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Literature DB >> 21842847

Enantioselective hydroformylation of aniline derivatives.

Abstract

We have developed a ligand that reversibly binds to aniline substrates, allowing for the control of regioselectivity and enantioselectivity in hydroformylation. In this paper we address how the electronics of the aniline ring affect both the binding of the substrate to the ligand and the enantioselectivity in this reaction.

Entities: Chemical Species

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Year: 2011 PMID： 21842847 PMCID： PMC3170429 DOI： 10.1021/jo201328d

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

24 in total

1. High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes.

Authors: Mark Kuil; Theresa Soltner; Piet W N M van Leeuwen; Joost N H Reek
Journal: J Am Chem Soc Date: 2006-09-06 Impact factor: 15.419

2. Catalytic scaffolding ligands: an efficient strategy for directing reactions.

Authors: Thomas E Lightburn; Michael T Dombrowski; Kian L Tan
Journal: J Am Chem Soc Date: 2008-06-25 Impact factor: 15.419

3. Highly selective room-temperature copper-catalyzed C-N coupling reactions.

Authors: Alexandr Shafir; Stephen L Buchwald
Journal: J Am Chem Soc Date: 2006-07-12 Impact factor: 15.419

4. Remote control of regio- and diastereoselectivity in the hydroformylation of bishomoallylic alcohols with catalytic amounts of a reversibly bound directing group.

Authors: Christian U Grünanger; Bernhard Breit
Journal: Angew Chem Int Ed Engl Date: 2010 Impact factor: 15.336

5. Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes.

Authors: Samir H Chikkali; Rosalba Bellini; Guillaume Berthon-Gelloz; Jarl Ivar van der Vlugt; Bas de Bruin; Joost N H Reek
Journal: Chem Commun (Camb) Date: 2010-01-18 Impact factor: 6.222

6. Application of a chiral scaffolding ligand in catalytic enantioselective hydroformylation.

Authors: Amanda D Worthy; Candice L Joe; Thomas E Lightburn; Kian L Tan
Journal: J Am Chem Soc Date: 2010-10-27 Impact factor: 15.419

7. Enantioselective hydroformylation of N-vinyl carboxamides, allyl carbamates, and allyl ethers using chiral diazaphospholane ligands.

Authors: Richard I McDonald; Gene W Wong; Ram P Neupane; Shannon S Stahl; Clark R Landis
Journal: J Am Chem Soc Date: 2010-10-13 Impact factor: 15.419

8. Origin of pressure effects on regioselectivity and enantioselectivity in the rhodium-catalyzed hydroformylation of styrene with (S,S,S)-BisDiazaphos.

Authors: Avery L Watkins; Clark R Landis
Journal: J Am Chem Soc Date: 2010-08-04 Impact factor: 15.419

9. Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: structure-selectivity relationship.

Authors: Xiaowei Zhang; Bonan Cao; Yongjun Yan; Shichao Yu; Baoming Ji; Xumu Zhang
Journal: Chemistry Date: 2010-01-18 Impact factor: 5.236