor: 60.622

6. Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln₃(adipate)_4.5(DMF)₂ (Ln = Gd-Er) Framework Series.

Authors: Patrick W Doheny; Simon J Cassidy; Paul J Saines
Journal: Inorg Chem Date: 2022-03-14 Impact factor: 5.165

6 in total

"Nanoscale lattice fence" in a metal-organic framework: interplay between hinged topology and highly anisotropic thermal response.

1. A Chlorin-Based Nanoscale Metal-Organic Framework for Photodynamic Therapy of Colon Cancers.

Review 2. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

3. Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behaviour.

4. Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework.

5. Controlling Thermal Expansion Behaviors of Fence-Like Metal-Organic Frameworks by Varying/Mixing Metal Ions.

6. Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln₃(adipate)_4.5(DMF)₂ (Ln = Gd-Er) Framework Series.

"Nanoscale lattice fence" in a metal-organic framework: interplay between hinged topology and highly anisotropic thermal response.

1. A Chlorin-Based Nanoscale Metal-Organic Framework for Photodynamic Therapy of Colon Cancers.

Review 2. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

3. Supramolecular-jack-like guest in ultramicroporous crystal for exceptional thermal expansion behaviour.

4. Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework.

5. Controlling Thermal Expansion Behaviors of Fence-Like Metal-Organic Frameworks by Varying/Mixing Metal Ions.

6. Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln3(adipate)4.5(DMF)2 (Ln = Gd-Er) Framework Series.

6. Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln₃(adipate)_4.5(DMF)₂ (Ln = Gd-Er) Framework Series.