Literature DB >> 21877685

A solid lithium electrolyte via addition of lithium isopropoxide to a metal-organic framework with open metal sites.

Brian M Wiers1, Maw-Lin Foo, Nitash P Balsara, Jeffrey R Long.   

Abstract

The uptake of LiO(i)Pr in Mg(2)(dobdc) (dobdc(4-) = 1,4-dioxido-2,5-benzenedicarboxylate) followed by soaking in a typical electrolyte solution leads to the new solid lithium electrolyte Mg(2)(dobdc)·0.35LiO(i)Pr·0.25LiBF(4)·EC·DEC (EC = ethylene carbonate; DEC = diethyl carbonate). Two-point ac impedance data show a pressed pellet of this material to have a conductivity of 3.1 × 10(-4) S/cm at 300 K. In addition, the results from variable-temperature measurements reveal an activation energy of just 0.15 eV, while single-particle data suggest that intraparticle transport dominates conduction.

Entities:  

Year:  2011        PMID： 21877685     DOI： 10.1021/ja205827z

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

1.  Conformal Ultrathin Film Metal-Organic Framework Analogues: Characterization of Growth, Porosity, and Electronic Transport.

Authors:  Jonathan Lau; Ashley E Trojniak; Macy J Maraugha; Alyssa J VanZanten; Alexander J Osterbaan; Andrew C Serino; Monica L Ohnsorg; Kevin M Cheung; David S Ashby; Paul S Weiss; Bruce S Dunn; Mary E Anderson
Journal:  Chem Mater       Date:  2019-10-15       Impact factor: 9.811

2.  Metal-organic frameworks as a tunable platform for designing functional molecular materials.

Authors:  Cheng Wang; Demin Liu; Wenbin Lin
Journal:  J Am Chem Soc       Date:  2013-08-28       Impact factor: 15.419

3.  An all solid-state Li ion battery composed of low molecular weight crystalline electrolyte.

Authors:  Prerna Joshi; Raman Vedarajan; Anjaiah Sheelam; Kothandaraman Ramanujam; Bernard Malaman; Noriyoshi Matsumi
Journal:  RSC Adv       Date:  2020-02-28       Impact factor: 4.036

4.  Million-Fold Electrical Conductivity Enhancement in Fe2(DEBDC) versus Mn2(DEBDC) (E = S, O).

Authors:  Lei Sun; Christopher H Hendon; Mikael A Minier; Aron Walsh; Mircea Dincă
Journal:  J Am Chem Soc       Date:  2015-05-06       Impact factor: 15.419

5.  Zero-strain reductive intercalation in a molecular framework.

Authors:  Joshua A Hill; Andrew B Cairns; Jared J K Lim; Simon J Cassidy; Simon J Clarke; Andrew L Goodwin
Journal:  CrystEngComm       Date:  2015-01-16       Impact factor: 3.545

6.  Sub-nanometer confinement enables facile condensation of gas electrolyte for low-temperature batteries.

Authors:  Guorui Cai; Yijie Yin; Dawei Xia; Amanda A Chen; John Holoubek; Jonathan Scharf; Yangyuchen Yang; Ki Hwan Koh; Mingqian Li; Daniel M Davies; Matthew Mayer; Tae Hee Han; Ying Shirley Meng; Tod A Pascal; Zheng Chen
Journal:  Nat Commun       Date:  2021-06-07       Impact factor: 14.919

7.  Molecular motions in functional self-assembled nanostructures.

Authors:  Alexandre Dhotel; Ziguang Chen; Laurent Delbreilh; Boulos Youssef; Jean-Marc Saiter; Li Tan
Journal:  Int J Mol Sci       Date:  2013-01-24       Impact factor: 5.923

8.  N7-(carboxymethyl)guanine-Lithium Crystalline Complex: A Bioinspired Solid Electrolyte.

Authors:  Dipak Dutta; N Nagapradeep; Haijin Zhu; Maria Forsyth; Sandeep Verma; Aninda J Bhattacharyya
Journal:  Sci Rep       Date:  2016-04-19       Impact factor: 4.379

Review 9.  Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges.

Authors:  Hao Bin Wu; Xiong Wen David Lou
Journal:  Sci Adv       Date:  2017-12-01       Impact factor: 14.136

10.  Low temperature ionic conductor: ionic liquid incorporated within a metal-organic framework.

Authors:  Kazuyuki Fujie; Kazuya Otsubo; Ryuichi Ikeda; Teppei Yamada; Hiroshi Kitagawa
Journal:  Chem Sci       Date:  2015-05-05       Impact factor: 9.825
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