Candice L Joe1, Kian L Tan. 1. Boston College, 2609 Beacon Street, Chestnut Hill, Massachusetts 02467-3860, USA.
Abstract
We have developed a ligand that reversibly binds to aniline substrates, allowing for the control of regioselectivity and enantioselectivity in hydroformylation. In this paper we address how the electronics of the aniline ring affect both the binding of the substrate to the ligand and the enantioselectivity in this reaction.
We have developed a ligand that reversibly binds to n class="Chemical">aniline substrates, allowing for the n class="Chemical">control of regioselectivity and enantioselectivity in hydroformylation. In this paper we address how the electronics of the aniline ring affect both the binding of the substrate to the ligand and the enantioselectivity in this reaction.
Authors: Samir H Chikkali; Rosalba Bellini; Guillaume Berthon-Gelloz; Jarl Ivar van der Vlugt; Bas de Bruin; Joost N H Reek Journal: Chem Commun (Camb) Date: 2010-01-18 Impact factor: 6.222